1,1-dimethyl-2-vinyloxyethylamine | 86241-96-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,1-dimethyl-2-vinyloxyethylamine
• 英文别名: 1-vinyloxy-2-methylpropan-2-amine；2-methyl-3-(vinyloxy)propan-2-amine；1,1-Dimethyl-2-vinyloxy-aethylamin；2-Amino-2-methyl-1-vinyloxy-propan；1,1-Di-methyl-2-vinyloxyethylamine；1-ethenoxy-2-methylpropan-2-amine
• CAS: 86241-96-5
• 化学式: C₆H₁₃NO
• mdl: MFCD19203548
• 分子量: 115.175
• InChiKey: VJMVRFXCVYILRL-UHFFFAOYSA-N

物化性质

• 沸点：
  125 °C
• 密度：
  0.8498 g/cm3(Temp: 25 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  8
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.666
• 拓扑面积：
  35.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,1-dimethyl-2-vinyloxyethylamine 在 三氟乙酸 作用下， 以 氯仿 为溶剂， 反应 72.0h， 生成 N,N′-{ethane-1,1-diylbis[oxy(2-methylpropan-1,2-diyl)]}bis(2,2,2-trifluoroacetamide)
  参考文献：
  名称：

  Acid-catalyzed transformations of N-[(vinyloxy)alkyl]-2,2,2-trifluoroacetamides. Synthesis of N-unsubstituted amino acetals

  摘要：

  DOI：

  10.1134/s107042801507026x
• 作为产物：
  描述：

  2-氨基-2-甲基-1-丙醇 、 乙炔 在 alkali 作用下， 生成 1,1-dimethyl-2-vinyloxyethylamine
  参考文献：
  名称：

  Olefinic Derivatives of 2,4-Diamino-s-triazines

  摘要：

  DOI：

  10.1021/jo01101a026

文献信息

• [EN] POLYMERIZABLE COMPOSITION COMPRISING AN OXIME SULFONATE AS THERMAL CURING AGENT<br/>[FR] COMPOSITION POLYMÉRISABLE COMPRENANT UN SULFONATE D'OXIME EN TANT QU'AGENT DE DURCISSEMENT THERMIQUE
  申请人：BASF SE

  公开号：WO2012101245A1

  公开（公告）日：2012-08-02

  The present invention relates to a polymerizable composition comprising at least one ethylenically unsaturated, polymerizable compound and at least one oxime sulfonate compound of the formula (I) QAaBbCc where a is 0, 1, 2, 3, 4 or 6, b is 0, 1, 2, 3, 4 or 6, and c is 0, 1, 2, 3, 4 or 6, where the sum of a + b + c is 1, 2, 3, 4 or 6 where (A) is a group (B) is a group (C) is a group where # denotes the point of attachment to Q; X is S or NR14 and Q, R1, R2, R3 and R14 are as defined in claim 1 and in the description. The present invention also relates to the use of the this composition, to novel oxime sulfonates and the use of the oxime sulfonates as thermal curing promoter.

  本发明涉及一种可聚合的组成，包括至少一种乙炔基不饱和的可聚合化合物和至少一种具有公式（I）QAaBbCc的亚硝基亚磺酸酯化合物，其中a为0、1、2、3、4或6，b为0、1、2、3、4或6，c为0、1、2、3、4或6，其中a+b+c的总和为1、2、3、4或6，其中（A）是一个基团，（B）是一个基团，（C）是一个基团，其中#表示与Q连接的点；X是S或NR14，Q、R1、R2、R3和R14如权利要求1和说明书中所定义。本发明还涉及使用这种组成物，新型亚硝基亚磺酸酯及其作为热固化促进剂的应用。
• Unsaturated ureido ethers and polymers thereof
  申请人：ROHM &

