(1-octyl)ferrocene

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: (1-octyl)ferrocene
• 英文别名: Octylferrocene
• 化学式: C₁₈H₂₆Fe
• 分子量: 298.251
• InChiKey: DRTCLTAOSAKXCN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.16
• 重原子数：
  19
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (1-octyl)ferrocene 在 silver nitrate 作用下， 以 not given 为溶剂， 生成 (1-octyl)ferricinium(1+)
  参考文献：
  名称：

  Alkylferrocenes: A simple preparation from lithioferrocenes and their aqueous electrochemistry

  摘要：

  Mono- and dialkylferrocenes are readily prepared by the nucleophilic substitution of n-alkyl halides with lithioferrocenes. The products can be purified by short-path distillation or recrystallization. Three alkylferrocenes were prepared by this synthetic strategy and characterized by cyclic voltammetry in aqueous solution. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00227-1
• 作为产物：
  描述：

  1-ferrocenyloctan-1-one 在 盐酸 、 汞 、 锌 作用下， 以 盐酸 为溶剂， 以71%的产率得到(1-octyl)ferrocene
  参考文献：
  名称：

  Notes- Even-Numbered n-Acyl and n-Alkyl Ferrocenes.

  摘要：

  DOI：

  10.1021/jo01063a618

文献信息

• Notes- Even-Numbered n-Acyl and n-Alkyl Ferrocenes.
  作者：Edwin DeYoung

  DOI：10.1021/jo01063a618

  日期：1961.4
• Lee Hanlan; Ugolick; Fulcher, Inorganic Chemistry, 1980, vol. 19, # 6, p. 1543 - 1551
  作者：Lee Hanlan、Ugolick、Fulcher、Togashi、Bocarsly、Gladysz

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Fe: Org.Verb.A1, 5.1.1.1.6, page 267 - 270
  作者：

  DOI：——

  日期：——
• Razuvaev, G. A.; Yudenich, S. G.; Druzhkov, O. N., Journal of general chemistry of the USSR, 1982, vol. 52, p. 2108 - 2109
  作者：Razuvaev, G. A.、Yudenich, S. G.、Druzhkov, O. N.、Dodonov, V. A.

  DOI：——

  日期：——
• Synthesis and electrochemical properties of mono- and (�)-1,2-dialkylferrocenes and alkylferrocenium hexafluorophosphates in aqueous and micellar media
  作者：M. A. Bazhenova、S. S. Bogush、A. G. Herbst、T. V. Demeshchik、Yu. G. Komarovskaya、V. S. Kurova、M. D. Reshetova、A. D. Ryabov、E. S. Ryabova、Yu. N. Frrsova

  DOI：10.1007/bf01435401

  日期：1996.10

  Simple methods have been developed for the preparation of a series of n-alkylferrocenes H(CH2)(n)Fc (n = 3, 5-8, or 12) based on Friedel-Crafts acylation of ferrocenes followed by reduction of the corresponding ketones with Zn amalgam. The properties of H(CH2)(n)Fc and the corresponding ferrocenium ions in micellar aqueous solutions and the behavior of water-soluble cations H(CH2)(n)Fc(+) in the absence of micelles were studied by cyclic voltammetry. In all cases, the formal redox potentials of ferrocenes (E(o)') increase linearly as n increases up to 8. Whether micelles are present or not, the corresponding correlation equation has the following form: E(o)' = alpha + beta n, where beta approximate to 29 mV in all cases. The synthesis of (+/-)-1-ethyl-2-methylferrocene from racemic alpha-dimethylaminoethylferrocene is reported.