Tripropylene | 13987-01-4

• 物质功能分类: 催化剂及助剂 - 聚合物
• 分子结构分类: 有机化合物 - 碳氢化合物 - 饱和烃
• 英文名称: Tripropylene
• 英文别名: 2,3-dimethylheptane;2,4-dimethylheptane;2,3,5-trimethylhexane
• CAS: 13987-01-4
• 化学式: C27H60
• 分子量: 384.8
• InChiKey: PCINYZCOJRSWJK-UHFFFAOYSA-N

物化性质

• 熔点：
  -93.4°C
• 沸点：
  446.37°C (rough estimate)
• 密度：
  0.7908 (estimate)
• 物理描述：
  Tripropylene appears as a clear colorless liquid with a sharp odor. Insoluble in water and less dense than water. Hence floats on water. May irritate skin on contact. Vapors heavier than air. Inhalation of vapors may cause irritation. Prolonged inhalation may lead to breathing difficulty. Ingestion causes abdominal discomfort, nausea and diarrhea. Used to make other chemicals and as a lubricating oil additive.
• 闪点：
  75 °F (USCG, 1999)

计算性质

• 辛醇/水分配系数(LogP)：
  10.26
• 重原子数：
  27
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  异丙苯酚 、 Tripropylene 、 反应 7.0h， 以gave 2-isopropyl-4-nonylphenol (239.4 g, 96.4% purity by GC area %) in 46% yield的产率得到2-Isopropyl-4-nonylphenol
  参考文献：
  名称：

  Method for separating copper from iron

  摘要：

  在含有溶解的铜和铁价值的水性原料溶液中，通过将原料溶液与由烃溶剂和化合物I1组成的水不相溶的有机溶液接触，可以更优先地从铁中提取铜。其中，R5是C1-22线性或支链烷基、C2-22线性或支链烯基、C6芳基、C7-22芳基烷基、卤素、OH或—OR6，其中R6是C1-22线性或支链烷基、C2-22线性或支链烯基、C6芳基、C7-22芳基烷基；R1是氢，或C1-22线性或支链烷基或烯基、C6芳基或C7-22芳基烷基；R2-R4是氢、卤素、线性或支链C6-12烷基、—OR6，其中R6是C1-22线性或支链烷基、C2-22线性或支链烯基、C6芳基或C7-22芳基烷基，以形成由铁组成的水相和由烃溶剂和铜萃取剂复合物组成的有机相，其中铜萃取剂复合物在烃溶剂中可溶。选择R2-R5基团，以使铜萃取剂复合物在烃溶剂中可溶。在萃取阶段完成并且有机相和水相分离后，有机相基本上不含铁和/或铁萃取剂复合物。

  公开号：

  US20010055553A1
• 作为试剂：
  描述：

  1,1,3,3-四甲基茚满-5-醇 、 Tripropylene 、 氢氧化钙 在 lime 、 Tripropylene 、 水 作用下， 以 水 为溶剂， 反应 2.5h， 生成 6-异壬基-1,1,3,3-四甲基-5-茚醇
  参考文献：
  名称：

  Color photographic material containing a hydroxyindane

  摘要：

  提供一种彩色摄影记录材料，其中包含至少一种染料图像或用于生产染料图像的色偶合剂，并且该材料至少在一层亲水性层中含有下文所定义的羟基茚吲酮，以减少图像染料在暴露于紫外线或可见光时的褪色。

  公开号：

  US04052216A1

文献信息

• Method for separating copper from iron
  申请人：——

  公开号：US20010055553A1

  公开（公告）日：2001-12-27

  Copper is preferentially extracted from iron in an aqueous feedstock solution containing dissolved copper and iron values by contacting the feedstock solution with a water-immiscible organic solution comprised of a hydrocarbon solvent and a compound of the formula I 1 wherein R 5 is a C 1-22 linear or branched alkyl group, a C 2-22 linear or branched alkenyl group, a C 6 aryl group, a C 7-22 aralkyl group, a halogen, OH or —OR 6 wherein R 6 is a C 1-22 linear or branched alkyl group, a C 2-22 linear or branched alkenyl group, a C 6 aryl group, a C 7-22 aralkyl group; R 1 is hydrogen, or a C 1-22 linear or branched alkyl or alkenyl group, a C 6 aryl group or a C 7-22 aralkyl group; R 2 -R 4 is hydrogen, halogen, a linear or branched C 6-12 alkyl group, —OR 6 wherein R 6 is a C 1-22 linear or branched alkyl group, a C 2-22 linear or branched alkenyl group, a C 6 aryl group, or a C 7-22 aralkyl group to form an aqueous phase comprised of iron and an organic phase comprised of the hydrocarbon solvent and a copper-extractant complex wherein the copper-extractant complex is soluble in the hydrocarbon solvent. The R 2 -R 5 groups are chosen so that the copper-extractant complex is soluble in the hydrocarbon solvent. After the extraction stage is completed and the organic and aqueous phases separate, the organic phase is substantially free of iron and/or an iron-extractant complex.

