p-anisylmercuric chloride | 3009-79-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: p-anisylmercuric chloride
• 英文别名: p-Anisyl-quecksilberchlorid
• CAS: 3009-79-8
• 化学式: C₇H₇ClHgO
• 分子量: 343.175
• InChiKey: ODCJBHXFAFFNEW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.56
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  p-anisylmercuric chloride 在 di(rhodium)tetracarbonyl dichloride 四丁基碘化铵 作用下， 以 六甲基磷酰三胺 为溶剂， 反应 2.0h， 以88%的产率得到4,4-二甲氧基联苯
  参考文献：
  名称：

  Reactions of organometallic compounds, catalyzed by transition metal complexes. 7. Oxidative demercuration of arylmercury in the presence of complexes of palladium and rhodium

  摘要：

  DOI：

  10.1007/bf00948854
• 作为产物：
  描述：

  4-甲氧基苯硼酸 在 水 、 mercury dichloride 作用下， 生成 p-anisylmercuric chloride
  参考文献：
  名称：

  Torssell, Acta Chemica Scandinavica (1947), 1959, vol. 13, p. 115,116,118

  摘要：

  DOI：

文献信息

• Symmetrization of Phenylmercuric Hydroxides by the Action of Nickel(II) and Cobalt(II) Acetylacetonates. Isolation and Structural Characterization of an Intermediate in This Reaction
  作者：Manfred Döring、Gabriela Hahn、Michael Stoll、Alexander C. Wolski

  DOI：10.1021/om960799g

  日期：1997.4.1

  diphenylmercury, HgO, and Ni(acac)2(THF)2. With PhHgOH or PhHgSH the symmetrization reactions also occurred when catalytic amounts of Ni(acac)2 were used. In contrast, triphenyltin derivatives (hydroxide, acetate, oxide) on treatment with M(acac)2 in aqueous THF gave the stable complexes [M(acac)2(Ph3SnOH)]2 (M = Co, Ni). The structure of [Ni(acac)2(Ph3SnOH)]2 (2) was also determined by X-ray crystallography

  通过在环境温度下将PhHgOH掺入M（acac）2的配位域中，可以获得复合加合物[M（acac）2（PhHgOHgPh）] 2（M = Co，Ni）。[Ni（acac）2（PhHgOHgPh）（Et 2 O）] 2（1c）的X射线晶体结构显示了由乙酰丙酮氧和双（苯基汞）氧化物的桥联氧配位的二聚镍配合物。将化合物1c的THF溶液回流，得到二苯基汞，HgO和Ni（acac）2（THF）2。使用PhHgOH或PhHgSH时，当催化量的Ni（acac）2时也会发生对称化反应被使用。相反，在THF水溶液中用M（acac）2处理的三苯锡衍生物（氢氧化物，乙酸盐，氧化物）得到稳定的络合物[M（acac）2（Ph 3 SnOH）] 2（M = Co，Ni）。[Ni（acac）2（Ph 3 SnOH）] 2（2）的结构也通过X射线晶体学确定。
• Microwave induced novel synthetic route to organomercurials
  作者：Mazaahir Kidwai、Yogesh Goel

  DOI：10.1016/0277-5387(95)00569-2

  日期：1996.6

  Abstract Organomercurials of 2-mercapto-5-methyl-1,3,4-thiadiazole and 2-mercapto-5-[4′-methyl quinolinyl-2-oxy methyl] -1,3,4-oxadiazole with aryl mercuric chloride have been synthesized under microwave irradiation in open vessels in a domestic microwave oven within a few minutes. This reaction rate was ca 100 times faster than the reaction rate in the conventional way. These organomercurials have a

  摘要2-巯基-5-甲基-1,3,4-噻二唑和2-巯基5- [4'-甲基喹啉基-2-氧甲基] -1,3,4-恶二唑与芳基氯化汞的有机聚体有在几分钟内在家用微波炉的敞口容器中在微波辐射下合成了α-β-己内酰胺。该反应速率比常规方法快约100倍。这些有机汞的化学计量比为芳基汞和噻二唑或恶二唑部分的化学计量比为1：1。
• Synthesis of β,γ-unsaturated amides via palladium-promoted coupling of organomercurials and vinylic β-lactams
  作者：Richard C. Larock、Shuji Ding

  DOI：10.1016/s0040-4039(00)99607-2

  日期：1989.1

  The reaction of aryl or vinylic mercurials, Li2PdCl4 and vinylic β-lactams affords good yields of the corresponding ring-opened β,γ-unsaturated amides.

  芳基或乙烯基汞，Li 2 PdCl 4和乙烯基β-内酰胺的反应提供了良好产率的相应的开环β，γ-不饱和酰胺。
• Mercury in organic chemistry. 20. Alkylation of organomercurials via organocopper reagents
  作者：R.C. Larock、D.R. Leach

  DOI：10.1016/s0040-4039(01)81925-0

  日期：1981.1

  Aryl-, alkenyl-, and alkylmercurials readily cross-couple with primary and secondary alkyl- and alkenylcuprate reagents to provide the first truly general method for the alkylation of a wide variety of organomercurials.

  芳基，烯基和烷基汞容易与伯，仲烷基和烯基铜酸盐试剂交联，从而为各种有机汞的烷基化提供了第一个真正通用的方法。
• Thermal studies on organomercury(II) complexes of 6-thioguanine
  作者：Vinod Kumar Ahluwalia、Jasjeet Kaur、Balbir Singh Ahuja、Gurvinder Singh Sodhi

  DOI：10.1016/0040-6031(91)80287-s

  日期：1991.3

  Abstract Organomercury(II) complexes involving 6-thioguanine of the type p -XC 6 H 4 HgL ( I ) (LH = 6-thioguanine; X = Me, MeO, NO 2 ) have been synthesized. Spectral studies (IR and UV) indicate that the 6-thioguanine moiety acts as a bidentate group. From thermogravimetric (TG) curves, the order, activation energy and apparent activation entropy of the thermal decomposition reaction have been elucidated

  摘要 已经合成了涉及 p -XC 6 H 4 HgL ( I ) 型 6-硫鸟嘌呤的有机汞 (II) 配合物（LH = 6-硫鸟嘌呤；X = Me、MeO、NO 2 ）。光谱研究（IR 和 UV）表明 6-硫鸟嘌呤部分充当双齿基团。从热重(TG)曲线可以阐明热分解反应的阶次、活化能和表观活化熵。活化能的变化与苯环上取代基的性质有关。反应热是从差示扫描量热 (DSC) 研究中获得的。