5-bromopicene

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 5-bromopicene
• 英文别名: 5-Bromopicene
• 化学式: C₂₂H₁₃Br
• 分子量: 357.249
• InChiKey: KTAIYEDBIBXRJO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  23
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  硼酸三甲酯 、 5-bromopicene 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 10.0h， 以71%的产率得到Picen-5-ylboronic acid
  参考文献：
  名称：

  化合物、有机电致发光元件用材料、有机电致 发光元件和电子设备

  摘要：

  提供更高性能的、特别是驱动电压和外量子效率良好、且长寿命化的有机电致发光元件和具有该有机电致发光元件的电子设备。进而提供用于实现它们的化合物。具体地，提供具有三亚苯骨架的特定结构的化合物、使用了该化合物的有机电致发光元件、以及具有该有机电致发光元件的电子设备。

  公开号：

  CN105473600B
• 作为产物：
  描述：

  苉 在 溴 作用下， 以 氯苯 为溶剂， 反应 33.0h， 以75%的产率得到5-bromopicene
  参考文献：
  名称：

  π-f轨道相互作用的首次证明，取决于Eu（iii）发光体的配位几何。

  摘要：

  这里，证明了取决于Eu（iii）络合物中的配位几何形状的π-f轨道相互作用。热分析和计算计算表明，基于配位几何结构的变化，Eu（iii）配合物的相变。在Eu（iii）配合物中发现了相移相关的红移LMCT谱带和辐射速率变化。

  DOI：

  10.1039/d0dt00528b

文献信息

• RARE-EARTH COMPLEX, LIGHT-EMITTING MATERIAL, LIGHT-EMITTING OBJECT, LIGHT-EMITTING DEVICE, INTERLAYER FOR LAMINATED GLASS, LAMINATED GLASS, WINDSHIELD FOR VEHICLE, WAVELENGTH CONVERSION MATERIAL, AND SECURITY MATERIAL
  申请人：NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITY

  公开号：US20210269460A1

  公开（公告）日：2021-09-02

  Disclosed is a rare-earth complex including a rare-earth ion, and a ligand coordinate-bonded to the rare-earth ion and having a condensed polycyclic aromatic group. The condensed polycyclic aromatic group is a residue formed by removing a hydrogen atom bonded to a condensed aromatic ring from a condensed polycyclic aromatic compound represented by the following Formula (I). In Formula (I), R 1 and R 2 represent hydrogen atoms or groups which are bonded to each other to form one aromatic ring or a condensed aromatic ring including two or more aromatic rings.

  本发明涉及一种稀土络合物，包括稀土离子和配体，配体以配位键与稀土离子结合，并具有紧凑多环芳香基团。所述紧凑多环芳香基团是由从以下式（I）所表示的紧凑多环芳香化合物中去除结合在紧凑芳香环上的氢原子形成的残基。 在式（I）中，R1和R2表示与彼此相连形成一个芳香环或包括两个或更多芳香环的紧缩芳香环的氢原子或基团。
• ORGANIC ELECTROLUMINESCENT DEVICE AND MATERIAL FOR ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP2166585A1

  公开（公告）日：2010-03-24

  An organic electroluminescence device includes: a cathode; an anode; and a single-layered or multilayered organic thin-film layer provided between the cathode and the anode. In the organic electroluminescence device, the organic thin-film layer includes an emitting layer, and the emitting layer contains: a phosphorescent material; and a host material represented by the following formula (1).         Ra-Ar1-Ar2-Rb     (1) In the formula, Ar1, Ar2, Ra and Rb each represent a substituted or unsubstituted benzene ring or a substituted or unsubstituted fused aromatic hydrocarbon group selected from a group consisting of a naphthalene ring, a chrysene ring, a fluoranthene ring, a triphenylene ring, a phenanthrene ring, a benzophenanthrene ring, a dibenzophenanthrene ring, a benzotriphenylene ring, a benzochrysene ring, a picene ring and a benzo[b]fluoranthene ring.

  一种有机电致发光器件包括：阴极；阳极；以及设置在阴极和阳极之间的单层或多层有机薄膜层。在有机电致发光器件中，有机薄膜层包括发光层，发光层包含：磷光材料；以及由下式（1）表示的主材料。 Ra-Ar1-Ar2-Rb (1) 式中，Ar1、Ar2、Ra 和 Rb 分别代表一个取代或未取代的苯环，或一个取代或未取代的融合芳香烃基团，该基团选自由以下组成的组菊烯环、荧蒽环、三亚苯环、菲环、苯并菲环、二苯并菲环、苯并三亚 苯环、苯并菊烯环、噻吩环和苯并[b]荧蒽环。
• ORGANIC ELECTROLUMINESCENCE DEVICE AND MATERIAL FOR ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：NISHIMURA Kazuki

  公开号：US20090009067A1

  公开（公告）日：2009-01-08

  An organic electroluminescence device includes: a cathode; an anode; and a single-layered or multilayered organic thin-film layer provided between the cathode and the anode. In the organic electroluminescence device, the organic thin-film layer includes at least one emitting layer, and the at least one emitting layer contains: at least one phosphorescent material; and a host material represented by the following formula (1). Ra—Ar 1 —Ar 2 —Rb   (1) In the formula, Ar 1 , Ar 2 , Ra and Rb each represent a substituted or unsubstituted benzene ring or a substituted or unsubstituted condensed aromatic hydrocarbon group selected from a group consisting of a naphthalene ring, a chrysene ring, a fluoranthene ring, a triphenylene ring, a phenanthrene ring, a benzophenanthrene ring, a dibenzophenanthrene ring, a benzotriphenylene ring, a benzochrysene ring, a picene ring and a benzo[b]fluoranthene ring.
• COMPOUND, MATERIAL FOR ORGANIC ELECTROLUMINESCENT ELEMENTS, ORGANIC ELECTROLUMINESCENT ELEMENT AND ELECTRONIC DEVICE
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20160343950A1

  公开（公告）日：2016-11-24

  An organic electroluminescence device having higher performance, in particular exhibiting a better driving voltage and a better external quantum efficiency, while having an extended lifetime; and an electronic equipment provided with the organic electroluminescence device are provided. In addition, a compound for realizing the same device and equipment is provided. Specifically, a compound having a specific structure having a triphenylene skeleton; an organic electroluminescence device using the compound; and an electronic equipment provided with the organic electroluminescence device were provided.
• US8154195B2
  申请人：——

  公开号：US8154195B2

  公开（公告）日：2012-04-10