VO(acac)2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: VO(acac)2
• 英文别名: 4-Oxopent-2-en-2-olate;oxovanadium(2+)
• 化学式: C₁₀H₁₄O₅V
• 分子量: 265.16
• InChiKey: JFHJZWAQYMGNBE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -0.44
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  97.3
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  乙酰氧肟酸 、 VO(acac)2 、 对溴苯甲酰肼 以 甲醇 为溶剂， 反应 1.0h， 以77%的产率得到
  参考文献：
  名称：

  Synthesis, Crystal Structures and Catalytic Property of Oxidovanadium(V) Complexes with N’-(4-Oxopentan-2-ylidene)nicotinohydrazide and 4-Bromo-N’-(4-oxopentan

  摘要：

  A pair of structurally similar oxidovanadium(V) complexes with the general formula [VOLE], with the hydrazone compounds N'-(4-oxopentan-2-ylidene)nicotinohydrazide (H2L1) and 4-bromo-N'-(4-oxopentan-2-ylidene)benzohydrazide (H2L2), and the acetohydroxamic acid (HL') as ligands, have been synthesized and structurally characterized by physico-chemical methods and single crystal X-ray determination. Single crystal X-ray analysis indicates that the V atoms in the complexes are in octahedral coordination, with the ONO donor atoms of the hydrazone ligands, and the OO donor atoms of the acetohydroxamate ligands, as well as an oxido O atom. The complexes showed good property for the catalytic epoxidation of styrene.

  DOI：

  10.17344/acsi.2020.5932

文献信息

• Synthesis, Crystal Structures and Catalytic Property of Oxidovanadium(V) Complexes with N’-(4-Oxopentan-2-ylidene)nicotinohydrazide and 4-Bromo-N’-(4-oxopentan
  作者：Qiwen Yang、Pu Wang、Yan Lei

  DOI：10.17344/acsi.2020.5932

  日期：——

  A pair of structurally similar oxidovanadium(V) complexes with the general formula [VOLE], with the hydrazone compounds N'-(4-oxopentan-2-ylidene)nicotinohydrazide (H2L1) and 4-bromo-N'-(4-oxopentan-2-ylidene)benzohydrazide (H2L2), and the acetohydroxamic acid (HL') as ligands, have been synthesized and structurally characterized by physico-chemical methods and single crystal X-ray determination. Single crystal X-ray analysis indicates that the V atoms in the complexes are in octahedral coordination, with the ONO donor atoms of the hydrazone ligands, and the OO donor atoms of the acetohydroxamate ligands, as well as an oxido O atom. The complexes showed good property for the catalytic epoxidation of styrene.