2,3-butanediol diglycidyl ether

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 英文名称: 2,3-butanediol diglycidyl ether
• 英文别名: 2-[3-(Oxiran-2-ylmethoxy)butan-2-yloxymethyl]oxirane；2-[3-(oxiran-2-ylmethoxy)butan-2-yloxymethyl]oxirane
• 化学式: C₁₀H₁₈O₄
• 分子量: 202.251
• InChiKey: PKLOCHBLBMUEFT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  14
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  43.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  环氧氯丙烷 、 2,3-丁二醇 在 三氟化硼乙醚 、 potassium hydroxide 作用下， 反应 9.0h， 以85.87%的产率得到2,3-butanediol diglycidyl ether
  参考文献：
  名称：

  2,3-丁二醇二缩水甘油醚及其制备方法

  摘要：

  本发明提供了2,3‑丁二醇二缩水甘油醚及其制备方法。其制备的方法包括，2,3‑丁二醇与环氧氯丙烷开环反应生成中间产物氯醇醚，氯醇醚与碱反应合成2,3‑丁二醇二缩水甘油醚粗产品，粗品经过纯化的步骤获得2,3‑丁二醇二缩水甘油醚纯品。本发明获得产品环氧值为9.28%~9.92%，室温25℃的黏度为28~35mPa·S，与环氧树脂E‑44混合固化后混合物吸水率相比环氧树脂原料降低16~22%。

  公开号：

  CN106496162A

文献信息

• CURABLE SHEET COMPOSITION
  申请人：Nemoto Takashi

  公开号：US20100247924A1

  公开（公告）日：2010-09-30

  A curable sheet composition able to follow up a mold shape under the application of heat and pressure, able to polymerize and cure upon being irradiated with light, permitting an optical element molding pattern to be fixed, and comprising 50% to 94% of a polycarbonate diol-modified urethane acrylate oligomer, 5% to 40% of a (meth)acrylate containing at least one carboxyl group in each molecule thereof, and 0.5% to 5% of a photopolymerization initiator.

  一种可治愈的片状组合物，能够在加热和压力的作用下跟随模具形状，能够在受到光照后聚合和固化，允许光学元件成型图案被固定，包括50％至94％的聚碳酸酯二醇改性脲基丙烯酸酯低聚物，5％至40％的（甲）基丙烯酸酯，其中每个分子至少含有一个羧基，以及0.5％至5％的光聚合引发剂。
• CURABLE RESIN COMPOSITION
  申请人：Threebond Co., Ltd.

  公开号：EP3527620A1

  公开（公告）日：2019-08-21

  A liquid thermally expandable curable resin composition for use such as bonding by filling a clearance has difficulty in achieving both drying property and film forming property and also has a problem with storage stability. The problems were solved with a curable resin composition having the following composition. A curable resin composition comprises: (A) a film forming resin, (B) an epoxy resin, (C) an organic solvent, (D) thermally expandable particles, and (E) a curing agent ingredient for the (B). The (C) is selected from organic solvents having a boiling point of 100°C or less and being liquid at normal temperature and contains a combination of (C-1) an ester-based solvent and (C-2) one or more solvents selected from ketone-based solvents, ether-based solvents, and glycol-based solvents, and a content ratio between the (C-1) and the (C-2) in a mass ratio is in a range of (C-l)/(C-2) = 0.12 to 0.23.

