[2,4-二硝基(~13~C_6_)苯基]肼 | 51052-01-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: [2,4-二硝基(~13~C_6_)苯基]肼
• 中文别名: 5,5-二羟基戊醛
• 英文名称: glutaraldehyde monoacetal
• 英文别名: 5,5-Dihydroxyvaleraldehyde；5,5-dihydroxypentanal
• CAS: 51052-01-8
• 化学式: C₅H₁₀O₃
• 分子量: 118.133
• InChiKey: JVWLHJMVGBZOGY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.8
• 重原子数：
  8
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  57.5
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  戊二醛 在 水 作用下， 生成 [2,4-二硝基(~13~C_6_)苯基]肼 、 戊烷-1,1,5,5-四醇
  参考文献：
  名称：

  Temperature dependent near-UV molar absorptivities of glyoxal and gluteraldehyde in aqueous solution

  摘要：

  Molar absorptivities have been determined for glyoxal and gluteraldehyde in aqueous solution. Absorptivities are reported at eight temperatures in the range 5-70 degreesC for wavelengths greater than 200 nm. For glyoxal the data indicate did less than 0.02% of the glyoxal molecules exist in the free dialdehyde form, and that at 25 degreesC approximately 98% of the molecules are hydrated at both carbonyl groups, results that are consistent with previous experiments. For gluteraldehyde hydration of the two carbonyl groups occurs in an independent manner. The following thermodynamic data are found for gluteraldehyde hydration: DeltaH = -35.8 +/- 1.3 kJ mole(-1), DeltaS = 103 +/- 7 J (mole K)(-1), and K = 7.5 +/- 2.0. The results for gluteraldehyde are compared with previous results obtained for the hydration of aliphatic aldehydes. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1386-1425(00)00311-5

文献信息

• Temperature dependent near-UV molar absorptivities of glyoxal and gluteraldehyde in aqueous solution
  作者：Maruful Malik、Jeffrey A. Joens

  DOI：10.1016/s1386-1425(00)00311-5

  日期：2000.12

  Molar absorptivities have been determined for glyoxal and gluteraldehyde in aqueous solution. Absorptivities are reported at eight temperatures in the range 5-70 degreesC for wavelengths greater than 200 nm. For glyoxal the data indicate did less than 0.02% of the glyoxal molecules exist in the free dialdehyde form, and that at 25 degreesC approximately 98% of the molecules are hydrated at both carbonyl groups, results that are consistent with previous experiments. For gluteraldehyde hydration of the two carbonyl groups occurs in an independent manner. The following thermodynamic data are found for gluteraldehyde hydration: DeltaH = -35.8 +/- 1.3 kJ mole(-1), DeltaS = 103 +/- 7 J (mole K)(-1), and K = 7.5 +/- 2.0. The results for gluteraldehyde are compared with previous results obtained for the hydration of aliphatic aldehydes. (C) 2000 Elsevier Science B.V. All rights reserved.