3,6-bis(2-(3,4-ethlyenedioxy)thienyl)-N-methylcarbazole | 177215-53-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 3,6-bis(2-(3,4-ethlyenedioxy)thienyl)-N-methylcarbazole
• 英文别名: 3,6-bis(2-(3,4-ethylenedioxy)thienyl)-N-methylcarbazole；3,6-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-9-methylcarbazole
• CAS: 177215-53-1
• 化学式: C₂₅H₁₉NO₄S₂
• 分子量: 461.562
• InChiKey: CXBGQZLCPSKFGZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  32
• 可旋转键数：
  2
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  98.3
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  3,6-二溴咔唑 在 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) lithium hydride 作用下， 以 四氢呋喃 、 N,N-二甲基甲酰胺 为溶剂， 反应 12.0h， 生成 3,6-bis(2-(3,4-ethlyenedioxy)thienyl)-N-methylcarbazole
  参考文献：
  名称：

  Muticoloured electrochromic polymers derived from easily oxidized bis[2-(3,4-ethylenedioxy)thienyl]carbazoles

  摘要：

  通过高共轭、低氧化电位单体的电聚合，合成了两种双[2-(3,4-亚乙二氧基)噻吩基]咔唑基聚合物；这些聚合物表现出多色电致变色特性，每种聚合物都具有三种独立的可访问状态。

  DOI：

  10.1039/cc9960001777

文献信息

• MONOMER OF THE "PUSH-PULL" TYPE AND PHOTOCHROMIC ELECTROCONDUCTING POLYMER MATERIAL OBTAINED FROM THIS MONOMER
  申请人：Fabre-Francke Isabelle

  公开号：US20080146816A1

  公开（公告）日：2008-06-19

  The invention relates to a “push-pull” type compound, used for manufacturing polymer materials having both electrical conduction and photochromic properties, which responds to the general formula A-X-R in which: A is an electron acceptor group; X is a group having a π-conjugated system and forms a photochromic group with A; and R is a polymerizable electron-donor group that is chosen among the carbazole group and the groups derived from the carbazole group by substitution, and which is linked to X by the nitrogen atom of the carbazole group. The invention also relates to an electroconducting and photochromic polymer material, obtained by polymerization of this compound. Applications: optoelectronics, signal processing, data storage, etc.

  该发明涉及一种“推拉”型化合物，用于制造具有电导和光致变色性能的聚合物材料，其响应于一般公式A-X-R，其中：A是一个电子受体基团；X是一个具有π-共轭系统并与A形成光致变色基团的基团；R是一种可聚合的电子给体基团，选择自咔唑基团和咔唑基团的取代物，并且通过咔唑基团的氮原子与X相连。该发明还涉及一种通过该化合物的聚合获得的具有电导和光致变色性能的聚合物材料。应用领域：光电子学、信号处理、数据存储等。
• Electrochromic polymers and polymer electrochromic devices
  申请人：University of Florida

  公开号：US20030174377A1

  公开（公告）日：2003-09-18

  The subject invention pertains to electrochromic polymers and polymer electrochromic devices. In a specific embodiment, two complementary polymers can be matched and incorporated into dual polymer electrochromic devices. The anodically coloring polymers in accordance with the subject invention can allow control over the color, brightness, and environmental stability of an electrochromic window. In addition, high device contrast ratios, high transmittance changes, and high luminance changes can be achieved, along with half-second switching times for full color change. Also provided are electrochromic devices such as advertising signage, video monitors, stadium scoreboards, computers, announcement boards, warning systems for cell phones, warning/information systems for automobiles, greeting cards, electrochromic windows, billboards, electronic books, and electrical wiring. The subject invention also provides for the use of complementary electrochromic polymers in the manufacture of electrochromic devices. In some embodiments, the devices of the invention can be prepared using metal vapor deposition or line patterning.

  本发明涉及电致变色聚合物和聚合物电致变色器件。在一个特定的实施例中，可以将两种互补的聚合物配对并纳入双聚合物电致变色器件中。根据本发明的阳极着色聚合物可以允许控制电致变色窗户的颜色、亮度和环境稳定性。此外，可以实现高对比度比、高透射率变化和高亮度变化，以及半秒钟的全彩色变换时间。还提供了电致变色器件，例如广告标志、视频监视器、体育场记分牌、计算机、公告牌、手机警告系统、汽车警告/信息系统、贺卡、电致变色窗户、广告牌、电子书和电气布线。本发明还提供了在制造电致变色器件时使用互补电致变色聚合物的方法。在一些实施例中，可以使用金属蒸汽沉积或线路图案制备本发明的器件。
• ELECTROCHROMIC POLYMERS AND POLYMER ELECTROCHROMIC DEVICES
  申请人：University of Florida

  公开号：EP1465962A1

  公开（公告）日：2004-10-13
• FORMATION OF CONJUGATED POLYMERS FOR SOLID-STATE DEVICES
  申请人：University of Connecticut

  公开号：EP2550557A2

  公开（公告）日：2013-01-30
• ELECTROCHROMIC DEVICES PREPARED FROM THE IN SITU FORMATION OF CONJUGATED POLYMERS
  申请人：Sotzing Gregory Allen

  公开号：US20130235323A1

  公开（公告）日：2013-09-12

  Disclosed herein are electrochromic devices, including eyewear, windows, and displays, prepared by in situ formation of conjugated polymers.