2-propylpropanediol

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-propylpropanediol
• 英文别名: 2-methylpentanediol；2-methylpentane-1,1-diol
• 化学式: C₆H₁₄O₂
• 分子量: 118.176
• InChiKey: ACOQOLIJGGKILA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  8
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-propylpropanediol 、 trans-4-(trifluoromethyl)cyclohexanecarbaldehyde 在 对甲苯磺酸 作用下， 以 甲苯 为溶剂， 生成 2-(trans-4-Trifluoromethylcyclohexyl)-5-propyl-1,3-dioxane
  参考文献：
  名称：

  Trifluoromethylcyclohexane derivatives

  摘要：

  本发明涉及一种具有以下结构的三氟甲基环己烷衍生物 ##STR1## 其中R是一个烷基或烯基基团，含有多达18个碳原子，未取代或通过CN或至少一个卤素取代，其中一个或多个不相邻的CH.sub.2基团可以被选自包括--O--、--S--、--CO--、--O--CO--、--CO--O--和--C.tbd.C--的基团替代；A.sup.1和A.sup.2各自独立地是a) 1,4-苯基基团，其中一个或两个CH基团可以被N取代，b) 1,4-环己基基团，其中一个或两个不相邻的CH.sub.2基团可以被--O--或--S--取代，c) 1,4-环己烯基、哌啶-1,4-二基、1,4-双环[2,2,2]-辛基或萘-2,6-二基基团，基团a)和b)可以通过卤素原子或氰基和/或甲基基团单取代或多取代；##STR2## Z.sup.1和Z.sup.2各自独立地是--CO--O--、--O--CH--、--CH.sub.2 CH.sub.2 --、--CH(CN)--CH.sub.2 --、--CH.sub.2 --CH(CN)--、--CH.dbd.CH--、--OCH .sub.2 --、--CH.sub.2 O--、--CH.dbd.N--、--N.dbd.CH--、--NO.dbd.N--、--N.dbd.NO--、--N.dbd.N--或单键，o为0、1或2。这些化合物可用作液晶介质的组分，特别适用于电光显示元件，尤其是矩阵型液晶显示器。

  公开号：

  US05209868A1

文献信息

• Process for producing aliphatic oligocarbonate diols
  申请人：——

  公开号：US20040143130A1

  公开（公告）日：2004-07-22

  The present invention relates to a process for producing an aliphatic oligocarbonate diol comprising a) reacting an aliphatic diol with dimethyl carbonate at an elevated pressure in a reaction mixture, and b) subsequently removing unreacted methanol and dimethyl carbonate under a reduced pressure to uncap the terminal OH groups.

  本发明涉及一种生产脂肪族寡碳酸酯二元醇的方法，包括a)在反应混合物中，在升高的压力下将脂肪族二元醇与碳酸二甲酯反应，b)随后在减压下去除未反应的甲醇和碳酸二甲酯，以去除末端的羟基基团。
• Lightfast colorant and lightfast ink composition including the same
  申请人：Samsung Electronics Co., Ltd.

  公开号：US20040158050A1

  公开（公告）日：2004-08-12

  A lightfast colorant and a lightfast ink composition including the lightfast colorant utilize a lightfast colorant that is derived by covalently binding a cinnamate derivative and a conventional colorant. The lightfast colorant improves storage stability as well as lightfastness when added to an ink composition.

  一种耐光色料和包括该耐光色料的耐光墨水组合物利用通过共价结合肉桂酸酯衍生物和传统色料而得到的耐光色料。当添加到墨水组合物中时，这种耐光色料提高了存储稳定性和耐光性。
• [EN] OLIGOMERS OF FDCA AND GLYCOLS FROM A ONE-POT ESTERIFICATION-TRANSESTERIFICATION PROCESS USING WATER-TOLERANT METAL TRIFLATE CATALYST<br/>[FR] OLIGOMÈRES DE FDCA ET DE GLYCOLS ISSUS D'UN PROCÉDÉ MONOTOPE D'ESTÉRIFICATION-TRANSESTÉRIFICATION UTILISANT UN CATALYSEUR À BASE DE TRIFLATE MÉTALLIQUE TOLÉRANT À L'EAU
  申请人：ARCHER DANIELS MIDLAND CO

  公开号：WO2017091412A1

  公开（公告）日：2017-06-01

  A method for preparing sugar-based oligomers is described. The process involves sequential (one-pot) esterification of 2,5-furan-dicarboxylic acid (FDCA) with an alcohol and transesterification with a glycol, as catalyzed by relatively low amounts of homogeneous water-tolerant Lewis acid catalysts, which can be retained in the product mixture from the esterification through transesterification.

