(5-Hydroxymethyl-2-m-tolyl-3H-imidazol-4-yl)-methanol | 61698-34-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: (5-Hydroxymethyl-2-m-tolyl-3H-imidazol-4-yl)-methanol
• 英文别名: [2-(3-Methylphenyl)-1H-imidazole-4,5-diyl]dimethanol；[4-(hydroxymethyl)-2-(3-methylphenyl)-1H-imidazol-5-yl]methanol
• CAS: 61698-34-8
• 化学式: C₁₂H₁₄N₂O₂
• 分子量: 218.255
• InChiKey: MORJXSSLQYWCHC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  69.1
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-m-tolyl-1H-imidazole 、 聚合甲醛 、 potassium carbonate 在 甲醇 作用下， 反应 1.0h， 以to afford 2-m-tolyl-4,5-dihydroxymethyl imidazole as a final product in an amount of 2 g (yield 9%)的产率得到(5-Hydroxymethyl-2-m-tolyl-3H-imidazol-4-yl)-methanol
  参考文献：
  名称：

  Novel imidazole compounds and process for preparations thereof

  摘要：

  一种生产C-甲基醇咪唑的方法，包括将在2位含有芳基的咪唑化合物与甲醛在pH至少为7的反应介质中反应，从而使甲醛加到咪唑环的碳原子上。产物可以是单甲基醇咪唑或双甲基醇咪唑，具体取决于起始咪唑化合物。因此获得的大部分C-甲基醇咪唑都是新化合物。

  公开号：

  US04104473A1

文献信息

• Novel imidazole compounds and process for preparations thereof
  申请人：Shikoku Chemicals Corporation

  公开号：US04104473A1

  公开（公告）日：1978-08-01

  A process for producing C-methylol imidazoles which comprises reacting imidazole compounds containing an aryl group at the 2-position with formaldehyde in a reaction medium having a pH of at least 7 whereby the formaldehyde adds to the carbon atom of the imidazole ring. The products are either monomethylol imidazoles or dimethlol imidazoles depending upon the starting imidazole compounds. Most of the C-methylol imidazoles thus obtained are new compounds.

  一种生产C-甲基醇咪唑的方法，包括将在2位含有芳基的咪唑化合物与甲醛在pH至少为7的反应介质中反应，从而使甲醛加到咪唑环的碳原子上。产物可以是单甲基醇咪唑或双甲基醇咪唑，具体取决于起始咪唑化合物。因此获得的大部分C-甲基醇咪唑都是新化合物。
• HEAT-CURABLE RESIN COMPOSITION, PREPREG, AND METHOD FOR PRODUCING FIBER-REINFORCED COMPOSITE USING EACH OF SAME
  申请人：Toho Tenax Co., Ltd.

  公开号：EP3075785A1

  公开（公告）日：2016-10-05

  The present invention provides a heat-curable resin composition, which comprises (1) a heat-curable resin mixture comprising a heat-curable resin (a) and thickener particles (b) and exhibiting a viscosity (150°C) after having been held at a temperature of 150°C for 30 seconds that is a viscosity (S), and (2) a curing agent, and is characterized in that the heat-curable resin composition exhibits a lowest viscosity (R) at 80-120°C, the lowest viscosity (R) is 0.1-10 Pa·s, and the viscosity (S) and lowest viscosity (R) satisfy the relationship of formula (1): 5 < S/R < 200 ...formula (1).

  本发明提供了一种热固化树脂组合物，它包括(1)热固化树脂混合物，该混合物由热固化树脂(a)和增稠剂颗粒(b)组成，在150℃的温度下保持30秒后表现出粘度(S)，(2)固化剂，其特征在于热固化树脂组合物在80-120℃时表现出最低粘度(R)，最低粘度(R)为0.1-10 Pa-s，粘度 (S) 和最低粘度 (R) 满足式 (1) 的关系：5 < S/R < 200 ......式（1）。
• SELF-ADHESIVE PREPREG AND METHOD FOR PRODUCING SAME
  申请人：Teijin Limited

  公开号：EP3603915A1

  公开（公告）日：2020-02-05

  The present invention provides a self-adhesive prepreg which is characterized by comprising: a base prepreg that is composed of reinforcing fibers and a thermosetting resin composition (I), some or all of which is impregnated into a reinforcing fiber layer that is formed of the reinforcing fibers; an adhesive layer that is composed of a nonwoven fabric which is laminated on at least one surface of the base prepreg so as to be integrated with the base prepreg and a thermosetting resin composition (II) which is laminated on the surface of the nonwoven fabric so as to be integrated with the nonwoven fabric.

  本发明提供了一种自粘预浸料，其特征在于包括基体预浸料，由增强纤维和热固性树脂组合物 (I) 组成，其中部分或全部浸渍在由增强纤维形成的增强纤维层中； 粘合层，由无纺布和热固性树脂组合物 (II) 组成，无纺布层压在基体预浸料的至少一个表面上，以便与基体预浸料融为一体，热固性树脂组合物 (II) 层压在无纺布的表面上，以便与无纺布融为一体。
• MOLDING MATERIAL AND FIBER-REINFORCED COMPOSITE MATERIAL
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3632982A1

  公开（公告）日：2020-04-08

  A molding material that enables acquirement of a fiber-reinforced composite material which has excellent demoldability from a mold and excellent surface appearance, which contaminates a mold surface after molding less, and which has excellent mechanical properties and heat resistance; and a fiber-reinforced composite material which has excellent demoldability from a mold and surface appearance, which contaminates a mold surface after molding less, and which has excellent mechanical properties and heat resistance, are provided. A molding material of the present invention includes a component (A): an epoxy resin; a component (B): an epoxy resin curing agent; a component (C): a compound that has a solubility parameter of 11.2 or less and a melting point of 115°C or lower; and a reinforcement fiber.

  本发明提供了一种成型材料，该材料可获得从模具脱模性和表面外观优异、成型后对模具表面污染少、机械性能和耐热性优异的纤维增强复合材料；以及一种从模具脱模性和表面外观优异、成型后对模具表面污染少、机械性能和耐热性优异的纤维增强复合材料。本发明的一种成型材料包括组分（A）：环氧树脂；组分（B）：环氧树脂固化剂；组分（C）：溶解度参数为 11.2 或以下、熔点为 115°C 或以下的化合物；以及增强纤维。
• CARBON FIBER BUNDLE, PREPREG, AND FIBER-REINFORCED COMPOSITE MATERIAL
  申请人：Teijin Limited

  公开号：EP3719184A1

  公开（公告）日：2020-10-07

  The objective of the present invention is to provide a carbon fiber having an excellent strength development ratio when used in a composite material. The present invention, which resolves this problem, simultaneously satisfies expressions (1) and (2). Lc/d≤3 TS×d×Lc>6.0×105 Lc: X-ray crystallite size (Å) d: single fiber diameter (µm) TS: Strand tensile strength (MPa)

  本发明的目的是提供一种在复合材料中使用时具有优异强度发展比的碳纤维。本发明解决了这一问题，同时满足表达式（1）和（2）。Lc/d≤3 TS×d×Lc>6.0×105 Lc：X 射线晶粒尺寸（埃） d：单纤维直径（微米） TS：股拉伸强度（兆帕）