5-vinyl-8-hydroxyquinoline

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 5-vinyl-8-hydroxyquinoline
• 英文别名: 5-ethenylquinolin-8-ol
• 化学式: C₁₁H₉NO
• 分子量: 171.199
• InChiKey: YYSAQRFXEUTRAR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  33.1
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  cadmium(II) acetate dihydrate 、 5-vinyl-8-hydroxyquinoline 、 2-cyano-3-(8-hydroxyquinolin-5-yl)acrylic acid 以 四氢呋喃 、 甲醇 为溶剂， 反应 12.0h， 以56%的产率得到
  参考文献：
  名称：

  一种8-羟基喹啉衍生物合镉配合物染料敏化剂(BDTT-VCd)及其制备方法与用途

  摘要：

  本发明涉及如式1所示的一种D(‑A‑π‑A)2型8‑羟基喹啉衍生物合镉配合物染料敏化剂(BDTT‑VCd)及其制备方法与用途。该染料敏化剂是以含有辅助电子受体(A)、π桥、主电子受体(A)和锚定基团等功能团的8‑羟基喹啉衍生物合镉配合物通过Heck偶联与电子给体(D)苯并二噻吩联二噻吩(BDTT)反应合成的D(‑A‑π‑A)2型配合物。实验以该配合物为染料敏化剂的染料敏化太阳能电池的光伏性能测试表现出较好的效果：光电转化效率(PCE)达到8.26％，染料热稳定性高，其热分解温度达到了280℃以上，能满足作为光伏材料的需求，这将在染料敏化太阳能电池的基础开发应用方面具有一定的前景。

  公开号：

  CN113354667B
• 作为产物：
  描述：

  8-羟基-5-喹啉羧醛 在 sodium hydride 、 三乙胺 作用下， 以 四氢呋喃 、 氯仿 为溶剂， 反应 26.0h， 生成 5-vinyl-8-hydroxyquinoline
  参考文献：
  名称：

  一种亚胺衍生物与8-羟基喹啉衍生物合镉配合物染料敏化剂及其制备方法与用途

  摘要：

  本发明涉及式1所示的一种D(‑A‑π‑A)2型亚胺衍生物与8‑羟基喹啉衍生物合镉配合物染料敏化剂(BDTT‑PCd)及其制备方法与用途。该染料敏化剂是以含有辅助电子受体(A)、π桥、主电子受体(A)和锚定基团等功能团的亚胺衍生物与8‑羟基喹啉衍生物合镉配合物通过Heck偶联反应与电子给体(D)苯并二噻吩联二噻吩（BDTT）反应合成的D(‑A‑π‑A)2配合物。实验以BDTT‑PCd为染料敏化剂的染料敏化太阳能电池光伏性能测试表现出较好的效果：光电转化效率（PCE）达到8.82%，染料热分解温度达到了320℃以上，热稳定性高，能满足光伏材料的需求，这将在染料敏化太阳能电池的开发应用方面具有一定的前景。式1，配合物BDTT‑PCd的结构。

  公开号：

  CN112279870B

文献信息

• FINE ZINC OXIDE PARTICLES, PROCESS FOR PRODUCING THE SAME, AND USE THEREOF
  申请人：NIPPON SHOKUBAI KAGAKU KOGYO CO. LTD.

  公开号：EP0768277A1

  公开（公告）日：1997-04-16

  A process for producing zinc oxide fine particles comprising heating a mixture comprising a zinc source, a carboxyl-containing compound, and an alcohol; a process for producing zinc oxide-polymer composite particles, which comprises heating a mixture comprising a zinc source, a carboxyl-containing compound, a polymer, and an alcohol at a temperature of 100°C or higher; a process for producing inorganic compound particles having on their surface a cluster of thin plate like zinc oxide crystals with their tip projecting outward, which comprises heating a mixture comprising a zinc source, a carboxyl-containing compound, lactic acid or a compound thereof, and an alcohol at a temperature of 100°C or higher; a process for producing zinc oxide-based particles comprising heating a mixture comprising a zinc source, a carboxyl-containing compound, at least one element additive selected from the group consisting of the group IIIB metal elements and the group IVB metal elements, and an alcohol at a temperature of 100°C or higher; zinc oxide-based fine particles obtained by these processes; and uses of the zinc oxide-based fine particles.

