(Z)-4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-2-iodo-non-2-en-1-ol | 99325-08-3

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代醇
• 英文名称: (Z)-4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-2-iodo-non-2-en-1-ol
• 英文别名: (Z)-4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-2-iodonon-2-en-1-ol
• CAS: 99325-08-3
• 化学式: C₉H₄F₁₃IO
• 分子量: 502.014
• InChiKey: HUIAECWNXSPFSH-IWQZZHSRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  24
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  14

反应信息

• 作为产物：
  描述：

  全氟己基碘烷 、 2-丙炔-1-醇 在 锌 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 生成 4,4,5,5,6,6,7,7,8,8,9,9,9-Tridecafluoro-2-iodo-2-nonen-1-ol 、 (Z)-4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-2-iodo-non-2-en-1-ol
  参考文献：
  名称：

  Stereoselective Synthesis of (Z)-Perfluoroalkyl-1-iodo-1-triisopropyl Silylalkenes: A Convenient Route to Perfluoroalkyl-Substituted Unsaturated Synthons

  摘要：

  The quantitative and fully stereoselective synthesis of (Z)-perfluoroalkyl-1-iodo-1-triisopropylsilylalkenes and their easy, high-yielding transformation into the corresponding 1-iodo-2-perfluoroacetylenes and (Z)-2-perfluoroalkyl-1-iodo-1-alkenes, compounds of interest as synthons for classical organometallic chemistry or for metal-catalyzed coupling reactions, are discussed.

  DOI：

  10.1080/00397910903161843

文献信息

• Stereoselective Synthesis of (<i>Z</i>)-Perfluoroalkyl-1-iodo-1-triisopropyl Silylalkenes: A Convenient Route to Perfluoroalkyl-Substituted Unsaturated Synthons
  作者：Juan Francisco Chesa、Dolores Velasco、Francisco López-Calahorra

  DOI：10.1080/00397910903161843

  日期：2010.5.19

  The quantitative and fully stereoselective synthesis of (Z)-perfluoroalkyl-1-iodo-1-triisopropylsilylalkenes and their easy, high-yielding transformation into the corresponding 1-iodo-2-perfluoroacetylenes and (Z)-2-perfluoroalkyl-1-iodo-1-alkenes, compounds of interest as synthons for classical organometallic chemistry or for metal-catalyzed coupling reactions, are discussed.