2,3-difluoro-4-(trans-4-pentylcyclohexylmethoxy)benzene

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2,3-difluoro-4-(trans-4-pentylcyclohexylmethoxy)benzene
• 英文别名: 1,2-difluoro-3-[(4-pentylcyclohexyl)methoxy]benzene
• 化学式: C₁₈H₂₆F₂O
• 分子量: 296.401
• InChiKey: HDIYLPKPMOEUBR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  21
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  硼酸三甲酯 、 2,3-difluoro-4-(trans-4-pentylcyclohexylmethoxy)benzene 在 仲丁基锂 、 盐酸 、 水 作用下， 以 四氢呋喃 、 正己烷 、 环己烷 为溶剂， 以89%的产率得到2,3-difluoro-4-(trans-4-pentylcyclohexylmethoxy)phenylboronic acid
  参考文献：
  名称：

  TETRA- OR PENTA-CYCLIC LIQUID CRYSTALLINE COMPOUND HAVING LATERAL FLUORINE, LIQUID CRYSTAL COMPOSITION, AND LIQUID CRYSTAL DISPLAY ELEMENT

  摘要：

  公开号：

  EP2206695B1
• 作为产物：
  描述：

  trans-4-chloromethyl-1-pentylcyclohexane 、 2,3-二氟苯酚 在 potassium phosphate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 7.0h， 以95.1%的产率得到2,3-difluoro-4-(trans-4-pentylcyclohexylmethoxy)benzene
  参考文献：
  名称：

  TETRA- OR PENTA-CYCLIC LIQUID CRYSTALLINE COMPOUND HAVING LATERAL FLUORINE, LIQUID CRYSTAL COMPOSITION, AND LIQUID CRYSTAL DISPLAY ELEMENT

  摘要：

  公开号：

  EP2206695B1

文献信息

• FOUR- OR FIVE-RING LIQUID CRYSTAL COMPOUND HAVING LATERAL FLUORINE, LIQUID CRYSTAL COMPOSITION, AND LIQUID CRYSTAL DISPLAY DEVICE
  申请人：Kobayashi Masahide

  公开号：US20100309402A1

  公开（公告）日：2010-12-09

  The invention provides a liquid crystal compound having stability to heat, light and so forth, a wide temperature range of a nematic phase, a small viscosity, a suitable optical anisotropy, and a suitable elastic constant K 33 , and further having a suitable and negative dielectric anisotropy and an excellent compatibility with other liquid crystal compounds, and a liquid crystal composition having stability to heat, light and so forth, a low viscosity, a large optical anisotropy, a suitable and negative dielectric anisotropy, and a suitable elastic constant K 33 , a low threshold voltage, a high maximum temperature (phase-transition temperature on a nematic phase-isotropic phase) of a nematic phase, and a low minimum temperature of the nematic phase. The liquid crystal compound which has a specific structure having fluorine at a lateral position and also having phenylene in which hydrogen on the benzene ring is replaced by fluorine, and a liquid crystal composition containing the compound are prepared.

  本发明提供了一种液晶化合物，具有耐热、耐光等稳定性，广泛的向列相温度范围，低粘度，适当的光学各向异性和适当的弹性常数K33，进一步具有适当且负的介电各向异性和与其他液晶化合物优异的相容性，以及一种液晶组合物，具有耐热、耐光等稳定性，低粘度，大的光学各向异性，适当且负的介电各向异性，适当的弹性常数K33，低阈值电压，向列相的高最大温度（向列相-等向相相变温度）和低向列相的最低温度。制备了一种具有侧位氟和苯环上氢被氟取代的苯基的特定结构的液晶化合物以及含有该化合物的液晶组合物。
• LIQUID CRYSTAL COMPOUND HAVING XANTHENE SKELETON AND EXHIBITING NEGATIVE DIELECTRIC ANISOTROPY, LIQUID CRYSTAL COMPOSITION, AND LIQUID CRYSTAL DISPLAY ELEMENT
  申请人：JNC Corporation

  公开号：EP2987790A1

  公开（公告）日：2016-02-24

  To provide a liquid crystal compound satisfying at least one of physical properties such as a high stability to heat, light and so forth, a high clearing point, a low minimum temperature of a liquid crystal phase, a small viscosity, a suitable optical anisotropy, a large negative dielectric anisotropy, a suitable elastic constant and an excellent compatibility with other liquid crystal compounds. The compound is represented by formula (1). In the formula, for example, R1 and R2 are alkyl having 1 to 15 carbons; ring A1 and ring A2 are 1,4-cyclohexylene or 1,4-phenylene, Z1 and Z2 are a single bond, -(CH2)2-, -CH=CH-, -C≡C-, -COO-, -OCO-, -CH2O-, -OCH2-, -CF2O-, -OCF2- or -CF=CF-, a and b are 0, 1 or 2, and a sum of a and b is 1 or 2.

  提供一种液晶化合物，它至少满足以下物理特性中的一项：对热、光等的高稳定性、高澄明点、低液晶相最低温度、小粘度、适当的光学各向异性、大的负介电各向异性、适当的弹性常数以及与其他液晶化合物的良好兼容性。 该化合物用式（1）表示。 例如，在式中，R1 和 R2 是具有 1 至 15 个碳原子的烷基；环 A1 和环 A2 是 1,4-环己烯或 1,4-亚苯基，Z1 和 Z2 是单键、-(CH2)2-、-CH=CH-、-C≡C-、-COO-、-OCO-、-CH2O-、-OCH2-、-CF2O-、-OCF2- 或-CF=CF-，a 和 b 是 0、1 或 2，a 和 b 之和是 1 或 2。
• LIQUID CRYSTAL COMPOUND HAVING XANTHENE SKELETON AND EXHIBITING NEGATIVE DIELECTRIC ANISOTROPY, LIQUID CRYSTAL COMPOSITION AND LIQUID CRYSTAL DISPLAY DEVICE
  申请人：JNC CORPORATION

  公开号：US20160068754A1

  公开（公告）日：2016-03-10

  A liquid crystal compound satisfies at least one of physical properties such as a high stability to heat, light and so forth, a high clearing point, a low minimum temperature of a liquid crystal phase, a small viscosity, a suitable optical anisotropy, a large negative dielectric anisotropy, a suitable elastic constant and an excellent compatibility with other liquid crystal compounds. The compound is represented by formula (1). In the formula, for example, R 1 and R 2 are alkyl having 1 to 15 carbons; ring A 1 and ring A 2 are 1,4-cyclohexylene or 1,4-phenylene, Z 1 and Z 2 are a single bond, —(CH 2 ) 2 —, —CH═CH—, —C≡C—, —COO—, —OCO—, —CH 2 O—, —OCH 2 —, —CF 2 O—, —OCF 2 — or —CF═CF—, a and b are 0, 1 or 2, and a sum of a and b is 1 or 2.
• US4925590A
  申请人：——

  公开号：US4925590A

  公开（公告）日：1990-05-15
• US5279764A
  申请人：——

  公开号：US5279764A

  公开（公告）日：1994-01-18