5-(butan-3-one)norbornylene | 371148-21-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5-(butan-3-one)norbornylene
• 英文别名: 4-{Bicyclo[2.2.1]hept-5-en-2-yl}butan-2-one；4-(2-bicyclo[2.2.1]hept-5-enyl)butan-2-one
• CAS: 371148-21-9
• 化学式: C₁₁H₁₆O
• 分子量: 164.247
• InChiKey: HINVNHPVUMDHHV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  吡咯 、 5-(butan-3-one)norbornylene 在 三氟乙酸 作用下， 反应 14.0h， 生成 5-methyl-5-(5-ethylenebicyclo[2.2.1]hept-2-ene)dipyrrolylmethane
  参考文献：
  名称：

  Imminoamines and preparation thereof

  摘要：

  描述了一种生产一种或多种取代亚胺胺的方法，特别是β-不饱和β-亚胺胺的方法，在单一反应中，通过在过渡金属催化复合物存在下，反应一种或多种初级胺、炔烃和异氰酸酯，所述过渡金属催化复合物优选为钛金属催化复合物，如(N,N-二(吡咯基-α-甲基)-N-甲基胺基)钛(Ti(NMe2)2(dpma))，在有效的反应条件下，使得初级胺、炔烃和异氰酸酯3组分偶联反应，生成一种或多种取代亚胺胺。

  公开号：

  US20040110983A1

文献信息

• DIAZIRINE COMPOUNDS AND COMPOSITIONS DERIVED THEREFROM
  申请人：PROMERUS, LLC

  公开号：US20160083352A1

  公开（公告）日：2016-03-24

  A series of diazirine compounds of formula (I) having utility as photocrosslinkers are disclosed. Where, A, L, z, Ar x and R y are as defined herein. Also disclosed are the photodefinable compositions containing these compounds.

  揭示了一系列具有光交联剂作用的二氮烯化合物的化学式（I），其中A、L、z、Arx和Ry的定义如本文所述。还揭示了含有这些化合物的光可定义组合物。
• Novel ester compounds having alicyclic structure and method for preparing same
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：US20010051742A1

  公开（公告）日：2001-12-13

  Ester compounds of formula (1) are useful as monomers to form base resins for use in chemically amplified resist compositions adapted for micropatterning lithography. 1 R 1 is H or C 1-6 alkyl, R 2 is an unsubstituted or halo-substituted acyl or alkoxycarbonyl group of 1-15 carbon atoms, R 3 is an acid labile group, k is 0 or 1, and m is an integer from 0 to 5.

  式（1）的酯化合物是有用的单体，可形成基础树脂，用于化学增强的抗蚀剂组合物，适用于微图案化学制图。其中，1R1为氢或C1-6烷基，R2为未取代或卤代的1-15个碳原子的酰基或烷氧羰基基团，R3为酸敏感基团，k为0或1，m为0至5的整数。
• Acetal compound, polymer, resist composition and patterning response
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：US20020132970A1

  公开（公告）日：2002-09-19

  Acetal compounds in which a 5- or 6-membered ring acetal structure is connected to a norbornene structure through a linker represented by —(CH 2 ) m — in which one hydrogen atom may be substituted with a hydroxyl or acetoxy group, and m is from 1 to 8 are novel. Using the acetal compounds as a monomer, polymers are obtained. A resist composition comprising the polymer as a base resin is sensitive to high-energy radiation and has excellent sensitivity, resolution, and etching resistance.

  新颖的乙缩醛化合物，其中5-或6-成员环乙缩醛结构通过一个连接基团（表示为—（CH2）m—，其中一个氢原子可以被羟基或乙酰氧基取代，m为1至8）连接到诺博烯结构上。使用乙缩醛化合物作为单体，可以获得聚合物。以该聚合物为基础树脂的抗蚀剂组合物对高能辐射具有敏感性，并具有优异的敏感性、分辨率和蚀刻抗性。
• Ester compounds having alicyclic structure, and methods for preparing the same
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP1149826A2

  公开（公告）日：2001-10-31

  Ester compounds of formula (1) are useful as monomers to form base resins for use in chemically amplified resist compositions adapted for micropatterning lithography. R1 is H or C1-6 alkyl, R2 is an unsubstituted or halo-substituted acyl or alkoxycarbonyl group of 1-15 carbon atoms, R3 is an acid labile group, k is 0 or 1, and m is an integer from 0 to 5.

  式（1）的酯类化合物可作为单体形成基底树脂，用于微图案光刻的化学放大抗蚀剂组合物。 R1 是 H 或 C1-6 烷基，R2 是未取代或卤代取代的酰基或 1-15 个碳原子的烷氧羰基，R3 是易酸基团，k 是 0 或 1，m 是 0 至 5 的整数。
• Polar group-containing olefin copolymer, process for preparing the same, thermoplastic resin composition containing the copolymer, and uses thereof
  申请人：Imuta Junichi

  公开号：US20090137757A1

  公开（公告）日：2009-05-28

  A polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a process for preparing the copolymer, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit derived from an □-olefin of 2 to 20 carbon atoms, and a constituent unit derived from a straight-chain, branched or cyclic polar group-containing monomer having at the end a polar group such as a hydroxyl group or an epoxy group and/or a constituent unit derived from a macromonomer having at the end a polymer segment obtained by anionic polymerization, ring-opening polymerization or polycondensation. The polar group-containing olefin copolymer can be prepared by polymerizing the α-olefin with the polar group-containing monomer and/or the macromonomer in the presence of a metallocene catalyst. The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.