二环己基过氧化物 | 1758-61-8

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 中文名称: 二环己基过氧化物
• 英文名称: dicyclohexyl peroxide
• 英文别名: dicyclohexylperoxide；cyclohexyl peroxide；cyclohexylperoxycyclohexane
• CAS: 1758-61-8
• 化学式: C₁₂H₂₂O₂
• 分子量: 198.305
• InChiKey: FYLJKQFMQFOLSZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2909600000

反应信息

• 作为反应物：
  描述：

  二环己基过氧化物 生成 环己酮
  参考文献：
  名称：

  DRULINER, J. D.;KITSON, F. G.;RUDAT, M. A.;TOLMAN, C. A., J. ORG. CHEM., 1983, 48, N 25, 4951-4953

  摘要：

  DOI：
• 作为产物：
  描述：

  环己烷 生成 二环己基过氧化物
  参考文献：
  名称：

  KRZYSZTOFORSKI, ANDRZEJ;BURGHARDT, ANDRZEJ;CIBOROWSKI, STANISLAW;PYZIKOWS+

  摘要：

  DOI：

文献信息

• FUNCTIONALIZED COPOLYMERS AND USE THEREOF
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20210031152A1

  公开（公告）日：2021-02-04

  An article that includes a functionalized copolymer and the use thereof, particularly in a process for binding biomaterials, such as in a process for separating aggregated proteins from monomeric proteins in a biological solution; wherein the article includes: a) a porous substrate; and b) a copolymer covalently attached to the porous substrate, the copolymer comprising a hydrocarbon backbone and a plurality of pendant groups attached to the hydrocarbon backbone, wherein 1) each of a first plurality of pendant groups comprises: (a) at least one acidic group or salt thereof; and (b) a spacer group that directly links the at least one acidic group or salt thereof to the hydrocarbon backbone by a chain of at least 6 catenated atoms; and 2) each of a second plurality of pendant groups comprises: (a) at least one acidic group or salt thereof; and (b) a spacer group that directly links the at least one acidic group or salt thereof to the hydrocarbon backbone by a chain of at least 6 catenated atoms; and wherein the first plurality of pendant groups are different than the second plurality of pendant groups; and wherein a mole ratio of the first plurality of pendant groups to the second plurality of pendant groups is in a range of 95:5 to 5:95.

  一篇包括功能化共聚物及其用途的文章，特别是在结合生物材料的过程中使用，例如在从生物溶液中分离聚集蛋白质和单体蛋白质的过程中；其中该文章包括：a) 多孔基底；和 b) 共价连接到多孔基底上的共聚物，该共聚物包括一个碳氢骨架和多个连接到碳氢骨架上的挂链基团，其中1) 第一多数挂链基团中的每一个包括：(a) 至少一个酸性基团或其盐；和 (b) 一个通过至少6个串联原子链直接将至少一个酸性基团或其盐连接到碳氢骨架的空间基团；和 2) 第二多数挂链基团中的每一个包括：(a) 至少一个酸性基团或其盐；和 (b) 一个通过至少6个串联原子链直接将至少一个酸性基团或其盐连接到碳氢骨架的空间基团；其中第一多数挂链基团不同于第二多数挂链基团；并且第一多数挂链基团与第二多数挂链基团的摩尔比在95:5到5:95的范围内。
• [EN] PROCESSES FOR SEPARATING AGGREGATED PROTEINS FROM MONOMERIC PROTEINS IN A BIOLOGICAL SOLUTION<br/>[FR] PROCÉDÉS DE SÉPARATION DE PROTÉINES AGRÉGÉES À PARTIR DE PROTÉINES MONOMÈRES DANS UNE SOLUTION BIOLOGIQUE
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2018048698A1

  公开（公告）日：2018-03-15

  A process for separating aggregated proteins from monomeric proteins in a biological solution, the process including: providing at least one filter element having a contacting surface, wherein the filter element comprises filter media comprising: a porous substrate; and disposed on the porous substrate, a polymer comprising a hydrocarbon backbone and a plurality of pendant groups attached to the hydrocarbon backbone, wherein each of a first plurality of pendant groups comprises: (1) at least one acidic group or salt thereof; and (2) a spacer group that directly links the at least one acidic group or salt thereof to the hydrocarbon backbone by a chain of at least 6 catenated atoms; and allowing an initial biological solution to contact the contacting surface of the filter element under conditions effective to separate the aggregated proteins from the monomeric proteins such that a final biological solution includes purified monomeric proteins.

