2-(4-methoxyphenyl)-1-(naphthalene-1-yl)-4,5-diphenyl-1H-imidazole

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 2-(4-methoxyphenyl)-1-(naphthalene-1-yl)-4,5-diphenyl-1H-imidazole
• 英文别名: 2-(4-Methoxyphenyl)-1-naphthalen-1-yl-4,5-diphenylimidazole；2-(4-methoxyphenyl)-1-naphthalen-1-yl-4,5-diphenylimidazole
• 化学式: C₃₂H₂₄N₂O
• 分子量: 452.555
• InChiKey: BABIKCWDGKLOTM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  35
• 可旋转键数：
  5
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  27
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-萘胺 、 4-甲氧基苯甲醛 、 联苯甲酰 在 ammonium acetate 作用下， 以 乙醇 为溶剂， 生成 2-(4-methoxyphenyl)-1-(naphthalene-1-yl)-4,5-diphenyl-1H-imidazole
  参考文献：
  名称：

  Nano ZnO, Cu-doped ZnO, and Ag-doped ZnO assisted generation of light from imidazole

  摘要：

  A sensitive 2-(4-methoxyphenyl)-1-(naphthalene-1-yl)-4,5-diphenyl-1H-imidazole (MNDI) fluorescent sensor for nanoparticulate ZnO has been designed and synthesized. The nanocrystalline ZnO, Cu-doped ZnO, and Ag-doped ZnO have been synthesised by sol-gel method and characterized by powder X-ray diffraction, scanning electron microscopy(SEM), UV-vis diffuse reflectance, photoluminescence and life time spectral studies. All the synthesized nanoparticles display violet emission due to charge carrier-recombination. The synthesized sensor emission is enhanced by nanocrystalline pristine ZnO but is suppressed by Cu-doped ZnO and Ag-doped ZnO nanoparticles. The suppression of fluorescence is more by copper than by silver doping. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jphotochem.2014.09.002

文献信息

• Nano ZnO, Cu-doped ZnO, and Ag-doped ZnO assisted generation of light from imidazole
  作者：J. Jayabharathi、C. Karunakaran、V. Kalaiarasi、P. Ramanathan

  DOI：10.1016/j.jphotochem.2014.09.002

  日期：2014.12

  A sensitive 2-(4-methoxyphenyl)-1-(naphthalene-1-yl)-4,5-diphenyl-1H-imidazole (MNDI) fluorescent sensor for nanoparticulate ZnO has been designed and synthesized. The nanocrystalline ZnO, Cu-doped ZnO, and Ag-doped ZnO have been synthesised by sol-gel method and characterized by powder X-ray diffraction, scanning electron microscopy(SEM), UV-vis diffuse reflectance, photoluminescence and life time spectral studies. All the synthesized nanoparticles display violet emission due to charge carrier-recombination. The synthesized sensor emission is enhanced by nanocrystalline pristine ZnO but is suppressed by Cu-doped ZnO and Ag-doped ZnO nanoparticles. The suppression of fluorescence is more by copper than by silver doping. (C) 2014 Elsevier B.V. All rights reserved.