  一种生产氧化锌微粒的工艺，包括加热由锌源、含羧基化合物和醇组成的混合物；一种生产氧化锌-聚合物复合微粒的工艺，包括在100℃或更高温度下加热由锌源、含羧基化合物、聚合物和醇组成的混合物；一种生产无机化合物颗粒的工艺，该无机化合物颗粒表面有一簇尖端向外突出的薄板状氧化锌晶体，该工艺包括在 100°C 或更高温度下加热由锌源、含羧基化合物、乳酸或其化合物和醇组成的混合物；一种生产氧化锌基微粒的工艺，包括在 100℃或更高温度下加热由锌源、含羧基化合物、至少一种选自 IIIB 族金属元素和 IVB 族金属元素组成的组的元素添加剂以及醇组成的混合物；通过这些工艺获得的氧化锌基微粒；以及氧化锌基微粒的用途。
• Zinc oxide-based fine particles, process for producing the same, and use thereof
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP0893409A1

  公开（公告）日：1999-01-27

  A process for producing zinc oxide fine particles comprising heating a mixture comprising a zinc source, a carboxyl-containing compound, and an alcohol; a process for producing zinc oxide-polymer composite particles, which comprises heating a mixture comprising a zinc source, a carboxyl-containing compound, a polymer, and an alcohol at a temperature of 100°C or higher; a process for producing inorganic compound particles having on their surface a cluster of thin plate like zinc oxide crystals with their tip projecting outward, which comprises heating a mixture comprising a zinc source, a carboxyl-containing compound, lactic acid or a compound thereof, and an alcohol at a temperature of 100°C or higher; a process for producing zinc oxide-based particles comprising heating a mixture comprising a zinc source, a carboxyl-containing compound, at least one element additive selected from the group consisting of the group IIIB metal elements and the group IVB metal elements, and an alcohol at a temperature of 100°C or higher; zinc oxide-based fine particles obtained by these processes; and uses of the zinc oxide-based fine particles.

  一种生产氧化锌微粒的工艺，包括加热由锌源、含羧基化合物和醇组成的混合物；一种生产氧化锌-聚合物复合微粒的工艺，包括在100℃或更高温度下加热由锌源、含羧基化合物、聚合物和醇组成的混合物；一种生产无机化合物颗粒的工艺，该无机化合物颗粒表面有一簇尖端向外突出的薄板状氧化锌晶体，该工艺包括在 100°C 或更高温度下加热由锌源、含羧基化合物、乳酸或其化合物和醇组成的混合物；一种生产氧化锌基微粒的工艺，包括在 100℃或更高温度下加热由锌源、含羧基化合物、至少一种选自 IIIB 族金属元素和 IVB 族金属元素组成的组的元素添加剂以及醇组成的混合物；通过这些工艺获得的氧化锌基微粒；以及氧化锌基微粒的用途。
• Imprinted polymer and method for preparing the same
  申请人：Universite De Toulon

  公开号：US10683378B2

  公开（公告）日：2020-06-16

  An imprinted polymer that is not electrically conductive is obtained by polymerization of at least one monomer with at least one crosslinking agent in the presence of a target. The polymer has in its structure at least one cavity having the shape of a target and at least one redox probe assuming either a polymerizable form or a non-polymerizable form. Methods are for preparing an imprinted polymer, for detecting a target implementing such a polymer. The polymer is used as a sensor, and more particularly an imprinted sensor, an active interface to manufacture electrochemical (bio)sensors, or to manufacture solid-phase extraction substrates.

  一种不导电的压印聚合物是通过至少一种单体与至少一种交联剂在目标物存在的情况下进行聚合而得到的。聚合物的结构中至少有一个具有目标物形状的空腔和至少一个可聚合或不可聚合的氧化还原探针。制备压印聚合物的方法，以及用这种聚合物检测目标物的方法。这种聚合物可用作传感器，特别是压印传感器，也可用作制造电化学（生物）传感器或制造固相萃取基质的活性界面。
• POLYMÈRE À EMPREINTE ET PROCÉDÉ DE PRÉPARATION
  申请人：Université de Toulon

  公开号：EP2935376B1

  公开（公告）日：2019-06-12
• IMPRINTED POLYMER AND METHOD FOR PREPARING THE SAME
  申请人：UNIVERSITE DE TOULON

  公开号：US20150344607A1

  公开（公告）日：2015-12-03

  An imprinted polymer that is not electrically conductive is obtained by polymerization of at least one monomer with at least one crosslinking agent in the presence of a target. The polymer has in its structure at least one cavity having the shape of a target and at least one redox probe assuming either a polymerizable form or a non-polymerizable form. Methods are for preparing an imprinted polymer, for detecting a target implementing such a polymer. The polymer is used as a sensor, and more particularly an imprinted sensor, an active interface to manufacture electrochemical (bio)sensors, or to manufacture solid-phase extraction substrates.