  在含有溶解的铜和铁价值的水性原料溶液中，通过将原料溶液与由烃溶剂和化合物I1组成的水不相溶的有机溶液接触，可以更优先地从铁中提取铜。其中，R5是C1-22线性或支链烷基、C2-22线性或支链烯基、C6芳基、C7-22芳基烷基、卤素、OH或—OR6，其中R6是C1-22线性或支链烷基、C2-22线性或支链烯基、C6芳基、C7-22芳基烷基；R1是氢，或C1-22线性或支链烷基或烯基、C6芳基或C7-22芳基烷基；R2-R4是氢、卤素、线性或支链C6-12烷基、—OR6，其中R6是C1-22线性或支链烷基、C2-22线性或支链烯基、C6芳基或C7-22芳基烷基，以形成由铁组成的水相和由烃溶剂和铜萃取剂复合物组成的有机相，其中铜萃取剂复合物在烃溶剂中可溶。选择R2-R5基团，以使铜萃取剂复合物在烃溶剂中可溶。在萃取阶段完成并且有机相和水相分离后，有机相基本上不含铁和/或铁萃取剂复合物。
• Color photographic material containing a hydroxyindane
  申请人：AGFA-Gevaert, A.G.

  公开号：US04052216A1

  公开（公告）日：1977-10-04

  A color photographic recording material is provided containing at least one dye image or a color coupler for the production of a dye image and the material contains in at least one hydrophilic layer a hydroxyindane as defined hereinafter to reduce the fading of the image dye on exposure to UV or visible light.

  提供一种彩色摄影记录材料，其中包含至少一种染料图像或用于生产染料图像的色偶合剂，并且该材料至少在一层亲水性层中含有下文所定义的羟基茚吲酮，以减少图像染料在暴露于紫外线或可见光时的褪色。
• Solvent extraction process
  申请人：Cognis Corporation

  公开号：US06632410B2

  公开（公告）日：2003-10-14

  Copper is preferentially extracted from iron in an aqueous feedstock solution containing dissolved copper and iron values by contacting the feedstock solution with a water-immiscible organic solution comprised of a hydrocarbon solvent and a compound of the formula I wherein R5 is a C1-22 linear or branched alkyl group, a C2-22 linear or branched alkenyl group, a C6 aryl group, a C7-22 aralkyl group, a halogen, OH or —OR6 wherein R6 is a C1-22 linear or branched alkyl group, a C2-22 linear or branched alkenyl group, a C6 aryl group, a C7-22 aralkyl group; R1 is hydrogen, or a C1-22 linear or branched alkyl or alkenyl group, a C6 aryl group or a C7-22 aralkyl group; R2-R4 is hydrogen, halogen, a linear or branched C6-12 alkyl group, —OR6 wherein R6 is a C1-22 linear or branched alkyl group, a C2-22 linear or branched alkenyl group, a C6 aryl group, or a C7-22 aralkyl group to form an aqueous phase comprised of iron and an organic phase comprised of the hydrocarbon solvent and a copper-extractant complex wherein the copper-extractant complex is soluble in the hydrocarbon solvent. The R2-R5 groups are chosen so that the copper-extractant complex is soluble in the hydrocarbon solvent. After the extraction stage is completed and the organic and aqueous phases separate, the organic phase is substantially free of iron and/or an iron-extractant complex.

  在含有溶解铜和铁价值的水性原料溶液中，通过将原料溶液与一个由烃溶剂和公式I的化合物组成的不溶于水的有机溶液接触，可以优先从铁中提取铜。在公式I中，R5是C1-22线性或支链烷基，C2-22线性或支链烯基，C6芳基，C7-22芳基烷基，卤素，OH或-OR6，其中R6是C1-22线性或支链烷基，C2-22线性或支链烯基，C6芳基，C7-22芳基烷基；R1是氢，或C1-22线性或支链烷基或烯基，C6芳基或C7-22芳基烷基；R2-R4是氢，卤素，线性或支链C6-12烷基，-OR6，其中R6是C1-22线性或支链烷基，C2-22线性或支链烯基，C6芳基或C7-22芳基烷基，以形成由铁组成的水相和由烃溶剂和铜萃取剂复合物组成的有机相，其中铜萃取剂复合物在烃溶剂中可溶。R2-R5基团被选择为铜萃取剂复合物在烃溶剂中可溶。在萃取阶段完成并且有机相和水相分离后，有机相基本上不含铁和/或铁萃取剂复合物。