  公开号：US02734891A1

  公开（公告）日：1956-02-14

  Compounds of formula CH2=C(R)COO-A-NH-CO-NH2 wherein R is hydrogen or a methyl group and A represents a saturated, divalent, aliphatic or cycloaliphatic hydrocarbon group, may be polymerized or copolymerized with compounds containing at least one vinylidene group. A is preferably an alkylene group containing 2-14 carbon atoms, e.g. an ethylene, propylene or trimethylene group. The polymerization can be carried out in bulk or in solution or emulsion, and may be accelerated by the use of heat, ultraviolet light and free-radical catalysts, e.g. a : a1 - bis - azoisobutyronitrile, methyl azoisobutyrate, ascaridol, tertiary-butyl and cumene hydroperoxides, benzoyl, acetyl, lauroyl, ditertiary-butyl and stearyl peroxides, tertiary-butyl perbenzoate and "per salts" such as ammonium persulphate and ammonium perborate. Specified vinylidene compounds are N-dialkyl acrylamides, e.g. dimethyl and diethyl acrylamide; esters of acrylic, methacrylic and a-chloroacrylic acids, e.g. methyl, ethyl, butyl, octyl and 2-ethylhexyl acrylate, methyl, tertiary-butyl and octyl methacrylate; butyl and lauryl chloroacrylate; vinyl hydrocarbons, e.g. styrene, a-methylstyrene, vinylnaphthalene, vinyltoluene, di- and trivinylbenzene; vinyl and vinylidene chloride; diallyl phthalate and allyl and methallyl esters of saturated aliphatic carboxylic acids, e.g. allyl acetate and methallyl propionate; acrylonitrile and vinylpyridine. Specified ureido esters are b-ureidoethyl acrylate and methacrylate. At least 1 per cent molar and preferably 2-20 per cent of ureido ester is used in the preparation of copolymers. In an example beta-ureidoethyl acrylate and methacrylate are copolymerized with ethyl, butyl and octyl acrylates in an aqueous emulsion containing tert.-octylphenoxypolyethoxyethanol as a dispersing agent and a mixture of ammonium persulphate and sodium hydrosulphite as a catalyst. The copolymer emulsions produced are used in the shrink-proofing of woolen fabric. Specification 759,860 is referred to. ALSO: The invention comprises compounds of formula CH2 = C(R)COO-A-NH-CO-NH2 wherein R represents hydrogen or a methyl group and A represents a saturated, divalent, aliphatic or cycloaliphatic hydrocarbon group preferably containing 2-14 carbon atoms, e.g. ethylene, propylene and trimethylene. The compounds are prepared by reacting ammonia with a isocyanato ester of acrylic or methacrylic acid having the formula CH2 = C(R)COO-A-NCO The reaction is conducted at temperatures of 0-50 DEG C. and preferably in presence of an inert solvent. The examples describe the preparation of b-ureidoethyl acrylate and methacrylate. Specification 759,860 is referred to. ALSO: Woollen fabrics are shrink-proofed by padding them with an aqueous emulsion of a copolymer comprising at least 1 per cent (on a molar basis) of a copolymerized ureido ester of formula:-CH2=C(R)COO-A-NH-CO-NH2 wherein R is hydrogen or a methyl group and A is a saturated, divalent, aliphatic or cycloaliphatic hydrocarbon group, and at most 99 per cent of a copolymerized compound containing a vinyl or vinylidene group, and heating the treated fabric to at least 240 DEG F. Specified vinyl or vinyliden compounds are N-dialkyl acrylamides, e.g. dimethyl and diethyl acrylamide; esters of acrylic, methacrylic and a-chloroacrylic acids, e.g. methyl, ethyl, butyl, octyl or 2 - ethyhexyl acrylate, methyl, tertiary-butyl or octyl methacrylate, or butyl or lauryl chloroacrylate; vinyl hydrocarbons, e.g. styrene, a-methylstyrene, vinylnaphthalene, vinyltoluene or di- and trivinylbenzene; vinyl and vinylidene chloride; diallylphthalate and allyl and methallyl esters of saturated aliphatic carboxylic acids, e.g. allyl acetate or methallyl propionate; acrylonitrile and vinylpyridine. Specified ureido esters are b-ureidoethylacrylate and methacrylate. Specification 759,860 is referred to.