  一种从生物溶液中分离聚集蛋白质和单体蛋白质的方法，该方法包括：提供至少一个具有接触表面的过滤元件，其中过滤元件包括包括过滤介质的多孔基质；并且在多孔基质上设置了一种聚合物，该聚合物包括一个烃骨架和附着在烃骨架上的多个偏基团，其中第一多个偏基团中的每一个包括：（1）至少一个酸性基团或其盐；和（2）一个间隔基团，通过至少6个串联原子的链将至少一个酸性基团或其盐直接连接到烃骨架；并且允许初始生物溶液在有效条件下接触过滤元件的接触表面，以使聚集蛋白质与单体蛋白质分离，从而得到含有纯化单体蛋白质的最终生物溶液。
• SYSTEM AND METHOD FOR PREPARING CYCLOALKANONE
  申请人：Tsai Yau-Ching

  公开号：US20090264682A1

  公开（公告）日：2009-10-22

  A system and a method for preparing cycloalkanone are provided. The method includes the steps of: (a) oxidizing cycloalkane to form a mixture containing ketone, alcohol and unreacted cycloalkane; (b) adding to the mixture alkali metal hydroxide or alkali metal carbonate to form a first mixed solution; (c) separating the first mixed solution into a first organic phase solution and a first aqueous phase solution; and (d) extracting the first organic phase solution by water to obtain a second organic phase solution and a second aqueous phase solution; and (e) distilling the second organic phase to separate out cycloalkanone. The method performs phase separation after a mixing step, and then performs water extraction, thereby effectively lowering the contents of the metal salts in the organic phases. Compared with acid-water extraction, the method not only provides better cooling effects but also reduces equipment corrosion, and therefore has the advantage of decreasing the need for sewage treatments.

  提供了一种制备环烷酮的系统和方法。该方法包括以下步骤：(a) 氧化环烷烃以形成含有酮、醇和未反应环烷烃的混合物；(b) 向混合物中添加碱金属氢氧化物或碱金属碳酸盐以形成第一混合溶液；(c) 将第一混合溶液分离为第一有机相溶液和第一水相溶液；(d) 通过水提取第一有机相溶液以获得第二有机相溶液和第二水相溶液；和 (e) 蒸馏第二有机相以分离出环烷酮。该方法在混合步骤后执行相分离，然后进行水提取，有效降低有机相中金属盐的含量。与酸水提取相比，该方法不仅提供更好的冷却效果，还减少了设备腐蚀，因此具有减少污水处理需求的优势。
• Method For Producing Ketone And/Or Alcohol, And System Thereof
  申请人：Ube Industries, Ltd.

  公开号：US20170313641A1

  公开（公告）日：2017-11-02

  This invention provides producing having an objective ketone and/or alcohol by decomposing of a hydrocarbon compound rapidly and selectively having a same number of carbon atoms as a hydrocarbon compound by decomposing a hydroperoxide in a reaction solution obtained from oxidizing the hydrocarbon compound using molecular oxygen of this invention involves, a hydroperoxide decomposition step for decomposing the hydroperoxide into the ketone and/or alcohol by contacting the reaction solution with an aqueous solution containing a carbonate of an alkaline earth metal or a carbonate of an alkali metal and a transition metal compound, a separation step for separating into an oil phase comprising the ketone and/or alcohol, and a water phase comprising the carbonate of an alkaline earth metal or carbonate of an alkali metal and the transition metal compound, a recovery step for recovering the carbonate of an alkali metal or carbonate of an alkaline earth metal and the transition metal compound by combusting the water phase, and a recycling step for recycling to the hydroperoxide decomposition step by dissolving at least the carbonate of the alkali metal or the carbonate of the alkaline earth metal among the recovered substances obtained from the recovery step in water.

  这项发明提供了通过将烃化合物氧化得到的反应溶液中的过氧化物分解，快速和选择性地生产具有与烃化合物相同碳原子数的目标酮和/或醇的方法。该方法涉及将烃化合物氧化得到的反应溶液中的过氧化物分解为酮和/或醇的过程，包括以下步骤：将反应溶液与含有碱土金属的碳酸盐或碱金属的碳酸盐以及过渡金属化合物的水溶液接触，将过氧化物分解为酮和/或醇的过氧化物分解步骤；将酮和/或醇组成的油相与碱土金属的碳酸盐或碱金属的碳酸盐以及过渡金属化合物组成的水相分离的分离步骤；通过燃烧水相回收碱金属的碳酸盐或碱土金属的碳酸盐和过渡金属化合物的回收步骤；通过将从回收步骤得到的回收物中至少溶解碱金属的碳酸盐或碱土金属的碳酸盐的水溶液回收碱金属的碳酸盐或碱土金属的碳酸盐和过渡金属化合物的循环步骤。
• PROCESS FOR PREPARING ALKYL HYDROPEROXIDE COMPOUNDS
  申请人：Bellenger Fabien

  公开号：US20120283482A1

  公开（公告）日：2012-11-08

  A method for making alkyl hydroperoxide compounds, specifically the preparation of cyclohexyl hydroperoxide is described. The preparation of cyclohexyl hydroperoxide by means of the oxidation of cyclohexane by oxygen in a multi-stage reactor or in reactors connected in series is also described. In these methods, the reactor surfaces in contact with the oxidation medium can be protected by a layer of heat-resistant PFA polymer.

  描述了一种制备烷基过氧化物化合物的方法，具体是环己基过氧化物的制备。还描述了通过在多级反应器或串联反应器中将环己烷氧化为环己基过氧化物的方法。在这些方法中，与氧化介质接触的反应器表面可以通过一层耐热PFA聚合物进行保护。