二氨基三硝基苯 | 26616-30-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 二氨基三硝基苯
• 英文名称: 1,2-diamino-3,4,5-trinitrobenzene
• 英文别名: Diaminotrinitrobenzene；3,4,5-trinitrobenzene-1,2-diamine
• CAS: 26616-30-8
• 化学式: C₆H₅N₅O₆
• 分子量: 243.136
• InChiKey: DWSHPNQTKZNJFW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  190
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  N,N’-二(对甲苯磺酰基)-1,2-苯二胺 在 硫酸 、 硝酸 作用下， 以 溶剂黄146 为溶剂， 反应 4.0h， 生成 二氨基三硝基苯
  参考文献：
  名称：

  Tuning the synthesis of a dinitroaromatic towards a new trinitroaromatic stabilized energetic material

  摘要：

  在1,2-二氨基苯的高稀释条件下，制备了二氨基三硝基苯的新异构体3，其中两个NH2电子给体基团提高了1,2,3-三硝基苯主链的热稳定性。其热分解仅在230℃左右开始，爆燃发生在298℃，这对于耐热炸药来说很有意义。在不同的稀释条件下，已知的1,2-二氨基-4,5-二硝基苯4的晶体结构也被报道，并揭示了有趣的范德华和分子间N-H⋯O-N氢键相互作用。

  DOI：

  10.1039/b412789g

文献信息

• SYSTEMS AND METHODS FOR CHEMICAL AND/OR MECHANICAL REMEDIATION OF NITRO COMPOUNDS AND NITRATE ESTERS
  申请人：Lubbe Carl Hermanus

  公开号：US20110041718A1

  公开（公告）日：2011-02-24

  Systems and methods for chemoremediation or mechanical destruction of undetonated explosive materials. An explosive apparatus contains an explosive material in close proximity to a chemical reagent selected for its chemoremediative properties. A barrier is interposed between the explosive material and the chemical reagent to delay the chemoremediation of the explosive material. Alternatively a water expandable material may be incorporated into the explosive material, whereby upon exposure to moisture the water absorbing material will expand sufficiently to fragment the explosive material into initiation insensitive particles. Initiation insensitivity is achieved by incorporation of water, which acts as a desensitizing agent as well as fragmenting the explosive material into particles sufficiently small that they are below the critical diameter for explosive initiation. The present invention also relates to self-degradable, shaped explosive formulations, comprising an explosive material and a water expandable material.

  化学修复或机械破坏未爆炸物质的系统和方法。爆炸装置包含一种爆炸物质，与一种选择其化学修复性能的化学试剂密切接触。在爆炸物质和化学试剂之间插入一道障碍物，以延迟爆炸物质的化学修复。或者，可将一种可膨胀的吸水材料并入爆炸物质中，当暴露于水分时，吸水材料将膨胀足够大，将爆炸物质分解成启动不敏感的颗粒。通过加入水来实现启动不敏感性，水既起到减敏剂的作用，又将爆炸物质分解成足够小的颗粒，使它们小于爆炸启动的临界直径。本发明还涉及自降解的成形爆炸配方，包括一种爆炸物质和一种可膨胀的吸水材料。
• Self-degradable explosive formulations
  申请人：Maxamcorp Holding, S.L.

  公开号：EP2305624A1

  公开（公告）日：2011-04-06

  The present invention relates to self-degradable, shaped explosive formulations, comprising a molecular explosive and a water-swellable polymer.

  本发明涉及可自降解的定型炸药制剂，包括分子炸药和水溶性聚合物。
• GAS GENERATING AGENT COMPOSITION HAVING REDUCED SOLID DISCHARGE AMOUNT OF INFLATOR
  申请人：Samsong Industries Ltd.

  公开号：EP3000799A1

  公开（公告）日：2016-03-30

  A gas generating agent for an inflator is an explosive composition required for expanding an airbag to protect passengers when a car accident occurs. An electrical signal detected by a sensor due to a car crash may cause the ignition and combustion of an igniter, an ignition charge, and a gas generating agent of the inflator in order. Gases and a high-temperature melting compound generated by the combustion of the gas generating agent are cooled and filtered through a filter to expand the airbag. In order for the high-temperature melting compound to be effectively cooled and filtered through the filter, the high-temperature melting compound must be converted into slag. In the present invention, by converting the high-temperature melting compound into the slag by using zeolite [Na4Al4Si4O25H18] or dolomite [CaMg(CO3)2] as a slag forming agent, and allowing an amount of combustion residuals discharged into the interior of the airbag during the operation of the inflator to be equal to or less than 1g, which is a standard value specified in USCAR-24, damage to the airbag can be prevented and passengers can be effectively protected.

  气体发生器的气体发生剂是一种爆炸性成分，用于在发生车祸时膨胀安全气囊以保护乘客。车祸导致的传感器检测到的电信号可依次点燃和燃烧气体发生器的点火器、点火炸药和气体发生剂。气体发生剂燃烧产生的气体和高温熔融化合物通过过滤器冷却和过滤，使安全气囊膨胀。为了使高温熔融化合物有效冷却并通过过滤器过滤，必须将高温熔融化合物转化为熔渣。在本发明中，通过使用沸石[Na4Al4Si4O25H18]或白云石[CaMg(CO3)2]作为熔渣形成剂，将高温熔融化合物转化为熔渣，并允许在气体发生器工作期间排入安全气囊内部的燃烧残余物量等于或小于 1g（这是 USCAR-24 中规定的标准值），可以防止安全气囊受损，并有效保护乘客。
• REDOX-ACTIVE CHROMOPHORE MOLECULES AND DEVICES UTILIZING THE SAME
  申请人：YEDA RESEARCH AND DEVELOPMENT CO., LTD.

  公开号：EP3228624A2

  公开（公告）日：2017-10-11

  A compound of general formula I: and a sensor device comprising said compound which is configured and operable for sensing at least one predetermined liquid or gas substance.

  通式 I 的化合物： 以及包含上述化合物的传感器装置，该装置经配置可用于感应至少一种预定的液体或气体物质。
• Perforating systems with insensitive high explosive
  申请人：Halliburton Energy Services, Inc.

  公开号：US10746002B2

  公开（公告）日：2020-08-18

  The disclosure relates to perforating systems for perforating the casing of a wellbore. The perforating systems contain insensitive high explosives. The disclosure also relates to shaped charges containing insensitive high explosives for use in such perforating systems. The disclosure further relates to methods of using such perforating systems to perforate the casing of a wellbore.

  本公开涉及用于穿孔井筒套管的穿孔系统。穿孔系统含有不敏感的烈性炸药。本公开还涉及用于此类穿孔系统的含有不敏感烈性炸药的定型装药。本公开还涉及使用这种穿孔系统对井筒套管进行穿孔的方法。