2,7-bis[5-(carbazol-9-yl)thiophen-2-yl]-9,9-di-n-hexylfluorene

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 2,7-bis[5-(carbazol-9-yl)thiophen-2-yl]-9,9-di-n-hexylfluorene
• 英文别名: 9-[5-[7-(5-Carbazol-9-ylthiophen-2-yl)-9,9-dihexylfluoren-2-yl]thiophen-2-yl]carbazole；9-[5-[7-(5-carbazol-9-ylthiophen-2-yl)-9,9-dihexylfluoren-2-yl]thiophen-2-yl]carbazole
• 化学式: C₅₇H₅₂N₂S₂
• 分子量: 829.185
• InChiKey: AEPZSCGBLCRFES-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  19.3
• 重原子数：
  61
• 可旋转键数：
  14
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  66.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  9,9-二己基-2,7-二溴代芴 在 四(三苯基膦)钯 N-溴代丁二酰亚胺(NBS) 、 铜 、 sodium carbonate 、 potassium carbonate 作用下， 以 四氢呋喃 、 水 、 硝基苯 为溶剂， 反应 45.0h， 生成 2,7-bis[5-(carbazol-9-yl)thiophen-2-yl]-9,9-di-n-hexylfluorene
  参考文献：
  名称：

  Synthesis and properties of N-carbazole end-capped conjugated molecules

  摘要：

  A series of novel N-carbazole end-capped pi-conjugated molecules were synthesized by a divergent approach with the use of bromination, Suzuki cross-coupling, and Ullmann reactions and their physical properties were investigated. In dilute solution, UV-vis absorption spectra displayed bathochromic shift with respect to their conjugated backbones, and photoluminescence spectra showed emission maxima in the blue region. Thermal analysis revealed that they are thermally stable semi-crystalline and amorphous materials. All molecules exhibited good electrochemical stability with high-lying HOMO energy levels and have potential applications as hole-transporting and light-emitting layers in organic light-emitting diodes or as host materials for electrophosphorescent applications. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2006.12.011

文献信息

• Synthesis and properties of N-carbazole end-capped conjugated molecules
  作者：Vinich Promarak、Somsak Ruchirawat

  DOI：10.1016/j.tet.2006.12.011

  日期：2007.2

  A series of novel N-carbazole end-capped pi-conjugated molecules were synthesized by a divergent approach with the use of bromination, Suzuki cross-coupling, and Ullmann reactions and their physical properties were investigated. In dilute solution, UV-vis absorption spectra displayed bathochromic shift with respect to their conjugated backbones, and photoluminescence spectra showed emission maxima in the blue region. Thermal analysis revealed that they are thermally stable semi-crystalline and amorphous materials. All molecules exhibited good electrochemical stability with high-lying HOMO energy levels and have potential applications as hole-transporting and light-emitting layers in organic light-emitting diodes or as host materials for electrophosphorescent applications. (c) 2006 Elsevier Ltd. All rights reserved.
• Synthesis and characterization of novel N-carbazole end-capped oligothiophene-fluorenes
  作者：Vinich Promarak、Auradee Pankvuang、Somsak Ruchirawat

  DOI：10.1016/j.tetlet.2006.12.073

  日期：2007.2

  A series of novel N-carbazole end-capped oligothiophene-fluorenes was synthesized using Ullmann coupling, bromination, and Suzuki coupling reactions. The optical, thermal, and electrochemical properties of these materials can be tuned by varying the conjugation length of the oligothiophene segment. The terminal carbazole and central fluorene moieties of the resulting materials are beneficial for their morphology, conjugation length, and solubility. (c) 2006 Elsevier Ltd. All rights reserved.