5-(对甲苯基)戊-1-醇 | 101971-26-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 5-(对甲苯基)戊-1-醇
• 英文名称: 5-(4-methylphenyl)pentane-1-ol
• 英文别名: 5-(p-tolyl)pentan-1-ol；5-oxy-1-p-tolyl-pentane；1-Methyl-4-(ε-oxy-pentyl)-benzol；ε-p-Tolyl-n-amylalkohol；5-Oxy-1-p-tolyl-pentan；5-p-Tolyl-pentanol-(1)；p-Methylbenzenepentanol；5-(4-methylphenyl)pentan-1-ol
• CAS: 101971-26-0
• 化学式: C₁₂H₁₈O
• 分子量: 178.274
• InChiKey: MJUWMZDQXSGQEO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  5-(对甲苯基)戊-1-醇 在 硫酸 、 氢溴酸 作用下， 生成 5-Brom-1-p-tolyl-pentan
  参考文献：
  名称：

  363.血吸虫病的化学疗法。第四部分 4-氨基-2-甲氧基苯酚的一些醚

  摘要：

  DOI：

  10.1039/jr9610001863
• 作为产物：
  描述：

  5-(p-tolyl)pent-4-yn-1-ol 在 palladium 10% on activated carbon 、 氢气 作用下， 以 乙醇 为溶剂， 反应 15.5h， 以2.22 g的产率得到5-(对甲苯基)戊-1-醇
  参考文献：
  名称：

  新規リゾホスファチジン酸誘導体

  摘要：

  本发明旨在提供特异作用于LPA4受体的化合物以及含有该化合物的药物组合物。本发明涉及具有LPA4受体激动剂作用的新型磷脂酰肌醇酸衍生物，对涉及LPA4受体引起的血管形成异常疾病、血管障碍疾病或相关症状的预防和/或治疗具有用处。此外，本发明还涉及含有该磷脂酰肌醇酸衍生物的药物组合物。【选择图】无

  公开号：

  JP2021080183A

文献信息

• CURING AGENT FOR LOW TEMPERATURE CURE APPLICATIONS
  申请人：Vedage Gamini Ananda

  公开号：US20100048954A1

  公开（公告）日：2010-02-25

  The present invention discloses both amine compositions and amine-epoxy compositions containing N,N′-dimethyl-meta-xylylenediamine. A novel process for producing amines such as N,N′-dimethyl-meta-xylylenediamine, and structurally similar amines, is also disclosed.

  本发明公开了含有N,N'-二甲基-间二甲苯二胺的胺类组合物和胺-环氧组合物。还公开了一种生产胺类化合物，如N,N'-二甲基-间二甲苯二胺和结构类似的胺类化合物的新方法。
• Self-priming chromate free corrosion resistant coating composition and method
  申请人：Bhattacharya Dhrubo

  公开号：US20060063881A1

  公开（公告）日：2006-03-23

  A self-priming rapid curing chromate free corrosion resistant coating composition based on a random polyvinyl terpolymer and an alkyd resin with a hydroxyl number between 80-200 in association with a mineral acid catalyst, at least one organic solvent and a drying agent wherein the vinyl terpolymer is predominantly a polyvinyl formal with polyvinyl alcohol and polyvinyl acetate as the other two co-polymers, the terpolymer cross linking through its hydroxyl groups with the alkyd resin in the composition during curing. The composition can be applied as a clear coat or as a pigmented composition with addition of pigments on ferrous and non-ferrous metallic substrate and is suitable for continuous coil coating lines. A method of coating a ferrous and non-ferrous metallic substrate by applying a coating composition on its surface and coated articles so produced.

  一种基于随机聚乙烯三元聚合物和醇酸树脂的自吸引迅速固化无铬防腐涂料组合物，其醇酸值介于80-200之间，与矿酸催化剂、至少一种有机溶剂和干燥剂结合，其中聚乙烯三元聚合物主要是聚乙烯缩醛，另外两种共聚物为聚乙烯醇和聚乙烯醋酸酯，通过其羟基与树脂在固化过程中交联。该组合物可作为透明涂层或添加颜料后应用于铁和非铁金属基底，适用于连续线圈涂层生产线。一种在铁和非铁金属基底表面涂覆涂料组合物的方法以及由此生产的涂覆制品。
• Benzimidazolone compound
  申请人：Hosaka Masaki

  公开号：US20060058531A1

  公开（公告）日：2006-03-16

  There are provided benzimidazolone compounds that provide a plurality of hues from a single structural formula, and are useful as pigments that offer superior dispersibility in binder resins, as well as benzimidazolone compounds that are useful as pigments, and show minimal flocculation when pigments of two or more different hues are blended together to produced a desired hue. A benzimidazolone compound represented by a general formula (1) shown below. (wherein, R 1 , R 2 , R 3 and R 4 each represent, independently, a hydrogen atom, an alkyl group of 1 to 5 carbon atoms, or an alkoxy group of 1 to 5 carbon atoms, and R 5 and R 6 each represent, independently, an alkyl group of 1 to 5 carbon atoms.)