  用于填充间隙进行粘合等用途的液态热膨胀性可固化树脂组合物在实现干燥性能和成膜性能方面存在困难，在储存稳定性方面也存在问题。具有以下组成的可固化树脂组合物解决了这些问题。可固化树脂组合物包括：(A) 成膜树脂；(B) 环氧树脂；(C) 有机溶剂；(D) 热膨胀性颗粒；(E) (B) 的固化剂成分。(C)选自沸点为 100℃或以下且在常温下为液态的有机溶剂，包含(C-1)酯基溶剂和(C-2)选自酮基溶剂、醚基溶剂和乙二醇基溶剂的一种或多种溶剂的组合，且(C-1)和(C-2)的质量比范围为(C-l)/(C-2)=0.12 至 0.23。
• OPTICAL ARTICLE WITH A DURABILITY IMPROVED HARD COATING
  申请人：ESSILOR INTERNATIONAL

  公开号：EP3923038A1

  公开（公告）日：2021-12-15

  The present invention relates to an optical article comprising a substrate having at least one main surface coated with a coating comprising at least one layer of an abrasion and/or scratch-resistant coating, wherein the abrasion and/or scratch-resistant coating is formed from a composition comprising at least one epoxy compound bearing at least one silicon atom having at least one hydrolysable group directly linked to the silicon atom and at least one group comprising an epoxy function linked to the silicon atom through a carbon atom, and/or a hydrolysate thereof, at least one plasticizer, a silane hydrolysate and colloidal silica, wherein the total amount of plasticizer in the composition is lower than 10wt% of the dry extract of the total composition, and wherein the weight ratio of silane of formula (I) to plasticizer is higher than 0.4 in the dry exact of the composition. The invention further relates to a process for the manufacture of such an abrasion and/or scratch-resistant coating on a substrate.

  本发明涉及一种光学制品，该光学制品包括基底，该基底至少有一个主表面涂有一层涂层，该涂层包括至少一层耐磨和/或抗划伤涂层，其中耐磨和/或抗划伤涂层由一种组合物形成，该组合物包括至少一种环氧化合物，该环氧化合物含有至少一个硅原子，该硅原子上有至少一个与硅原子直接相连的可水解基团和至少一个通过碳原子与硅原子相连的环氧官能团、和/或其水解物、至少一种增塑剂、硅烷水解物和胶体二氧化硅，其中组合物中增塑剂的总量低于总组合物干萃取物的 10wt%，式（I）硅烷与增塑剂的重量比高于组合物干萃取物的 0.4。本发明进一步涉及在基材上制造这种耐磨和/或抗划伤涂层的工艺。
• Curable resin composition
  申请人：THREEBOND CO., LTD.

  公开号：US11091676B2

  公开（公告）日：2021-08-17

  A liquid thermally expandable curable resin composition for use such as bonding by filling a clearance has difficulty in achieving both drying property and film forming property and also has a problem with storage stability. The problems were solved with a curable resin composition having the following composition. A curable resin composition comprises: (A) a film forming resin, (B) an epoxy resin, (C) an organic solvent, (D) thermally expandable particles, and (E) a curing agent ingredient for the (B). The (C) is selected from organic solvents having a boiling point of 100° C. or less and being liquid at normal temperature and contains a combination of (C-1) an ester-based solvent and (C-2) one or more solvents selected from ketone-based solvents, ether-based solvents, and glycol-based solvents, and a content ratio between the (C-1) and the (C-2) in a mass ratio is in a range of (C-1)/(C-2)=0.12 to 0.23.

  用于填充间隙进行粘合等用途的液态热膨胀性可固化树脂组合物在实现干燥性能和成膜性能方面存在困难，在储存稳定性方面也存在问题。具有以下组成的可固化树脂组合物解决了这些问题。可固化树脂组合物包括：(A) 成膜树脂；(B) 环氧树脂；(C) 有机溶剂；(D) 热膨胀性颗粒；(E) (B) 的固化剂成分。(C)选自沸点为 100℃或以下且在常温下为液态的有机溶剂，包含(C-1)酯基溶剂和(C-2)一种或多种选自酮基溶剂、醚基溶剂和乙二醇基溶剂的溶剂组合，且(C-1)和(C-2)的质量比范围为(C-1)/(C-2)=0.12 至 0.23。
• TYRE FOR VEHICLE WHEELS
  申请人：Pirelli Tyre S.p.A.

  公开号：EP2931802A1

  公开（公告）日：2015-10-21