9-乙氧基蒽 | 6487-28-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 中文名称: 9-乙氧基蒽
• 英文名称: 9-ethoxyanthracene
• 英文别名: ethyl-[9]anthryl ether；Aethyl-[9]anthryl-aether；Aethyl-anthranyl-aether；9-Aethoxy-anthracen；9-ethoxy-anthracene；9-Ethoxy-anthracen
• CAS: 6487-28-1
• 化学式: C₁₆H₁₄O
• 分子量: 222.287
• InChiKey: LSOHZXVUUOEOTL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2909309090

反应信息

• 作为反应物：
  描述：

  9-乙氧基蒽 在 氢氧化钾 、 三氯化铁 、 溶剂黄146 作用下， 生成 二蒽酮
  参考文献：
  名称：

  Barnett; Cook; Matthews, Journal of the Chemical Society, 1923, vol. 123, p. 2005

  摘要：

  DOI：
• 作为产物：
  描述：

  蒽酮 、 对甲苯磺酸乙酯 在 氢氧化钾 作用下， 生成 9-乙氧基蒽
  参考文献：
  名称：

  Barnett; Cook; Matthews, Journal of the Chemical Society, 1923, vol. 123, p. 2005

  摘要：

  DOI：

文献信息

• Magnetic substance and magnetic substance manufacturing method
  申请人：IHI Corporation

  公开号：US09779862B2

  公开（公告）日：2017-10-03

  [object] A magnetization technique that enhances magnetic properties of an organic compound is provided without damaging properties of the organic compound or while maintaining the structure of the organic compound. [solution] The present disclosure is a method for manufacturing a magnetic substance composed of crystals of a magnetization target compound and an electron acceptor by combining the magnetization target compound with the electron acceptor; forming a solution by dissolving a mixture of the magnetization target compound and the electron acceptor in a solvent; maintaining the solution in a very low temperature state and allowing the solution to deposit the crystals of the magnetic target compound and the electron acceptor; and separating the crystals from the solvent.

  提供一种增强有机化合物磁性能的磁化技术，而不损害有机化合物的性质或同时保持有机化合物的结构。 本公开是一种制造由磁化目标化合物和电子受体的晶体组成的磁性物质的方法，通过将磁化目标化合物与电子受体结合；在溶剂中溶解磁化目标化合物和电子受体的混合物形成溶液；将溶液保持在非常低的温度状态并允许溶液沉积磁性目标化合物和电子受体的晶体；并将晶体与溶剂分离。
• BORATE-BASED BASE GENERATOR, AND BASE-REACTIVE COMPOSITION COMPRISING SUCH BASE GENERATOR
  申请人：WAKO PURE CHEMICAL INDUSTRIES, LTD.

  公开号：US20160340374A1

  公开（公告）日：2016-11-24

  An object of the present invention is to provide a compound which is capable of attaining a composition having high storage stability without reacting with a base-reactive compound, even in the case of storage for a long period of time in a mixed state with the base-reactive compound, such as an epoxy-based compound, as well as capable of generating a strong base (guanidines, biguanides, phosphazenes or phosphoniums) by irradiation of light (active energy rays) or heating; a base generator comprising the compound; and a base-reactive composition comprising the base generator and the base-reactive compound. The present invention relates to the compound represented by the general formula (A); the base generator comprising the compound; and the base-reactive composition comprising the base generator and the base-reactive compound. (wherein R 1 represents an alkyl group; an arylalkynyl group which may be substituted with a halogen atom, an alkyl group, an alkoxy group, or an alkylthio group; an alkenyl group; a 2-furylethynyl group; a 2-thiophenylethynyl group; or a 2,6-dithianyl group; R 2 to R 4 each independently represent an alkyl group; an arylalkynyl group which may be substituted with a halogen atom, an alkyl group, an alkoxy group, or an alkylthio group; the aryl group which may be substituted with a halogen atom, an alkyl group, an alkoxy group, or an alkylthio group; a furanyl group; a thienyl group; or an N-alkyl-substituted pyrrolyl group; Z + represents an ammonium cation having a guanidinium group, a biguanidium group or a phosphazenium group, or a phosphonium cation.)