  提供了苯并咪唑酮化合物，可从单一结构式中提供多种色调，并且可作为颜料，具有在粘合剂树脂中提供优越的分散性的优点，以及可作为颜料的苯并咪唑酮化合物，当混合两种或两种以上不同色调的颜料以产生所需的色调时，显示最小的絮凝现象。以下是表示为通用公式（1）的苯并咪唑酮化合物。（其中，R1、R2、R3和R4分别独立地表示氢原子、1至5个碳原子的烷基或1至5个碳原子的烷氧基，而R5和R6分别独立地表示1至5个碳原子的烷基。）
• Ring-opening of cyclic ethers with carbon–carbon bond formation by Grignard reagents
  作者：Stig Holden Christensen、Torkil Holm、Robert Madsen

  DOI：10.1016/j.tet.2014.05.026

  日期：2014.8

  The ring-opening of cyclic ethers with concomitant C–C bond formation was studied with a number of Grignard reagents. The transformation was performed in a sealed vial by heating to ∼160 °C in an aluminum block or at 180 °C in a microwave oven. Good yields of the product alcohols were obtained with allyl- and benzylmagnesium halides when the ether was tetrahydrofuran or 3,3-dimethyloxetane. Lower yields

  用许多格氏试剂研究了伴随有CC键形成的环状醚的开环。通过在铝瓶中加热到约160°C或在微波炉中加热到180°C，在密封的小瓶中进行转化。当醚是四氢呋喃或3,3-二甲基氧杂环丁烷时，用烯丙基卤化和苄基卤化镁可获得良好的产物醇收率。用取代的四氢呋喃得到的产率较低，而用四氢吡喃没有观察到开环。只有高反应性的烯丙基和苄基格利雅试剂参与了转化，而与其他烷基卤化镁没有反应发生。
• POLYMER AND COMPOSITION
  申请人：DSM IP ASSETS B.V.

  公开号：US20160237213A1

  公开（公告）日：2016-08-18

  The present invention relates to a polyester resin obtained by reaction in a process (I) between the following components A to E to obtain a polyester P (the polyester comprising an alkyd resin and/or a saturated polyester resin), where (A) Component A (also referred to herein as the Imide and/or Imide Component) comprises one or more cyclic imides of Formula (1); where R′ represents a divalent optionally substituted saturated C 1-30 organo moiety; and R represents H or a monovalent optionally substituted saturated C 1-30 organo moiety; (A′) Optional Component A′ comprises saturated dicarboxylic acid and/or saturated hydroxyacid and that is not optional in case component A does not comprise a dicarboxylic acid or a hydroxyacid; 1(B) Component B (also referred to herein as the Polyol and/or Polyol Component) comprises at least one saturated polyhydric alcohol; (C) Optional Component C (also referred to herein as the Rosin and/or Rosin Component) comprises naturally occurring rosin, the rosin comprising from 40 to 80 parts per hundred by weight of rosin of an unsaturated mono carboxylic acid comprising at least one C 5-25 cyclohydrocarbo moiety capable of undergoing a Diels Alder or Ene reaction; (D) Optional Component D (also referred to herein as the Fatty Acid and/or Fatty Acid Component) comprises at least one linear C 2-60 hydrocarbo carboxylic acid optionally comprising at least two linoleically unsaturated double bonds; 2(E) Optional Component E (also referred to as the Other Component E) which may comprise at least one monofunctional or polyfunctional monomer other than any of Components A to D.

  本发明涉及通过在以下组分A到E之间的过程（I）中反应获得的聚酯树脂P（聚酯包括醇酸树脂和/或饱和聚酯树脂），其中（A）组分A（在此也称为咪唑和/或咪唑组分）包括公式（1）的一个或多个环状咪唑；其中R'表示二价的、可选取代的饱和的C1-30有机基团；R表示H或一价的、可选取代的饱和的C1-30有机基团；（A'）可选组分A'包括饱和的二羧酸和/或饱和的羟酸，在组分A不包括二羧酸或羟酸的情况下不是可选的；（B）组分B（在此也称为多元醇和/或多元醇组分）包括至少一种饱和的多元醇；（C）可选组分C（在此也称为松香和/或松香组分）包括天然存在的松香，该松香包括每百份重量的松香中40至80份的不饱和单羧酸，该不饱和单羧酸包括至少一个可进行Diels Alder或Ene反应的C5-25环烃基团；（D）可选组分D（在此也称为脂肪酸和/或脂肪酸组分）包括至少一种线性的C2-60碳氢基团羧酸，可选包括至少两个亚油酸不饱和双键；（E）可选组分E（也称为其他组分E）可能包括至少一种单官能团或多官能团单体，除了组分A到D中的任何一种。