8-(4,6-dichloro-1,3,5-triazinoxy) quinoline

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 8-(4,6-dichloro-1,3,5-triazinoxy) quinoline
• 英文别名: 8-(4,6-Dichloro-1,3,5-triazinoxy)quinoline；8-[(4,6-dichloro-1,3,5-triazin-2-yl)oxy]quinoline
• 化学式: C₁₂H₆Cl₂N₄O
• mdl: MFCD18032245
• 分子量: 293.112
• InChiKey: IRFZUCPSGUCKFT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  60.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  8-(4,6-dichloro-1,3,5-triazinoxy) quinoline 、 9-咔唑乙醇 在 sodium hydroxide 作用下， 以 水 、 丙酮 为溶剂， 反应 48.0h， 生成 9,9'-(2,2'-(6-(quinolin-8-yloxy)-1,3,5-triazine-2,4-diyl)bis(oxy)bis(ethane-2,1-diyl))bis(9H-carbazole)
  参考文献：
  名称：

  用于高对比度电致变色器件的供体-受体型超结构咔唑和喹啉三嗪芯导电聚合物

  摘要：

  Star shaped functionalized molecules allow the production of sophisticated nano devices by using them as the building blocks for the formation of superstructured macromolecules. Here, we address star-shaped molecule which is formed by quinoline and electroactive carbazole functionalized triazine (TQEC). Using quinoline as electron accepting (A) and carbazole as electron donating (D) moiety, the resulting conductive polymer is designed to have high optical contrast. The cross-linked polymer (PTQEC) characterized after the electropolymerization of the A/D type molecule has been found to have superior optical and electrical properties. It has high optical contrast (71% at 675 nm), fast switching time about 3 s and high long time redox stability (91.75%). As a result of the spectroelectrochemical and electrochromic characterization, it is determined that PTQEC is transparent and green colored in its neutral and oxidized states, which is a desirable property for smart windows. Therefore electrochromic devices (ECDs) depending on PTQEC and PEDOT were established, where PEDOT functioned as the cathodically coloring layer. Optical and electrochemical characterizations of the device in the way of the optical contrast (51% at 540 nm), switching time (about 3 s), open circuit memory, redox stability (95.36%) and colors were investigated. (C) 2018 The Electrochemical Society.

  DOI：

  10.1149/2.1201805jes
• 作为产物：
  描述：

  8-羟基喹啉 、 三聚氯氰 在 sodium hydroxide 作用下， 以 水 、 丙酮 为溶剂， 反应 0.83h， 以86%的产率得到8-(4,6-dichloro-1,3,5-triazinoxy) quinoline
  参考文献：
  名称：

  In situ fluorescent labeling of highly volatile methylamine with 8-(4,6-dichloro-1,3,5-triazinoxy)quinoline

  摘要：

  第一个用于监测高挥发性甲胺 8-(4,6-二氯-1,3,5-三嗪氧基)喹啉的原位荧光标记探针已经设计、合成和评估。该探针标记光谱惰性的甲胺，通过抑制内部电荷转移引起荧光特性的巨大变化，因此可以用作原位标记探针。这种适用性已通过测量 N-甲基氨基甲酸酯（例如乙噻威）水解过程中释放的甲胺得到证明。

  DOI：

  10.1039/b101711j