二环[2.2.1]庚-5-烯-2-酮,1,7,7-三甲基-,(1S,4R)- | 15099-93-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 二环[2.2.1]庚-5-烯-2-酮,1,7,7-三甲基-,(1S,4R)-
• 英文名称: (1R)-bornen-(2)-one-(6)
• 英文别名: (1R)-Bornen-(2)-on-(6)；Dehydrocampher；(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]hept-5-en-2-one
• CAS: 15099-93-1；22516-10-5；104832-00-0
• 化学式: C₁₀H₁₄O
• 分子量: 150.221
• InChiKey: BQJYIYRCGDNPLN-XVKPBYJWSA-N

物化性质

• 沸点：
  197.0±9.0 °C(Predicted)
• 密度：
  1.013±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  二环[2.2.1]庚-5-烯-2-酮,1,7,7-三甲基-,(1S,4R)- 在 palladium on activated charcoal 、 溶剂黄146 作用下， 生成 白樟油
  参考文献：
  名称：

  Asahina; Ishidate; Tukamoto, Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan, 1936, vol. 56, p. 395,398

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 aluminum isopropoxide 作用下， 生成 二环[2.2.1]庚-5-烯-2-酮,1,7,7-三甲基-,(1S,4R)-
  参考文献：
  名称：

  Maelkoenen, Annales Academiae Scientiarum Fennicae, Series A2: Chemica, 1964, # 128, p. 30,41

  摘要：

  DOI：

文献信息

• Interlaminar fracture and low-velocity impact of carbon/epoxy composite materials
  作者：J. H. Hwang、O. Kwon、C. S. Lee、W. Hwang

  DOI：10.1007/bf02681828

  日期：2000.3

  The interlaminar fracture and the low-velocity impact behavior of carbon/epoxy composite materials have been studied using width-tapered double cantilever beam (WTDCB), end-notched flexure (ENF), and Boeing impact specimens. The objectives of this research are to determine the essential parameters governing interlaminar-fracture and damage of realistic laminated composites and to characterize a correlation between the critical strain energy release rates measured by interlaminar fracture and by low-velocity impact tests. The geometry and the lay-tip sequence of specimens are designed to probe various conditions such as the skewness parameter, beam volume, and test fixture. The effect of interfacial ply orientations and crack propagation directions on interlaminar fracture toughness and the effect of ply orientations and thickness on impact behavior ar-e examined. The critical strain energy release rare was calculated from the respective tests: in the interlaminar fracture test the compliance method and linear beam theory are used; the residual energy calculated from the impact test and the total delamination area estimated by ultrasonic inspection are used ill the low-velocity, impact test. Results show that the critical strain energy release rate is affected mainly by ply orientations. The critical strain energy release rate measured by the low-velocity impact test lies between the mode I and mode II critical strain energy release rates obtained by the interlaminar fracture test.
• Asahina; Ishidate; Tsukamoto, Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan, 1936, vol. 56, p. 395,397
  作者：Asahina、Ishidate、Tsukamoto

  DOI：——

  日期：——