EGC6SH | 537680-05-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: EGC6SH
• 英文别名: Ethanol, 2-[2-[2-[(6-mercaptohexyl)oxy]ethoxy]ethoxy]-；2-[2-[2-(6-sulfanylhexoxy)ethoxy]ethoxy]ethanol
• CAS: 537680-05-0
• 化学式: C₁₂H₂₆O₄S
• 分子量: 266.402
• InChiKey: ZFHKAEQCLIWJHF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  17
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  48.9
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  在 potassium tert-butylate 作用下， 以 乙醇 为溶剂， 反应 3.0h， 生成 EGC6SH
  参考文献：
  名称：

  Recognition of lectin with a high signal to noise ratio: carbohydrate-tri(ethylene glycol)-alkanethiol co-adsorbed monolayer

  摘要：

  密集排列的双吸附超薄单分子层，由短的三乙二醇硫醇（排斥蛋白质）和麦芽糖终止的硫醇（捕获凝集素）组成，提供了极高的信噪比表面。排斥分子具有两种不同功能（高度柔性的亲水臂和刚性的排列尾部基团），在识别单层中充当“纳米屏障”。

  DOI：

  10.1039/b809481k

文献信息

• Sensor surface
  申请人：Interuniversitaire Microelectronica Centrum vzw ( IMEC)

  公开号：EP1369692A2

  公开（公告）日：2003-12-10

  The present invention is related to a device suitable for the preparation of a sensor, comprising a substrate comprising a metal layer, said metal layer comprising at least a first region wherein to a first region is attached a first species having the chemical formula:         X-R1-S-S-R2-Y wherein R1 and R2 represent independently from each other spacer of n carbon atoms, n being an integer higher than 11; wherein X represents and Y represents an organic group. The first species is able to form a self-asssembling monolayer on said first region.

  本发明涉及一种适用于制备传感器的装置，包括 由金属层组成的基底，所述金属层至少包括第一区域，其中第一区域附着有化学式为 X-R1-S-S-R2-Y 其中 R1 和 R2 各自代表 n 个碳原子的间隔物，n 为大于 11 的整数； 其中 X 代表 和 Y 代表有机基团。第一种物质能够在所述第一区域上形成自组装单层。
• Electronic sensor device
  申请人：Interuniversitair Microelektronica Centrum (IMEC)

  公开号：US20040018532A1

  公开（公告）日：2004-01-29

  The present invention is related to a device suitable for the preparation of a sensor, comprising a substrate comprising a metal layer, the metal layer comprising at least a first region wherein to a first region is attached a first species comprising a compound of chemical formula: X—R 1 —S—S—R 2 —Y wherein R 1 and R 2 represent independently from each other spacer of n carbon atoms, n being an integer higher than 11; wherein X represents: 1 and Y represents an organic group. The first species is able to form a self-assembling monolayer on the first region.

  本发明涉及一种适用于制备传感器的装置，该装置包括一个由金属层组成的基底，金属层至少包括一个第一区域，在第一区域中附着有由化学式为 X-R 1 -S-S-R 2 -Y 其中 R 1 和 R 2 分别代表n个碳原子的间隔物，n为大于11的整数；其中X代表 1 和 Y 代表有机基团。第一种物质能够在第一区域上形成自组装单层。
• Selective Ion Binding Nanomaterials
  申请人：Cho Eun Seon

  公开号：US20120164755A1

  公开（公告）日：2012-06-28

  Nanoparticles with a patterned ligand coat can bind ions selectively. The ligand patterning can arise via self-assembly when two chemically dissimilar (e.g., in size and/or hydrophilicity) ligands are used together. One of the ligands can include one or more moieties capable of interacting with an ion, such as ether oxygens, hydroxyl groups, amine nitrogens, or other groups having a lone pair of electrons. Ion binding can be both selective and reversible.
• [EN] SELECTIVE NANOPARTICLE BASED ION BINDING NANOMATERIALS<br/>[FR] NANOMATÉRIAUX SE LIANT SÉLECTIVEMENT AUX IONS
  申请人：MASSACHUSETTS INST TECHNOLOGY

  公开号：WO2012092304A1

  公开（公告）日：2012-07-05

  Nanoparticles with a patterned ligand coat can bind ions selectively. The ligand patterning can arise via self-assembly when two chemically dissimilar (e.g., in size and/or hydrophilicity) ligands are used together. One of the ligands can include one or more moieties capable of interacting with an ion, such as ether oxygens, hydroxyl groups, amine nitrogens, or other groups having a lone pair of electrons. Ion binding can be both selective and reversible.
• Recognition of lectin with a high signal to noise ratio: carbohydrate-tri(ethylene glycol)-alkanethiol co-adsorbed monolayer
  作者：Yukari Sato、Kyoko Yoshioka、Mutsuo Tanaka、Teiichi Murakami、Miho Neide Ishida、Osamu Niwa

  DOI：10.1039/b809481k

  日期：——

  Densely packed co-adsorbed ultrathin mono molecular layers of short tri(ethylene glycol)-alkanethiolate (for repelling proteins) and maltoside terminated alkanethiolate (for capturing lectin) provided an extremely high signal to noise ratio surface: the repelling molecules, which had two different functions (highly flexible-hydrophilic arm and rigid packing tail group), worked as “nano barriers” in the recognition monolayer.

  密集排列的双吸附超薄单分子层，由短的三乙二醇硫醇（排斥蛋白质）和麦芽糖终止的硫醇（捕获凝集素）组成，提供了极高的信噪比表面。排斥分子具有两种不同功能（高度柔性的亲水臂和刚性的排列尾部基团），在识别单层中充当“纳米屏障”。