  化学式为CH2=C(R)COO-A-NH-CO-NH2的化合物中，R代表氢或甲基基团，A代表饱和的、二价的、脂肪族或环脂族碳氢化合物基团，可以与含有至少一个亚乙烯基团的化合物进行聚合或共聚合。A最好是含有2-14个碳原子的烷基基团，例如乙烯、丙烯或三甲基烷基基团。聚合可以在块状、溶液或乳液中进行，并可以通过热、紫外线光和自由基催化剂（如双(异丙基)过氧化物、甲基异丙酸异丙酯、阿斯卡里酮、叔丁基和叔丙基过氧化氢、苯甲酰、乙酰、月桂酰、双(叔丁基)过氧化氢和硬脂酰过氧化氢、叔丁基过苯甲酸酯以及铵过硫酸盐和过硼酸铵等“过盐”）来加速。指定的亚乙烯化合物包括N-二烷基丙烯酰胺，例如二甲基和二乙基丙烯酰胺；丙烯酸、甲基丙烯酸和α-氯丙烯酸的酯类，例如甲基、乙基、丁基、辛基和2-乙基己基丙烯酸酯，甲基、叔丁基和辛基甲基丙烯酸酯；丙烯酰氯丁酯和月桂基氯丙烯酸酯；乙烯烃类，例如苯乙烯、α-甲基苯乙烯、乙烯基萘、乙烯基甲苯、二乙烯苯和三乙烯苯；乙烯和亚乙烯氯化物；邻苯二甲酸二烯丙酯和饱和脂肪族羧酸醋酸丙烯酯和丙烯酸甲丙酯的烯丙基和甲基丙基酯，例如烯丙基醋酸酯和甲基丙酸丙酯；丙烯腈和乙烯吡啶。指定的尿素酯是β-尿素乙基丙烯酸酯和甲基丙烯酸酯。在共聚物的制备中至少使用1摩尔百分比，最好是2-20摩尔百分比的尿素酯。在一个示例中，β-尿素乙基丙烯酸酯和甲基丙烯酸酯与乙酸、丁酸和辛酸丙烯酸酯在含有叔辛基苯氧聚乙氧乙醇作为分散剂和一种混合物的水乳液中共聚合，该混合物包含过硫酸铵和亚硫酸氢钠作为催化剂。生产的共聚物乳液用于羊毛织物的防缩处理。参考规范759,860。 此外：该发明包括化学式为CH2 = C(R)COO-A-NH-CO-NH2的化合物，其中R代表氢或甲基基团，A代表饱和的、二价的、脂肪族或环脂族碳氢化合物基团，最好含有2-14个碳原子，例如乙烯、丙烯和三甲基烷基。这些化合物是通过将氨与丙烯酸或甲基丙烯酸的异氰酸酯反应而制备的，其化学式为CH2 = C(R)COO-A-NCO。反应在0-50摄氏度的温度下进行，最好在惰性溶剂的存在下进行。示例描述了β-尿素乙基丙烯酸酯和甲基丙烯酸酯的制备。参考规范759,860。此外：羊毛织物通过用含有至少1％（摩尔基础上）共聚合尿素酯的共聚物的水乳液浸渍，然后将处理后的织物加热至至少240华氏度来防缩。指定的乙烯或亚乙烯化合物包括N-二烷基丙烯酰胺，例如二甲基和二乙基丙烯酰胺；丙烯酸、甲基丙烯酸和α-氯丙烯酸的酯类，例如甲基、乙基、丁基、辛基或2-乙基己基丙烯酸酯，甲基、叔丁基或辛基甲基丙烯酸酯，或丁基或月桂基氯丙烯酸酯；乙烯烃类，例如苯乙烯、α-甲基苯乙烯、乙烯基萘、乙烯基甲苯或二-和三乙烯苯；乙烯和亚乙烯氯化物；邻苯二甲酸二烯丙酯和饱和脂肪族羧酸醋酸丙烯酯和丙烯酸甲丙酯的烯丙基和甲基丙基酯，例如烯丙基醋酸酯或甲基丙酸丙酯；丙烯腈和乙烯吡啶。指定的尿素酯是β-尿素乙基丙烯酸酯和甲基丙烯酸酯。参考规范759,860。
• [EN] OXIME SULFONATE DERIVATIVES<br/>[FR] DÉRIVÉS DE SULFONATE D'OXIME
  申请人：BASF SE

  公开号：WO2016030790A1

  公开（公告）日：2016-03-03

  Oxime sulfonate compounds of the formula (I), wherein R 1 is O(CO)R 4, COOR 5 or CONR 6R 7; n is 1 or 2; R 2 for example is C 1-C 8alkyl, C 3-C 6cycloalkyl or benzyl; R 3 is for example C 1-C 8alkyl, C 3-C 6cycloalkyl, C 1-C 8haloalkyl, C 2-C 8alkenyl, benzyl, phenyl or naphthyl, which optionally are substituted; R 4 is for example C 1-C 8alkyl, C 3-C 6cycloalkyl, C 1-C 8haloalkyl, C 2-C 8alkenyl, benzyl, phenyl or naphthyl, which optionally are substituted; R 5 is for example C 3-C 20alkyl, C 3-C 14cycloalkyl, C 2-C 8alkenyl, C 1-C 12alkyl which is substituted for example by one or more halogen; or R 5 is phenyl or naphthyl, which are unsubstituted; R 6 and R 7 each independently of one another for example are hydrogen, C 1-C 12alkyl, C 1-C 4haloalkyl, phenyl-C 1-C 4alkyl, C 2-C 8alkenyl or C 3-C 6cycloalkyl, phenyl or naphthyl; or R 6 and R 7, together with the N-atom to which they are attached, form a 5- or 6-membered ring; are suitable as thermal radical initiators.

