1,3-dioctylimidazolium iodide | 270908-51-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1,3-dioctylimidazolium iodide
• 英文别名: 1,2-di-n-octylimidazolium iodide；1,3-di-n-octylimidazolium iodide；1,3-Dioctylimidazol-1-ium;iodide
• CAS: 270908-51-5
• 化学式: C₁₉H₃₇N₂*I
• 分子量: 420.421
• InChiKey: FXJMBXFCCFVKKI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  22
• 可旋转键数：
  14
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.84
• 拓扑面积：
  8.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  palladium diacetate 、 1,3-dioctylimidazolium iodide 以 四氢呋喃 为溶剂， 以85%的产率得到bis(1,3-dioctylimidazol-2-ylidene)diiodopalladium(II)
  参考文献：
  名称：

  Fluoroalkylated N-heterocyclic carbene complexes of palladium

  摘要：

  Fluoroalkylated N-heterocyclic carbene complexes of palladium have been synthesized from imidazolium salts and Pd(OAc)(2). The analogous carbene complexes bearing long alkyl chains have also been prepared. The formation of these carbene complexes proceeds via an intermediate binuclear species, which has been isolated. Complexes such as these may find applications in catalysis in supercritical CO2 (scCO(2)). (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00008-5
• 作为产物：
  描述：

  咪唑 、 1-碘辛烷 在 四丁基溴化铵 、 sodium hydroxide 作用下， 以 水 为溶剂， 反应 49.0h， 以90%的产率得到1,3-dioctylimidazolium iodide
  参考文献：
  名称：

  （η6-芳烃）钌（N-杂环卡宾）配合物用于芳基吡啶的螯合辅助的芳构化和氘代反应：催化研究和机理研究

  摘要：

  一系列的（η 6 -arene）钌配合物在芳基吡啶的芳基化了测试。酮（η 6 - p -cymene）钌（N-杂环卡宾）复合物（标记为1的文本）被发现是最有效的，能够芳基化的宽组基本上不同的芳基吡啶的的。复合物1还能够通过氮导向机制促进一系列芳基化N杂环的区域选择性氘化。氘代胺中的两种用于测量芳基化过程中的动力学同位素效应（KIE）。逆KIE的检测，与观察到的C一起H活化过程不需要添加碱，表明芳构化过程中的限速步骤可能与先前报道的研究不同。

  DOI：

  10.1002/adsc.201000049

文献信息

• Artificial Enzymes with Thiazolium and Imidazolium Coenzyme Mimics
  作者：Huanyu Zhao、Frank W. Foss、Ronald Breslow

  DOI：10.1021/ja804577q

  日期：2008.9.24

  Hydrophobic thiazolium and imidazolium coenzyme mimics in the presence of modified-polyethylenimine enzyme mimics catalyze the benzoin condensation 2300-3300 times faster than the coenzyme mimics alone. Polycationic enzyme mimics provide not only a hydrophobic binding domain for coenzyme and substrate, but also electrostatic stabilization of anionic species that arise along the reaction pathway of

  在改性聚乙烯亚胺酶模拟物存在下，疏水性噻唑鎓和咪唑鎓辅酶模拟物催化安息香缩合反应比单独的辅酶模拟物快 2300-3300 倍。聚阳离子酶模拟物不仅为辅酶和底物提供疏水结合域，而且还为沿安息香缩合反应途径产生的阴离子物质提供静电稳定。
• Absorption cycle utilizing ionic liquid as working fluid
  申请人：Shiflett Brandon Mark

  公开号：US20060197053A1

  公开（公告）日：2006-09-07

  The present invention relates to an absorption cycle comprising a refrigerant pair comprising at least one refrigerant and at least one ionic liquid. The present invention also provides an absorption cycle that utilizes fluorocarbon gases in fluorinated ionic liquids. The present invention also provides a method of cooling using an absorption cycle comprising a refrigerant pair comprising at least one refrigerant and at least one ionic liquid. The present invention also provides a method of heating using an absorption cycle comprising a refrigerant pair comprising at least one refrigerant and at least one ionic liquid.

  本发明涉及一种吸收循环，包括制冷剂对，其中制冷剂对包括至少一种制冷剂和至少一种离子液体。本发明还提供了一种利用氟碳气体在氟化离子液体中的吸收循环。本发明还提供了一种利用制冷剂对包括至少一种制冷剂和至少一种离子液体的吸收循环进行冷却的方法。本发明还提供了一种利用制冷剂对包括至少一种制冷剂和至少一种离子液体的吸收循环进行加热的方法。
• Utilizing ionic liquids for hydrofluorocarbon separation
  申请人：Shiflett B. Mark

  公开号：US20070131535A1

  公开（公告）日：2007-06-14

  The present invention relates to a process for separating close-boiling and azeotropic components of mixtures, wherein said mixtures comprise at least one hydrofluorocarbon compound, using at least one ionic liquid.

  本发明涉及一种用至少一种离子液体分离混合物中接近沸点和共沸成分的方法，所述混合物包括至少一种氢氟碳化合物。
• Hybrid vapor compression-absorption cycle
  申请人：Shiflett Brandon Mark

  公开号：US20070019708A1

  公开（公告）日：2007-01-25

  The present invention relates to a hybrid vapor compression-absorption cooling or heating system and apparatus containing a refrigerant pair comprising at least one refrigerant and at least one ionic liquid. The present invention also provides for the performance of a hybrid vapor compression-absorption cycle that utilizes refrigerants and absorbents such as fluorocarbon gases in fluorinated ionic liquids. The present invention also provides a method of cooling by the execution of a hybrid vapor compression-absorption cycle using a refrigerant pair comprising at least one refrigerant and at least one ionic liquid. The present invention also provides a method of heating by the execution of a hybrid vapor compression-absorption cycle using a refrigerant pair comprising at least one refrigerant and at least one ionic liquid.

  本发明涉及一种混合蒸汽压缩-吸收制冷或加热系统和装置，其中包含至少一种制冷剂和至少一种离子液体组成的制冷剂对。本发明还提供了一种利用制冷剂和吸收剂（例如氟碳气体）在氟化离子液体中执行混合蒸汽压缩-吸收循环的方法。本发明还提供了一种通过执行使用至少一种制冷剂和至少一种离子液体组成的制冷剂对的混合蒸汽压缩-吸收循环来进行制冷的方法。本发明还提供了一种通过执行使用至少一种制冷剂和至少一种离子液体组成的制冷剂对的混合蒸汽压缩-吸收循环来进行加热的方法。
• Vapor Compression Cycle Utilizing Ionic Liquid as Compressor Lubricant
  申请人：Shiflett Brandon Mark

  公开号：US20070295478A1

  公开（公告）日：2007-12-27

  This invention relates to the use of ionic liquids as lubricants in vapor compression systems for cooling or heating. This invention also relates to an apparatus for adjusting temperature that operates a vapor compression cycle.

  本发明涉及在用于制冷或加热的蒸汽压缩系统中使用离子液体作为润滑剂。本发明还涉及一种用于调节温度的设备，该设备操作蒸汽压缩循环。