4,4,6,6-tetramethyl-heptan-3-one | 32557-57-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4,4,6,6-tetramethyl-heptan-3-one
• 英文别名: 4,4,6,6-Tetramethylheptan-3-one
• CAS: 32557-57-6
• 化学式: C₁₁H₂₂O
• 分子量: 170.295
• InChiKey: KQSNDNJMDRPELT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-ethyl-4,4,6-trimethyl-2-(1,1,3,3-tetramethyl-butyl)-[1,3]oxazinane 在 草酸 作用下， 生成 4,4,6,6-tetramethyl-heptan-3-one
  参考文献：
  名称：

  Dihydro-1,3-oxazines. XIII. Synthesis of specifically alkylated unsymmetrical ketones. Method for assembling ketones with .alpha.-(quaternary carbons)

  摘要：

  DOI：

  10.1021/ja00738a038

文献信息

• Method for preparing polyolefins containing vinylidene groups using azole compounds
  申请人：Chevron Oronite Company LLC

  公开号：EP1803741A1

  公开（公告）日：2007-07-04

  Disclosed is a method for preparing polyolefins containing vinylidine end groups from quasiliving carbocationically terminated polyolefin polymers by contacting the quasiliving carbocationically terminated polymer with a suitable azole quenching agent and substituted derivatives thereof.

  本发明公开了一种方法，通过将准羰基端聚烯烃聚合物与合适的唑类淬火剂及其取代衍生物接触，从准羰基端聚烯烃聚合物中制备含有乙烯烷端基团的聚烯烃。
• Method for preparing polyolefins containing vinylidene end groups using nonaromatic heterocyclic compounds
  申请人：Chevron Oronite Company LLC

  公开号：EP1803748A1

  公开（公告）日：2007-07-04

  Disclosed is a method for preparing polyolefins containing vinylidine end groups from quasiliving carbocationically terminated polyolefin polymers by contacting the quasiliving carbocationically terminated polymer with a suitable nonaromatic heterocyclic ring quenching agent and substituted derivatives thereof.

  本发明公开了一种方法，通过将准碳基终止聚烯烃聚合物与合适的非芳香杂环环淬火剂及其取代衍生物接触，从准碳基终止聚烯烃聚合物中制备含有乙烯烷端基的聚烯烃。
• Method for preparing polyolefins containing vinylidene end groups using polymeric nitrogen compounds
  申请人：Chevron Oronite Company LLC

  公开号：EP1803751A1

  公开（公告）日：2007-07-04

  Disclosed is a method for preparing polyolefins containing vinylidine end groups from quasiliving carbocationically terminated polyolefin polymers by contacting the quasiliving carbocationically terminated polymer with quenching agent selected from the group consisting of polypyrrole, polyvinylpyridine, polyphenothiazine, polyoxazine, and polypyrrole-co-thiophene and substituted derivatives thereof.

  本发明公开了一种从准碳基终止聚烯烃聚合物制备含有乙烯基末端基团的聚烯烃的方法，该方法是将准碳基终止聚合物与选自聚吡咯、聚乙烯吡啶、聚吩噻嗪、聚噁嗪和聚吡咯-共噻吩及其取代衍生物组成的组中的淬灭剂接触。
• Polyisobutenyl sulfonates having low polydispersity
  申请人：Chevron Oronite Company LLC

  公开号：EP1932859A2

  公开（公告）日：2008-06-18

  The present invention provides for polyisobutenyl sulfonates, methods for preparing them, and composition employing them; wherein said polyisobutenyl sulfonates have improved low temperature and high temperature viscometric properties. The polyisobutenyl sulfonates are prepared by sulfonating polyisobutene and reacting the polyisobutenyl sulfonate with an alkali metal or alkaline earth metal, wherein the polyisobutene is characterized by having at least 90 mole percent methyl-vinylidene, a number average molecular weight of about 350 to 5,000, and a ratio of weight average molecular weight to number average molecular weight Mw/Mn of from about 1.01 to about 1.4.

  本发明提供了聚异丁烯基磺酸盐、其制备方法以及使用它们的组合物；其中所述聚异丁烯基磺酸盐具有更好的低温和高温粘度特性。聚异丁烯基磺酸盐是通过磺化聚异丁烯并使聚异丁烯基磺酸盐与碱金属或碱土金属反应而制备的，其中聚异丁烯的特征是具有至少 90 摩尔%的甲基亚乙烯基，平均分子量约为 350 至 5000，平均分子量与平均分子量之比 Mw/Mn 约为 1.01 至 1.4。
• Methods of preparing functionalized polyolefins
  申请人：Chevron Oronite Company LLC

  公开号：US10544238B2

  公开（公告）日：2020-01-28

  Provided herein are methods for preparing a functionalized polyolefin from an unsaturated polyolefin containing one or more non-aromatic main-chain double bonds and for reducing the size and/or polydispersity index (i.e., increasing the homogeneity) of the unsaturated polyolefin.

  本文提供了从含有一个或多个非芳香族主链双键的不饱和聚烯烃制备官能化聚烯烃以及减小不饱和聚烯烃尺寸和/或聚分散指数（即增加均匀性）的方法。