5-hexyl-10,11-dihydro-5H-dibenzo[b,f]azepine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯氮卓类
• 英文名称: 5-hexyl-10,11-dihydro-5H-dibenzo[b,f]azepine
• 英文别名: 11-Hexyl-5,6-dihydrobenzo[b][1]benzazepine
• 化学式: C₂₀H₂₅N
• 分子量: 279.425
• InChiKey: KAVBGMLZQNGPLS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  21
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  5-hexyl-10,11-dihydro-5H-dibenzo[b,f]azepine 在 sodium methylate 、 溶剂黄146 、 三氯氧磷 作用下， 以 甲醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 12.5h， 生成
  参考文献：
  名称：

  DYE, PHOTOELECTRIC CONVERSION ELEMENT USING THE SAME, PHOTOELECTROCHEMICAL CELL, AND METHOD OF PRODUCING DYE

  摘要：

  一种染料，其结构由式（1A）表示：其中A代表与碳-氮键一起形成环的原子团；Y1A和Y2A中至少一个代表酸性基团，当它们各自代表酸性基团时，它们可以相同也可以不同，或者当它们中只有一个代表酸性基团时，另一个代表电子吸引基团；D代表给染料的基团；n代表大于等于1的整数；L代表单键或二价连接基团；Y3A代表酸性基团。

  公开号：

  US20110213144A1
• 作为产物：
  描述：

  亚氨基二苄 、 溴己烷 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以71.2%的产率得到5-hexyl-10,11-dihydro-5H-dibenzo[b,f]azepine
  参考文献：
  名称：

  Synthesis and photovoltaic performance of dihydrodibenzoazepine-based sensitizers with additional lateral anchor

  摘要：

  Three novel metal-free organic dyes with dihydro-5H-dibenzo[b,f]azepine as a donor and cyanoacrylic acid as an anchoring unit were designed as an innovative linear skeleton of D-D-pi-A type of organic dyes. The conversion efficiency of the derived dye-sensitized solar cells is moderate. Among them, the dye with a hydroxy group as an additional anchoring moiety exhibited the highest UV-Vis absorption with a maximum molar extinction coefficient of 24,136 M-1 cm(-1) at lambda(max) = 458 nm and the best photovoltaic performance with an overall power conversion efficiency of 4.88%, while the dye with a carboxy group as an additional anchoring moiety exhibited the lowest conversion efficiency (4.52%). The results show that the dye loading on the film and photovoltaic performance of the dyes were influenced by the additional anchoring units. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2013.08.023

文献信息

• METHOD OF PRODUCING PHOTOELECTRIC CONVERSION ELEMENT, PHOTOELECTRIC CONVERSION ELEMENT, AND PHOTOELECTROCHEMICAL CELL
  申请人：KOBAYASHI Katsumi

  公开号：US20110073187A1

  公开（公告）日：2011-03-31

  A method of producing a photoelectric conversion element, which the element contains an electrically conductive support, a photosensitive layer having porous semiconductor fine particles, a charge transfer layer; and a counter electrode; containing the steps of: applying a semiconductor fine particle dispersion liquid, in which the content of solids excluding semiconductor fine particles is 10% by mass or less based on the total amount of the dispersion liquid, on the support, to form a coating; heating the coating, to obtain porous semiconductor fine particles; and sensitizing the porous particles by adsorption of the following dye: wherein X represents a group of non-metallic atoms necessary for forming a 7-membered ring; Y represents a dye residue; n represents an integer of 1 or more; Z represents a substituent; m represents 0 or a positive integer; and R 1 represents a hydrogen atom or a specific substituent.
• US8647708B2
  申请人：——

  公开号：US8647708B2

  公开（公告）日：2014-02-11
• US8779126B2
  申请人：——

  公开号：US8779126B2

  公开（公告）日：2014-07-15
• US9424998B2
  申请人：——

  公开号：US9424998B2

  公开（公告）日：2016-08-23
• Synthesis and photovoltaic performance of dihydrodibenzoazepine-based sensitizers with additional lateral anchor
  作者：Xu-Feng Zang、Yang-Fan Xu、Zafar Iqbal、Zu-Sheng Huang、Dai-Bin Kuang、Lingyun Wang、Herbert Meier、Ying Li、Derong Cao

  DOI：10.1016/j.dyepig.2013.08.023

  日期：2013.12

  Three novel metal-free organic dyes with dihydro-5H-dibenzo[b,f]azepine as a donor and cyanoacrylic acid as an anchoring unit were designed as an innovative linear skeleton of D-D-pi-A type of organic dyes. The conversion efficiency of the derived dye-sensitized solar cells is moderate. Among them, the dye with a hydroxy group as an additional anchoring moiety exhibited the highest UV-Vis absorption with a maximum molar extinction coefficient of 24,136 M-1 cm(-1) at lambda(max) = 458 nm and the best photovoltaic performance with an overall power conversion efficiency of 4.88%, while the dye with a carboxy group as an additional anchoring moiety exhibited the lowest conversion efficiency (4.52%). The results show that the dye loading on the film and photovoltaic performance of the dyes were influenced by the additional anchoring units. (C) 2013 Elsevier Ltd. All rights reserved.