4-(1-oxoperfluorooctyl)-2-perfluorooctylphenol

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-(1-oxoperfluorooctyl)-2-perfluorooctylphenol
• 英文别名: 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluoro-1-[3-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctyl)-4-hydroxyphenyl]octan-1-one
• 化学式: C₂₂H₄F₃₂O₂
• 分子量: 908.221
• InChiKey: KTWAGFWTKYUZEH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12
• 重原子数：
  56
• 可旋转键数：
  14
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.68
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  34

反应信息

• 作为反应物：
  描述：

  4-(1-oxoperfluorooctyl)-2-perfluorooctylphenol 在 三乙胺 、 三氯化磷 作用下， 以 乙醚 为溶剂， 反应 2.0h， 以95%的产率得到tris-(4-(1-oxoperfluorooctyl)-2-perfluorooctylphenyl)phosphite
  参考文献：
  名称：

  Unexpected synthesis of a new highly fluorocarbon soluble phosphite for biphasic catalysis

  摘要：

  The synthesis of tris(4-(1-oxoperfluorooctyl)-2-perfluorooctylphenyl)phosphite and tris(2,4-bis(perfluorooctyl)phenyl)phosphite from commercially available 1-iodoperfluorooctane and 2,4-dibromophenol is described. The stability and the solubility of these new compounds are reported. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)00639-5
• 作为产物：
  描述：

  全氟辛基碘烷 、 2,4-二溴苯酚 在 铜 作用下， 以 二甲基亚砜 为溶剂， 反应 20.0h， 以55%的产率得到4-(1-oxoperfluorooctyl)-2-perfluorooctylphenol
  参考文献：
  名称：

  Unexpected synthesis of a new highly fluorocarbon soluble phosphite for biphasic catalysis

  摘要：

  The synthesis of tris(4-(1-oxoperfluorooctyl)-2-perfluorooctylphenyl)phosphite and tris(2,4-bis(perfluorooctyl)phenyl)phosphite from commercially available 1-iodoperfluorooctane and 2,4-dibromophenol is described. The stability and the solubility of these new compounds are reported. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)00639-5

文献信息

• Unexpected synthesis of a new highly fluorocarbon soluble phosphite for biphasic catalysis
  作者：Thomas Mathivet、Eric Monflier、Yves Castanet、André Mortreux、Jean-Luc Couturier

  DOI：10.1016/s0040-4039(99)00639-5

  日期：1999.5

  The synthesis of tris(4-(1-oxoperfluorooctyl)-2-perfluorooctylphenyl)phosphite and tris(2,4-bis(perfluorooctyl)phenyl)phosphite from commercially available 1-iodoperfluorooctane and 2,4-dibromophenol is described. The stability and the solubility of these new compounds are reported. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.