二(羟基甲基)过氧化物 | 17088-73-2

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 中文名称: 二(羟基甲基)过氧化物
• 英文名称: bis-hydroxymethyl peroxide
• 英文别名: bis-hydroxymethyl hydroperoxide；peroxy-bis-methanol；Bis-hydroxymethyl-peroxid；Dihydroxy-dimethylperoxyd；Dimethylolperoxyd；Diformalperoxydhydrat；Dioxy-dimethylperoxyd；Bis(hydroxymethyl)peroxide；hydroxymethylperoxymethanol
• CAS: 17088-73-2
• 化学式: C₂H₆O₄
• 分子量: 94.0672
• InChiKey: JLJXMZMKMRQOLN-UHFFFAOYSA-N

物化性质

• 熔点：
  62-64 °C
• 沸点：
  183.9±25.0 °C(Predicted)
• 密度：
  1.3000 (rough estimate)

计算性质

• 辛醇/水分配系数(LogP)：
  -1
• 重原子数：
  6
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  58.9
• 氢给体数：
  2
• 氢受体数：
  4

安全信息

• 海关编码：
  2909600000
• 储存条件：
  库房应保持通风、低温和干燥，并且在装卸时要轻拿轻放。

制备方法与用途

类别：爆炸物品

爆炸物危险特性

• 一种烈性爆炸物品，摩擦易引发爆炸。

可燃性危险特性

• 受热分解产生刺激烟雾。

储运特性

• 应存放在通风、低温和干燥的库房内，并轻装轻卸。

灭火剂

• 泡沫、二氧化碳及雾状水。

反应信息

• 作为反应物：
  描述：

  二(羟基甲基)过氧化物 在 氨 作用下， 生成 六亚甲基三过氧化二胺
  参考文献：
  名称：

  Legler, Chemische Berichte, 1885, vol. 18, p. 3344

  摘要：

  DOI：
• 作为产物：
  描述：

  丙烷 在 氧气 作用下， 生成 二(羟基甲基)过氧化物
  参考文献：
  名称：

  Harris; Egerton, Chemical Reviews, 1937, vol. 21, p. 291

  摘要：

  DOI：

文献信息

• The kinetics of complex formation between Ti(IV) and hydrogen peroxide
  作者：Daniel W. O'Sullivan、Michael Tyree

  DOI：10.1002/kin.20259

  日期：2007.8

  The kinetics of the formation of the titanium-peroxide [TiO2+2] complex from the reaction of Ti(IV)OSO4 with hydrogen peroxide and the hydrolysis of hydroxymethyl hydroperoxide (HMHP) were examined to determine whether Ti(IV)OSO4 could be used to distinguish between hydrogen peroxide and HMHP in mixed solutions. Stopped-flow analysis coupled to UV-vis spectroscopy was used to examine the reaction kinetics

  研究了 Ti(IV)OSO4 与过氧化氢反应和羟甲基过氧化氢 (HMHP) 的水解形成钛-过氧化物 [TiO2+2] 络合物的动力学，以确定是否可以使用 Ti(IV)OSO4区分混合溶液中的过氧化氢和 HMHP。使用与紫外-可见光谱耦合的停流分析来检查不同温度下的反应动力学。[TiO2+2] 配合物的摩尔吸光率 (e) 在 405 nm 处为 679.5 ± 20.8 L mol-1 cm-1。相对于 Ti(IV)OSO4 和 H2O2，过氧化氢和 Ti(IV)OSO4 之间的反应是一级反应，在 25°C 下的速率常数为 5.70 ± 0.18 × 104 M-1 s-1，活化能, Ea = 40.5 ± 1.9 kJ mol-1。在 pH 8.5 时，HMHP 的水解速率常数为 4.3 × 10-3 s-1。由于 Ti(IV)OSO4 和过氧化氢之间的复合物形成速率远快于 HMHP 的水解速率，因此
• Cytostatische Effekte organischer Persauerstoff-Verbindungen gegenüber Ascites-Krebszellen
  作者：Günther Weitzel、Eckhart Buddecke、Friedhelm Schneider

  DOI：10.1515/bchm2.1961.323.1.211

  日期：1961.1
• Cytostatische Effekte stickstoff haltiger organischer Peroxyde
  作者：Günther Weitzel、Friedhelm Schneider、Heinz Pfeil、Karl Seynsche

  DOI：10.1515/bchm2.1963.331.1.219

  日期：1963.1
• Jenkins; Style, Journal of the Chemical Society, 1953, p. 2357
  作者：Jenkins、Style

  DOI：——

  日期：——
• Aqueous solubility and reaction kinetics of hydroxymethyl hydroperoxide
  作者：Xianliang Zhou、Yin Nan Lee

  DOI：10.1021/j100180a051

  日期：1992.1

  The aqueous-phase equilibria and kinetics of the formation of hydroxymethyl hydroperoxide (HMP) and of bis(hydroxymethyl) peroxide (BHMP) from formaldehyde and hydrogen peroxide, i.e., H2CO + H2O2 reversible HOCH2O2H (1, -1), and HOCH2O2H + H2CO if and only if HOCH2O2CH2OH (2) were studied using an amperometric technique which is highly sensitive and selective for H2O2. The equilibrium constants of reactions 1 and 2 between 5 and 35-degrees-C were determined to be K1 = 2.35 x 10(-2) exp(2610/T) M-1 and K2 = 1.04 x 10(-3) exp(2780/T) M-1, respectively, both independent of pH between 4.0 and 8.4. The rate coefficients of (1) and (-1) determined at pH 7.07 +/- 0.02 between 5 and 35-degrees-C are k1 = 6.0 x 10(13) exp(-9450/T) M-1 s-1 and k-1 = 1.0 x 10(15) exp(-11800/T) s-1. Both k1 and k-1 are base-catalyzed and are linearly dependent on pH between 4.0 and 8.2, namely, k-1 = (5.0 +/- 0.3) x 10(-10)/[H+] s-1 at 25.8 +/- 0.1-degrees-C. The Henry's law constants of HMP and BHMP, determined by measuring their corresponding gas and aqueous concentrations at phase equilibrium, are 5.0(-0.9)+16 x 10(5) and 6(-2)+3 x 10(5) M atm-1 at 22.0 +/- 0.1-degrees-C, and 6.2(-0.9)+1.2 x 10(5) and 20(-7)+18 x 10(5) M atm-1 at 10.0 +/- 0.1-degrees-C, respectively. The reaction kinetics of HMP with S(IV) was studied by a competition technique using the H2O2-S(IV) reaction as the reference; the reaction is acid-catalyzed, with an effective second-order rate constant of (2.2 x 10(7))[H+] +/- 15% M-1 s-1 for the pH range 3-4 at 22.0 +/- 0.1-degrees-C. These results indicte that gas-phase HMP in the atmosphere is efficiently removed by wet scavenging processes and would be quantitatively detected by peroxide instruments involving gas-liquid scrubbers, provided that the scrubbed HMP is stabilized. The time constant of the dissociation of dissolved HMP to H2O2 is fairly short, being approximately 100 min at pH 5.5, shorter at higher pH. Consequently, HMP is expected to be stable and detected in atmospheric liquid water only at pH less-than-or-equal-to 5.5.