  本文描述了一种制备基于糖的寡聚体的方法。该过程涉及将2,5-呋喃二甲酸（FDCA）与醇顺序（一锅）酯化并与乙二醇酯交换反应，由相对较少的均相耐水路易斯酸催化剂催化，这些催化剂可以通过酯化到酯交换的产物混合物中保留。
• Concentrated, stable, preferably clear, fabric softening composition
  申请人：Trinh Toan

  公开号：US20060058216A1

  公开（公告）日：2006-03-16

  Principal solvents, especially mono-ol and diol principal solvents, having a ClogP of from about 0.15 to about 0.64, preferably from about 0.25 to about 0.62, and more preferably from about 0.40 to about 0.60, are disclosed that have the ability to make clear aqueous fabric softener compositions containing relatively high concentrations of fabric softener actives having ester linkages in their long, hydrophobic chains. The fabric softener actives are either unsaturated, or have intermediate length chains (˜C 12-14 ) and the said principal solvents are used at levels of less than about 40%. Other solvents may be present. Some of the said principal solvents are novel compounds and/or novel mixtures. Premixes of the fabric softening actives, the principal solvents, and, optionally, other solvents are useful in the preparation of complete formulations by obviating/limiting the need for heating.

  本发明揭示了主要溶剂，特别是具有ClogP约为0.15至约0.64，优选为约0.25至约0.62，更优选为约0.40至约0.60的单醇和双醇主要溶剂，具有制备含有长链疏水基中酯键的相对高浓度织物柔顺剂活性成分的清澈水性织物柔顺剂组合物的能力。织物柔顺剂活性成分可以是不饱和的，也可以具有中等长度的链（约C12-14），所述主要溶剂的使用水平小于约40％。其他溶剂可以存在。其中一些主要溶剂是新化合物和/或新混合物。织物柔顺剂活性成分、主要溶剂和可选的其他溶剂的预混物在制备完整配方时是有用的，因为它们可以避免/限制加热的需要。
• Concentrated, stable fabric softening composition
  申请人：——

  公开号：US20030153483A1

  公开（公告）日：2003-08-14

  Principal solvents, especially mono-ol and diol principal solvents, having a ClogP of from about 0.15 to about 0.64, preferably from about 0.25 to about 0.62, and more preferably from about 0.40 to about 0.60, are disclosed that have the ability to make clear aqueous fabric softener compositions containing relatively high concentrations of fabric softener actives having ester linkages in their long, hydrophobic chains. The fabric softener actives are either unsaturated, or have intermediate length chains (˜C 12-14 ) and the said principal solvents are used at levels of less than about 40%. Other solvents may be present. Some of the said principal solvents are novel compounds and/or novel mixtures. Premixes of the fabric softening actives, the principal solvents, and, optionally, other solvents are useful in the preparation of complete formulations by obviating/limiting the need for heating.

  本发明涉及主要溶剂，特别是具有从约0.15到约0.64的ClogP值的单醇和二醇主要溶剂，优选从约0.25到约0.62，更优选从约0.40到约0.60，具有使含有长的亲水性链中的酯键的织物柔软剂活性成分相对高浓度的清澈水性织物柔软剂组合物的能力。织物柔软剂活性成分可以是不饱和的，也可以具有中等长度的链（约C12-14），所述主要溶剂的使用水平低于约40％。其他溶剂可能也存在。其中一些主要溶剂是新化合物和/或新混合物。织物柔软剂活性成分、主要溶剂和可选的其他溶剂的预混物可用于制备完整配方，从而避免/限制加热的需要。