N-(4-iodophenyl)-5,7-dinitroquinolin-8-amine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: N-(4-iodophenyl)-5,7-dinitroquinolin-8-amine
• 化学式: C₁₅H₉IN₄O₄
• 分子量: 436.165
• InChiKey: ABWGBQMHIJKSIZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  117
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  8-氯-5,7-二硝基-喹啉 、 对碘苯胺 以80.3%的产率得到N-(4-iodophenyl)-5,7-dinitroquinolin-8-amine
  参考文献：
  名称：

  硝基喹啉系列自配合物的合成及光谱性质

  摘要：

  A number of new NH-bridged nitroquinoline derivatives with intramolecular charge transfer (autocomplexes) were synthesized starting from 8-chloro-5,7-dinitroquinoline and aromatic N,O-heterocyclic amines characterized by different donor powers and substitution patterns. The charge transfer in their molecules may occur via both direct polar conjugation through the bond sequence including the bridging nitrogen atom and through space between spatially close molecular fragments (contact charge transfer).

  DOI：

  10.1134/s1070428006070128

文献信息

• Synthesis and spectral properties of autocomplexes of the nitroquinoline series
  作者：I. G. Il’ina、V. V. Mel’nikov、B. N. Tarasevich、K. P. Butin

  DOI：10.1134/s1070428006070128

  日期：2006.7

  A number of new NH-bridged nitroquinoline derivatives with intramolecular charge transfer (autocomplexes) were synthesized starting from 8-chloro-5,7-dinitroquinoline and aromatic N,O-heterocyclic amines characterized by different donor powers and substitution patterns. The charge transfer in their molecules may occur via both direct polar conjugation through the bond sequence including the bridging nitrogen atom and through space between spatially close molecular fragments (contact charge transfer).