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vanadocene monobromide

中文名称
——
中文别名
——
英文名称
vanadocene monobromide
英文别名
bromovanadocene
vanadocene monobromide化学式
CAS
——
化学式
C10H10BrV
mdl
——
分子量
261.035
InChiKey
OLTFYNXAJWXACE-UHFFFAOYSA-M
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    None
  • 重原子数:
    None
  • 可旋转键数:
    None
  • 环数:
    None
  • sp3杂化的碳原子比例:
    None
  • 拓扑面积:
    None
  • 氢给体数:
    None
  • 氢受体数:
    None

反应信息

  • 作为反应物:
    描述:
    vanadocene monobromide 以85%的产率得到
    参考文献:
    名称:
    KRASILNIKOVA E. V.; LATYAEVA V. N.; GLADYSHEV E. N.; LINEVA A. N.; FOKEEV+, XIMIYA EHLEMENTOORGAN. SOEDIN. (GORKIJ), 1979, HO 7, 76-77
    摘要:
    DOI:
  • 作为产物:
    参考文献:
    名称:
    RAZUVAEV G. A.; LATYAEVA V. N.; KRASILNIKOVA E. V.; LINEVA A. N.; GLADYSH+, ZH. OBSHCH. XIMII, 1980, 50, HO 1, 96-100
    摘要:
    DOI:
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文献信息

  • Reactions of vanadocene with aliphatic halides
    作者:Reiner Sustmann、Gebhard Kopp
    DOI:10.1016/0022-328x(88)80156-6
    日期:1988.6
    and tertiary aliphatic halides have been shown to react with vanadocene by oxidative addition to give (alkyl)(halogeno)vanadocenes. The primary product is stable if the alkyl group is methyl, but olefin and alkane are formed in the case of alkyl groups having hydrogen atoms on an sp3 carbon β to the halogen. In the reaction of vanadocene with isopropyl and t-butyl bromide a significant amount of molecular
    已显示伯,仲和叔脂族卤化物通过氧化加成与钒二烯反应生成(烷基)(卤代)钒烯。如果烷基是甲基,则初级产物是稳定的,但是在烷基的卤素的sp 3碳β上具有氢原子的烷基的情况下,形成烯烃和烷烃。在钒氧杂环丁烯与异丙基和叔丁基溴的反应中,会产生大量的分子氢,对于叔丁基溴,烷烃的百分比几乎降至零。提供了一些V IV中间体的ESR证据。
  • Reactions of vanadocene with benzyl bromide
    作者:Reiner Sustmann、Gebhard Kopp
    DOI:10.1016/0022-328x(88)80155-4
    日期:1988.6
    The formation of bibenzyl in the reaction of vanadocene with benzyl bromide is explained in terms of an initial oxidative addition of benzyl bromide and subsequent free radical reactions. ESR evidence is presented for the VIV intermediate.
    在钒氧烯与苄基溴的反应中联苄的形成是通过苄基溴的初始氧化加成和随后的自由基反应来解释的。提出了V IV中间体的ESR证据。
  • Some complexes containing the dicyclopentadienyl-vanadium(III) group.
    作者:F.W. Sigert、H.J. de Liefde Meijer
    DOI:10.1016/s0022-328x(00)86332-9
    日期:1968.11
    The complexes (C5H5)2VIIIR, where R  pentafluorophenyl, cyclopentadienyl allyl, 2-methylalyl and 2-butenyl, were prepared by reaction of one mole of (C5H5)2VIIICl with one mole of C5F5Li, C5H5Na, or (methyl)allylmagnesium halide in tetrahydrofuran or diethyl ether. The pentafluorophenyl complex is very stable, but the other complexes had to be prepared and stored below room temperature. The complexes
    通过使一摩尔(C 5 H 5)2 V III Cl与一摩尔反应制备配合物(C 5 H 5)2 V III R,其中R 1五氟苯基,环戊二烯基烯丙基,2-甲基丙烯基和2-丁烯基。的C 5 F 5 Li,C 5 H 5Na,或在四氢呋喃或乙醚中的(甲基)烯丙基卤化镁。五氟苯基配合物非常稳定,但其他配合物必须制备并在室温以下保存。该络合物对氧非常敏感。每个分子有两个不成对的电子。红外和质子磁共振光谱表明,配体R是σ键合到金属上的。
  • Reactions of bis(cyclopentadienyl)vanadium derivatives with nitrogen mono-oxide and the crystal structure of an oxo-bridged nitrosyl complex of vanadium
    作者:Frank Bottomley、James Darkwa、Peter S. White
    DOI:10.1039/dt9850001435
    日期:——
    [V(η-C5H5)2(NCO)] was obtained independently from [VCl(η-C5H5)2] and NCO– in aqueous solution. The reaction between [V(η-C5H5)2(CO)] and NOCl gave a mixture of products including one or more containing NCO–, and there was no reaction between NO and [V(η-C5H5)2(CO)2]+. The reaction between [VI(η-C5H5)2] and NO gave two products, both analysing as VI(C5H5)2NO. One was a brown insoluble polymer with ionic iodide
    之间的反应[V(η-C 5 H ^ 5)2 ]和NO已经显示为具有1:1 stoicheiometry但最初的产物,推定为[V(η-C 5 H ^ 5)2(NO)]进行歧化,得到最终产物的混合物。[V(η-C之间的反应5 ħ 5)2(CO)]和NO发生用2:1 stoicheiometry并给予了复杂的含NCO这不能由聚合物氧化物分离。络合物[V(η-C 5 H ^ 5)2(NCO)的方式,由独立地获得的[的VCl(η-C 5 H ^ 5)2]和NCO –水溶液中。[V(η-C之间的反应5 ħ 5)2(CO)]和NOCl得到产物的混合物,包括一种或多种含NCO - ,并且没有和[V(η-C之间没有反应5 ħ 5)2(CO)2 ] +。之间的反应[VI(η-C 5 H ^ 5)2 ]和NO给两个产品,既分析作为VI(C 5 H ^ 5)2 NO。一种是带有离子碘化物的棕色不溶聚合物,据信它具有桥连N
  • Preparation, fluxional behaviour, and decomposition of bis(cyclopentadienyl)iodonitrosylvanadium. X-Ray crystal structure of [(cpVI)<sub>2</sub>{cpV(NO)}<sub>2</sub>(µ-O)<sub>4</sub>]
    作者:Frank Bottomley、James Darkwa、Peter S. White
    DOI:10.1039/c39820001039
    日期:——
    cp2VX(NO)(cp = C5H5,X = Br, I) are fluxional molecules in which linear and bent VNO groups interconvert; the molecule with the linear VNO group necessarily contains at least one ring with less than η5hapticity, While cp2VI(NO) decomposes in vacuo in tetrahydrofuran solution to give [(cpVI)2cpV(NO)}2(µ-O)4]whose X-ray crystal structure is reported.
    cp 2 VX(NO)(cp = C 5 H 5,X = Br,I)是线性和弯曲的VNO基团相互转换的助熔分子。与线性VNO基的分子必须含有具有小于至少一个环η 5哈普托数,虽然CP 2 VI(NO)分解在真空中在四氢呋喃溶液,得到[(CPVI)2 CPV(NO)} 2(μ - O)4 ],其X-射线晶体结构被报道。
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