  化合物的氧肟磺酸盐，其化学式为（I），其中R1为O（CO）R4，COOR5或CONR6R7; n为1或2; R2例如为C1-C8烷基，C3-C6环烷基或苄基; R3例如为C1-C8烷基，C3-C6环烷基，C1-C8卤代烷基，C2-C8烯基，苄基，苯基或萘基，可以选择性地被取代; R4例如为C1-C8烷基，C3-C6环烷基，C1-C8卤代烷基，C2-C8烯基，苄基，苯基或萘基，可以选择性地被取代; R5例如为C3-C20烷基，C3-C14环烷基，C2-C8烯基，C1-C12烷基，例如被一个或多个卤素取代; 或者R5是未被取代的苯基或萘基; R6和R7各自独立地例如为氢，C1-C12烷基，C1-C4卤代烷基，苯基-C1-C4烷基，C2-C8烯基或C3-C6环烷基，苯基或萘基; 或者R6和R7与它们所连接的N原子一起形成一个5-或6-成员环; 适用于热引发自由基反应剂。
• Process for continuous controlled alcoholysis of polyvinyl acetate
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0054716A2

  公开（公告）日：1982-06-30

  Improved process for the preparation of partially alcoholyzed polyvinyl acetate having good compositional uniformity comprises rapid premixing of the polyvinyl acetate polymer and base catalyst solutions in a static mixer and carrying out the alcoholysis reaction in an intermeshing, self-wiping, twin-rotor mixer or mixing extruder. The process yields polyvinyl alcohol product having a maximum hot water insoluble fraction of about 1.1% by weight obtained by the proper adjustment of the feed temperature, the shear rate in the premixer, and the catalyst concentration in the catalyst feed solution.

  制备具有良好成分均匀性的部分醇解聚醋酸乙烯酯的改进工艺包括在静态混合器中快速预混合聚醋酸乙烯酯聚合物和基催化剂溶液，并在啮合、自擦拭、双转子混合器或混合挤压机中进行醇解反应。 通过适当调节进料温度、预混合器中的剪切速率和催化剂进料溶液中的催化剂浓度，该工艺可获得最大热水不溶部分约为 1.1%（按重量计）的聚乙烯醇产品。
• (Meth)acrylate ester-based resin composition
  申请人：Nippon Shokubai Co., Ltd.

  公开号：EP1184396A1

  公开（公告）日：2002-03-06

  The present invention provides a novel (meth)acrylate ester-based resin composition which, for example, exhibits various good properties such as weather resistance, heat resistance, water resistance, acid resistance, alkali resistance, warm water resistance, impact resistance, flexibility, processability, adhesion, hardness, and elongation when being used for various uses such as coating agents (e.g. for films, plastics, glass, paper, fibers, leather), pressure sensitive adhesives, and adhesives in addition to various paints (e.g. paints for building exteriors, paints for building materials, paints for metals, paints for plastics, heavy anticorrosive paints, waterproof paints for roofs). This resin composition comprises a (meth)acrylate ester-based polymer and an aqueous medium, wherein the (meth)acrylate ester-based polymer is obtained by a process including the step of polymerizing a monomer component including a polymerizable unsaturated monomer as an essential component wherein the polymerizable unsaturated monomer is a cyclohexylalkyl ester of (meth)acrylic acid wherein the cyclohexyl group may have a substituent, and wherein the (meth)acrylate ester-based polymer is dispersed in the aqueous medium.

  本发明提供了一种新型(甲基)丙烯酸酯基树脂组合物，例如，该组合物在用于各种 用途（如涂层剂（如薄膜、塑料、玻璃、纸张、纤维、皮革）、压敏胶和粘合剂）时， 具有耐候性、耐热性、耐水性、耐酸性、耐碱性、耐温水性、耐冲击性、柔韧性、加工性、附着力、 硬度和伸长率等各种良好性能。例如薄膜、塑料、玻璃、纸张、纤维、皮革）、压敏胶和粘合剂，以及各种涂料（例如建筑外墙涂料、建筑材料涂料、金属涂料、塑料涂料、重防腐涂料、屋顶防水涂料）。这种树脂组合物由(甲基)丙烯酸酯基聚合物和水性介质组成，其中(甲基)丙烯酸酯基聚合物是通过包括以下步骤的工艺获得的：聚合单体组分，包括作为基本组分的可聚合不饱和单体，其中可聚合不饱和单体是(甲基)丙烯酸的环己基烷基酯，其中环己基可具有取代基，(甲基)丙烯酸酯基聚合物分散在水性介质中。