5-[2-(4,6-dimethoxypyrimidine-2-yloxy)-6-nitrophenyl]oxazole

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5-[2-(4,6-dimethoxypyrimidine-2-yloxy)-6-nitrophenyl]oxazole
• 英文别名: 5-[2-(4,6-dimethoxypyrimidin-2-yl)oxy-6-nitrophenyl]-1,3-oxazole
• 化学式: C₁₅H₁₂N₄O₆
• 分子量: 344.283
• InChiKey: HFNFYHFORMOGIB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  25
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  125
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  5-[2-(4,6-dimethoxypyrimidine-2-yloxy)-6-nitrophenyl]oxazole 、 银 在 溶剂黄146 作用下， 以 magnesium sulfate 、 乙酸乙酯 为溶剂， 生成 5-[2-amino-6-(4,6-dimethoxypyrimidine-2-yloxy)phenyl]oxazole
  参考文献：
  名称：

  Oxazole derivative, process for producing the same, and herbicide

  摘要：

  本发明涉及由式[I]表示的噁唑衍生物；其中A代表氮原子或R3-取代的碳原子；B代表氮原子，或未取代或X-取代的碳原子；Z代表氧原子，亚砜基或砜基；R1和R2分别独立地表示氢、C1-C6烷基、C1-C6烷氧基、C1-C6卤代烷氧基、C1-C6卤代烷基或类似物；R3表示氢、C1-C6烷基、卤素、硝基、甲酰基或酰基；X表示氢、C1-C6烷基、C3-C7环烷基、C2-C6烯基、C3-C6炔基、C1-C6卤代烷基或类似物；Y表示氢、C1-C6烷基、C3-C7环烷基、C2-C6烯基、C3-C6炔基、C1-C6卤代烷基或类似物；m表示1或2的整数，n表示1、2、3或4的整数，以及其盐。本发明指定的化合物具有优异的除草活性，并可用作除草剂的活性成分。

  公开号：

  US06268310B1

文献信息

• Oxazole derivatives, process for producing the same, and herbicide
  申请人：Nippon Soda Co., Ltd.

  公开号：US05962685A1

  公开（公告）日：1999-10-05

  The present invention is directed to oxazole derivatives represented by the formula \x9bI!; ##STR1## wherein A represents a nitrogen atom or a R.sub.3 -substituted carbon atom; B represents a nitrogen atom, or an unsubstituted or X-substituted carbon atom; Z represents an oxygen atom, sulfinyl or sulfonyl; R.sub.1 and R.sub.2 represent each independently hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.6 haloalkoxy, C.sub.1 -C.sub.6 haloalkyl or the like; R.sub.3 represents hydrogen, C.sub.1 -C.sub.6 alkyl, halogen, nitro, formyl or acyl; X represents hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.7 cycloalkyl, C.sub.2 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, C.sub.1 -C.sub.6 haloalkyl or the like; Y represents hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.7 cycloalkyl, C.sub.2 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, C.sub.1 -C.sub.6 haloalkyl or the like; m represents an integar of 1 or 2, and n represents an integar of 1, 2, 3 or 4, and the salts thereof. The compounds specified in the present invention have an excellent herbicidal activity and are useful as an active ingredients for herbicides.

  本发明涉及一种由以下式子表示的噁唑衍生物：\x9bI!; ##STR1## 其中，A代表氮原子或R.sub.3-取代的碳原子；B代表氮原子，或未取代或X取代的碳原子；Z代表氧原子、亚砜基或磺酰基；R.sub.1和R.sub.2各自独立地代表氢、C.sub.1-C.sub.6烷基、C.sub.1-C.sub.6氧烷基、C.sub.1-C.sub.6卤代氧烷基、C.sub.1-C.sub.6卤代烷基或类似物；R.sub.3代表氢、C.sub.1-C.sub.6烷基、卤素、硝基、甲酰基或酰基；X代表氢、C.sub.1-C.sub.6烷基、C.sub.3-C.sub.7环烷基、C.sub.2-C.sub.6烯基、C.sub.3-C.sub.6炔基、C.sub.1-C.sub.6卤代烷基或类似物；Y代表氢、C.sub.1-C.sub.6烷基、C.sub.3-C.sub.7环烷基、C.sub.2-C.sub.6烯基、C.sub.3-C.sub.6炔基、C.sub.1-C.sub.6卤代烷基或类似物；m表示1或2的整数，n表示1、2、3或4的整数，以及其盐。本发明中所指定的化合物具有优异的除草活性，并可用作除草剂的活性成分。
• OXAZOLE DERIVATIVE, PROCESS FOR PRODUCING THE SAME, AND HERBICIDE
  申请人：NIPPON SODA CO., LTD.

