L-glucuronic acid

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: L-glucuronic acid
• 英文别名: L-glucopyranuronic acid；(2R,3R,4R,5S)-3,4,5,6-tetrahydroxyoxane-2-carboxylic acid
• 化学式: C₆H₁₀O₇
• 分子量: 194.141
• InChiKey: AEMOLEFTQBMNLQ-LSGJAIDOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.3
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  127
• 氢给体数：
  5
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  L-glucuronic acid 在 吡啶 作用下， 反应 2.0h， 生成
  参考文献：
  名称：

  Triterpenoid saponins from Echinopsis macrogona (Cactaceae)

  摘要：

  Triterpene saponins, pachanosides C1, E1, F1 and G1 (1-4), and bridgesides A1, C1, C2, D1, D2, E1 and E2 (5-11) were isolated from Echinopsis macrogona. Compounds 1-4 were saponins with pachanane type triterpene saponins, while the others (5-11) were oleanane type triterpene saponins. While the aglycones of 2-4 and 8-11 were hitherto unknown, the structure of pachanol C was revised in this paper. Their structures were elucidated on the basis of chemical and physicochemical evidence. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.phytochem.2010.10.004

文献信息

• Triterpenoid saponins from Echinopsis macrogona (Cactaceae)
  作者：Sachie Okazaki、Kaoru Kinoshita、Satoru Ito、Kiyotaka Koyama、Hiroshi Yuasa、Kunio Takahashi

  DOI：10.1016/j.phytochem.2010.10.004

  日期：2011.1

  Triterpene saponins, pachanosides C1, E1, F1 and G1 (1-4), and bridgesides A1, C1, C2, D1, D2, E1 and E2 (5-11) were isolated from Echinopsis macrogona. Compounds 1-4 were saponins with pachanane type triterpene saponins, while the others (5-11) were oleanane type triterpene saponins. While the aglycones of 2-4 and 8-11 were hitherto unknown, the structure of pachanol C was revised in this paper. Their structures were elucidated on the basis of chemical and physicochemical evidence. (C) 2010 Elsevier Ltd. All rights reserved.