4-formyl-2-methoxyphenyl 3-phenylpropanoate | 933675-29-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: 4-formyl-2-methoxyphenyl 3-phenylpropanoate
• 英文别名: 4-Formyl-2-methoxyphenyl benzenepropanoate；(4-formyl-2-methoxyphenyl) 3-phenylpropanoate
• CAS: 933675-29-7
• 化学式: C₁₇H₁₆O₄
• 分子量: 284.312
• InChiKey: KKMMKVDNEHKUSM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  21
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4-formyl-2-methoxyphenyl 3-phenylpropanoate 、 4-氨基联苯 以 甲醇 为溶剂， 反应 0.5h， 以90%的产率得到
  参考文献：
  名称：

  Synthesis, film-forming properties, and photosensitivity of 4-alkoxy(acyloxy)-3-alkoxyphenylmethylene-(biphenyl-4-yl)amines

  摘要：

  The reactions of ethers and esters of the vanillin series with biphenyl-4-ylamine in absolute methanol yielded previously unknown E isomers of biphenyl-substituted azomethines (Schiff bases). The film properties and photosensitivity of the new compounds were examined.

  DOI：

  10.1134/s1070363207100167
• 作为产物：
  描述：

  3-苯基丙酸 在 吡啶 、 氯化亚砜 作用下， 以 苯 为溶剂， 生成 4-formyl-2-methoxyphenyl 3-phenylpropanoate
  参考文献：
  名称：

  New esters of vanillin and vanillal with some alkane-and arenecarboxylic acids

  摘要：

  Previously unknown esters were synthesized by the reaction of vanillin and vanillal with carboxylic acid chlorides.

  DOI：

  10.1134/s1070427206060322

文献信息

• Synthesis, film-forming properties, and thermal and light sensitivity of N,N′-bis[4-hydroxy(alkoxy, acyloxy)-3-alkoxyphenylmethylidene]benzene-1,4-diamines
  作者：E. A. Dikusar、N. G. Kozlov、V. I. Potkin、V. A. Azarko、A. P. Yuvchenko

  DOI：10.1134/s1070363208020175

  日期：2008.2

  Previously unknown E,E-isomeric Schiff bases were synthesized by reaction of p-phenylenediamine with 4-hydroxy-3-methoxybenzaldehyde, 3-ethoxy-4-hydroxybenzaldehyde, and their O-alkyl and O-acyl derivatives in anhydrous methanol. Film-forming properties and thermal and light sensitivity of the products were studied.

  之前未知的E,E-异构Schiff碱是通过在无水甲醇中将对苯二胺与4-羟基-3-甲氧基苯甲醛、3-乙氧基-4-羟基苯甲醛及其O-烷基和O-酰基衍生物反应合成的。对产物的成膜性能以及热稳定性和光敏感性进行了研究。
• Two-step synthesis of ferrocenyl esters of vanillic acid
  作者：M. S. Denisov、A. A. Gorbunov、V. O. Nebogatikov、L. V. Pavlogradskaya、V. A. Glushkov

  DOI：10.1134/s107036321703015x

  日期：2017.3

  group and ferroceneboronic acid at the carbonyl group catalyzed with various N-heterocyclic carbenes afforded the corresponding ferrocenyl esters. In these reactions copper(II) sulfate, cinnamic aldehyde, and air oxygen act as oxidants. The resulting ferrocenyl esters of vanillic acid were tested for cytotoxicity.

  香兰素与酚基团的芳族醛和羰基基团的二茂铁硼酸的连续反应由各种N-杂环卡宾催化，得到相应的二茂铁基酯。在这些反应中，硫酸铜（II），肉桂醛和空气中的氧气起氧化剂的作用。测试所得的香草酸二茂铁基酯的细胞毒性。
• In vitro methods for processing lignin and other aromatic compounds
  申请人：WISCONSIN ALUMNI RESEARCH FOUNDATION

  公开号：US10829745B2

  公开（公告）日：2020-11-10

  Enzymes for depolymerizing lignin. The enzymes include dehydrogenases, β-etherases, and glutathione lyases. The dehydrogenases can comprise one or more or LigD, LigO, LigN, and LigL. The β-etherases can comprise one or more of LigE, LigF, LigP, and BaeA. The glutathione lyases can comprise any one or more of LigG and a number of non-stereospecific, optionally recombinant glutathione lyases derived from Sphingobium sp. SYK-6, Novosphingobium aromaticivorans, Escherichia coli, Streptococcus sanguinis, Phanerochaete chrysosporium, and other microorganisms. The enzymes can be combined in compositions and/or used in methods of processing lignin or other aromatic compounds in vitro.

  用于解聚木质素的酶。这些酶包括脱氢酶、β-乙醚酶和谷胱甘肽裂解酶。脱氢酶可包括一种或多种 LigD、LigO、LigN 和 LigL。β-乙醚酶可包括 LigE、LigF、LigP 和 BaeA 中的一种或多种。谷胱甘肽裂解酶可包括 LigG 和一些非立体特异性的、可选择重组的谷胱甘肽裂解酶中的一种或多种，这些谷胱甘肽裂解酶来源于 Sphingobium sp. SYK-6、Novosphingobium aromaticivorans、大肠杆菌、血链球菌、Phanerochaete chrysosporium 和其他微生物。这些酶可以组合成组合物和/或用于体外处理木质素或其他芳香族化合物的方法中。
• 2-[3-Alkoxy-4-(hydroxy, alkoxy, acyloxy)phenyl]-2,3-dihydro-1H-benzimidazoles on the basis of vanillin and vanillal derivatives
  作者：E. A. Dikusar、N. G. Kozlov、V. I. Potkin

  DOI：10.1134/s1070363207110138

  日期：2007.11

  Previously unknown 2-[3-alkoxy-4-(hydroxy, alkoxy, acyloxy)phenyl]-2,3-dihydro-1H-benzimidazoles were prepared by the reaction of aldehydes of the vanillin series and their ethers and esters with 1,2-phenylenediamine in absolute methanol.
• ENZYMES AND METHODS FOR PROCESSING LIGNIN AND OTHER AROMATIC COMPOUNDS
  申请人：WISCONSIN ALUMNI RESEARCH FOUNDATION

  公开号：US20190048329A1

  公开（公告）日：2019-02-14

  Enzymes for depolymerizing lignin. The enzymes include dehydrogenases, β-etherases, and glutathione lyases. The dehydrogenases can comprise one or more or LigD, LigO, LigN, and LigL. The β-etherases can comprise one or more of LigE, LigF, LigP, and BaeA. The glutathione lyases can comprise any one or more of LigG and a number of non-stereospecific, optionally recombinant glutathione lyases derived from Sphingobium sp. SYK-6, Novosphingobium aromaticivorans, Escherichia coli, Streptococcus sanguinis, Phanerochaete chrysosporium , and other microorganisms. The enzymes can be combined in compositions and/or used in methods of processing lignin or other aromatic compounds in vitro.