Conductive rubber composition and manufacturing method and conductive rubber member thereof
申请人:JSR Corporation
公开号:EP1020492A1
公开(公告)日:2000-07-19
The present invention provides a conductive rubber composition with a low hardness and low distortion, and exhibiting less variations in volume specific resistance value and less dependence on environment, a manufacturing method thereof, and ,further, a conductive rubber member using the same. The conductive rubber composition of the present invention contains a particulate polymer (A1, crosslinked particulate polymer, and the like.), an uncrosslinked polymer (A2), and a conductivity imparting agent (B). The particulate polymer (A1) is a nonpolar polymer (SBR, and the like.), the uncrosslinked (A2) is a polar polymer (NBR, and the like.), and the more conductivity imparting agent (B) exists in the uncrosslinked polymer than in the crosslinked particulate polymer. This composition can be obtained by starting the kneading of the above-described respective compounds at such a temperature (T °C) that the Moony viscosity of the uncrosslinked polymer is equal to or less than the Moony viscosity of the particulate polymer. The particulate polymer (A1) preferably has an average particle diameter of 25 µm or less, and a duro A hardness of 45 to 80. The conductive rubber member, according to the present invention, can be obtained by molding the above-described conductive rubber composition, and then vulcanizing it.
本发明提供了一种硬度低、变形小、体积比电阻值变化小、对环境依赖性小的导电橡胶组合物及其制造方法,以及使用该组合物的导电橡胶件。本发明的导电橡胶组合物包含微粒聚合物(A1、交联微粒聚合物等)、非交联聚合物(A2)和导电性赋予剂(B)。微粒聚合物(A1)为非极性聚合物(丁苯橡胶等),未交联聚合物(A2)为极性聚合物(丁腈橡胶等),未交联聚合物中的导电率促进剂(B)比交联微粒聚合物中的导电率促进剂(B)更多。在未交联聚合物的莫尼粘度等于或小于微粒聚合物的莫尼粘度的温度(T ℃)下开始捏合上述各化合物,即可得到这种组合物。微粒聚合物(A1)的平均颗粒直径最好小于或等于 25 微米,杜洛 A 硬度为 45 至 80。根据本发明,导电橡胶件可通过模压上述导电橡胶组合物,然后进行硫化处理而获得。