  本发明的目的是提供一种化合物，能够在与碱反应性化合物混合状态长时间存储的情况下，仍能获得具有高储存稳定性的组合物，而不与碱反应性化合物发生反应，同时还能通过光照（活性能量射线）或加热产生强碱（胍胺、双胍胺、磷氮烷或磷銨）；包括该化合物的碱发生器；以及包括该碱发生器和碱反应性化合物的碱反应性组合物。本发明涉及由通式（A）表示的化合物；包括该化合物的碱发生器；以及包括该碱发生器和碱反应性化合物的碱反应性组合物。（其中R1代表烷基；可能被卤素原子、烷基、烷氧基或烷硫基取代的芳基炔基；烯基；2-呋喃基炔基；2-噻吩基炔基；或2,6-二硫基基；R2到R4各自独立地代表烷基；可能被卤素原子、烷基、烷氧基或烷硫基取代的芳基炔基；可能被卤素原子、烷基、烷氧基或烷硫基取代的芳基；呋喃基；噻吩基；或N-烷基取代的吡咯基；Z+代表具有胍胺基团、双胍胺基团或磷氮烷基团的铵阳离子，或磷銨阳离子。）
• Synthesis of 9-Anthryl Ethers from trans-9,10-Dihydro-9,10-dimethoxy­anthracene by Acid-Catalyzed Transetherification
  作者：Dae Chi、Keun Jang、Hee Shin

  DOI：10.1055/s-0028-1088073

  日期：2009.5

  Ar) to anthracene, anthryl ethers at the C9-position of anthracene were obtained as the major products when trans-9,10-dihydro-9,10-dimethoxyanthracene was reacted (10 minutes at 75 ˚C) with various alcohols. 9-Anthryl ethers with primary, secondary, cyclic alcohols, and polyethylene glycol (PEG) were isolated in 47-73% yields under optimized conditions. It is hoped that the devised method offers a

  在对蒽的亲电芳族加成反应（Ad E Ar）的研究中，当反式-9,10-二氢-9,10-二甲氧基蒽反应（10分钟）时，蒽C9位的蒽醚是主要产物。在75℃下）与各种酒精混合。在优化的条件下，以47-73％的收率分离出带有伯，仲，环状醇和聚乙二醇（PEG）的9-蒽醚。希望所设计的方法为通过将反式-9，10-二氢-9，10-二甲氧基蒽与各种醇进行酸催化的反式醚化提供一种新的合成路线来制备蒽醚。 互醚化-蒽醚-反式-9,10-二氢-9,10-二甲氧基蒽
• SULFONIUM SALT, HEAT- OR PHOTO-ACID GENERATOR, HEAT- OR PHOTO-CURABLE COMPOSITION, AND CURED PRODUCT THEREOF
  申请人：SAN APRO LTD.

  公开号：US20190284134A1

  公开（公告）日：2019-09-19

  The sulfonium salt does not contain a toxic metal and exhibits higher cationic polymerization performance and crosslinking performance than a tetrakis(pentafluorophenyl)borate salt. The heat- or photo-acid generator contains the sulfonium salt. The sulfonium salt is formed of a sulfonium cation selected from a group represented by general formulas (1), (9), (10) and (11) described below and a gallate anion represented by formula (a). The heat- or photo-acid generator contains the sulfonium salt. The heat- or energy ray-curable composition contains the acid generator and a cationically polymerizable compound. A cured product can be obtained by curing the same.

  硫铵盐不含有毒金属，表现出比四(五氟苯基)硼酸盐更高的阳离子聚合性能和交联性能。热或光酸发生剂含有硫铵盐。硫铵盐由下面描述的通用公式(1)、(9)、(10)和(11)所代表的一组硫铵阳离子和由公式(a)代表的镓酸根阴离子形成。热或光酸发生剂含有硫铵盐。热或能量射线固化组合物含有酸发生剂和阳离子聚合性化合物。通过固化可以获得固化产品。
• Base Multiplying Agents and Base-Reactive Curable Compositions
  申请人：Aoki Kenichi

  公开号：US20080200580A1

  公开（公告）日：2008-08-21

  To provide such a base multiplying agent capable of being used for crosslinking reaction, for example of a epoxy compound and the like, that generates another base by action of a base, and can efficiently perform base multiplying reaction, and a base-reactive curable composition using the base multiplying agent. The base generating agent of the invention is represented by the following formula (1): (In the formula (1), X represents a hydrogen atom, a substituted alkyl group or an unsubstituted alkyl group; Y represents a substituted or unsubstituted alkylene chain; and n represents an integer of from 1 to 4.)

  为了提供这样一种基数倍增剂，它能够用于交联反应，例如环氧化合物等，通过碱的作用产生另一种基数，并能够高效地进行基数倍增反应，以及使用该基数倍增剂的基反应固化组合物。该发明的基数生成剂由以下式（1）表示：（在式（1）中，X代表氢原子、取代烷基或未取代烷基；Y代表取代或未取代亚烷链；n代表1至4的整数。）