  公开号：EP0776894A1

  公开（公告）日：1997-06-04

  The present invention is directed to oxazole derivatives represented by the formula [I]; wherein A represents a nitrogen atom or a R3-substituted carbon atom; B represents a nitrogen atom, or an unsubstituted or X-substituted carbon atom; Z represents an oxygen atom, sulfinyl or sulfonyl; R1 and R2 represent each independently hydrogen, C1-C6 alkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C6 haloalkyl or the like; R3 represents hydrogen, C1-C6 alkyl, halogen, nitro, formyl or acyl; X represents hydrogen, C1-C6 alkyl, C3-C7 cycloalkyl, C2-C6 alkenyl, C1-C6 alkynyl, C1-C6 haloalkyl or the like; Y represents hydrogen, C1-C6 alkyl, C3-C7 cycloalkyl, C2-C 6 alkenyl, C3-C6 alkynyl, C1-C6 haloalkyl or the like; m represents an integar of 1 or 2, and n represents an integar of 1, 2, 3 or 4, and the salts thereof. The compounds specified in the present invention have an excellent herbicidal activity and are useful as an active ingredients for herbicides.

  本发明涉及式[I]代表的噁唑衍生物； 其中 A 代表氮原子或 R3 取代的碳原子；B 代表氮原子或未取代或 X 取代的碳原子；Z 代表氧原子、亚砜基或磺酰基；R1 和 R2 各自独立地代表氢、C1-C6 烷基、C1-C6 烷氧基、C1-C6 卤代烷氧基、C1-C6 卤代烷基或类似物；R3 代表氢、C1-C6 烷基、卤素、硝基、甲酰基或酰基；X代表氢、C1-C6烷基、C3-C7环烷基、C2-C6烯基、C1-C6炔基、C1-C6卤代烷基或类似物；Y代表氢、C1-C6烷基、C3-C7环烷基、C2-C6烯基、C3-C6炔基、C1-C6卤代烷基或类似物；m代表1或2的整数，n代表1、2、3或4的整数，及其盐类。本发明所述化合物具有优异的除草活性，可用作除草剂的活性成分。
• US6107251A
  申请人：——

  公开号：US6107251A

  公开（公告）日：2000-08-22
• US6268310B1
  申请人：——

  公开号：US6268310B1

  公开（公告）日：2001-07-31
• Oxazole derivative, process for producing the same, and herbicide
  申请人：Nippon Soda Co., Ltd.

  公开号：US06268310B1

  公开（公告）日：2001-07-31

  The present invention is directed to oxazole derivatives represented by the formula [I]; wherein A represents a nitrogen atom or a R3-substituted carbon atom; B represents a nitrogen atom, or an unsubstituted or X-substituted carbon atom; Z represents an oxygen atom, sulfinyl or sulfonyl; R1 and R2 represent each independently hydrogen, C1-C6 alkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C6 haloalkyl or the like; R3 represents hydrogen, C1-C6 alkyl, halogen, nitro, formyl or acyl; X represents hydrogen, C1-C6 alkyl, C3-C7 cycloalkyl, C2-C6 alkenyl, C3-C6 alkynyl, C1-C6 haloalkyl or the like; Y represents hydrogen, C1-C6 alkyl, C3-C7 cycloalkyl, C2-C6 alkenyl, C3-C6 alkynyl, C1-C6 haloalkyl or the like; m represents an integar of 1 or 2, and n represents an integar of 1, 2, 3 or 4, and the salts thereof. The compounds specified in the present invention have an excellent herbicidal activity and are useful as an active ingredients for herbicides.

  本发明涉及由式[I]表示的噁唑衍生物；其中A代表氮原子或R3-取代的碳原子；B代表氮原子，或未取代或X-取代的碳原子；Z代表氧原子，亚砜基或砜基；R1和R2分别独立地表示氢、C1-C6烷基、C1-C6烷氧基、C1-C6卤代烷氧基、C1-C6卤代烷基或类似物；R3表示氢、C1-C6烷基、卤素、硝基、甲酰基或酰基；X表示氢、C1-C6烷基、C3-C7环烷基、C2-C6烯基、C3-C6炔基、C1-C6卤代烷基或类似物；Y表示氢、C1-C6烷基、C3-C7环烷基、C2-C6烯基、C3-C6炔基、C1-C6卤代烷基或类似物；m表示1或2的整数，n表示1、2、3或4的整数，以及其盐。本发明指定的化合物具有优异的除草活性，并可用作除草剂的活性成分。