(Z)-allyl 3-((dimethylcarbamoyl)oxy)but-2-enoate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (Z)-allyl 3-((dimethylcarbamoyl)oxy)but-2-enoate
• 英文别名: prop-2-enyl (Z)-3-(dimethylcarbamoyloxy)but-2-enoate
• 化学式: C₁₀H₁₅NO₄
• 分子量: 213.233
• InChiKey: FLVUPPCTFRMCRV-FPLPWBNLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  55.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  乙酰乙酸烯丙酯 、 N,N-二甲基甲酰胺 在 叔丁基过氧化氢 、 copper(II) oxide 作用下， 以 水 为溶剂， 反应 4.0h， 生成 (Z)-allyl 3-((dimethylcarbamoyl)oxy)but-2-enoate
  参考文献：
  名称：

  通过甲酰胺与1,3-二羰基化合物的氧化偶联，高效超声辅助合成烯醇氨基甲酸酯

  摘要：

  已经报道了通过CuO纳米颗粒作为催化剂和叔丁基氢过氧化物（TBHP）作为氧化剂的甲酰胺与相应的氨基甲酸酯中的1，3-二羰基化合物的声化学氧化偶联。在优化的反应条件下，合成了烯醇氨基甲酸酯的各种衍生物，产率高到高。与常规方法相比，此方法的主要优点是条件温和。

  DOI：

  10.2174/1570178617666191126095420

文献信息

• Anchoring of a Copper(II)–Schiff Base Complex onto Silica-Coated Ferrite Nanoparticles: A Magnetically Separable Catalyst for Oxidative C–O Coupling by Direct C(sp2)–H and C(sp3)–H Bond Activation
  作者：Rashid Ghanbaripour、Marjaneh Samadizadeh、Golnaz Honarpisheh、Majid Abdolmohammadi

  DOI：10.1055/s-0035-1560067

  日期：——

  A novel catalyst consisting of a Schiff base-copper complex on surface-modified silica-coated ferrite nanoparticles was been prepared and used for oxidative C-O cross-coupling reactions of 1,3-dicarbonyl compounds with formamides for the synthesis of enol carbamates. The new catalyst has also been used for esterification of alkylbenzenes with cyclic ethers.
• Copper nanoparticles on charcoal: an effective nanocatalyst for the synthesis of enol carbamates and amides via an oxidative coupling route
  作者：Dariush Saberi、Sakineh Mansoori、Esmali Ghaderi、Khodabakhsh Niknam

  DOI：10.1016/j.tetlet.2015.11.072

  日期：2016.1

  The catalytic activity of copper nanoparticles on charcoal (Cu/C) was investigated as an environmentally friendly heterogeneous catalyst for the synthesis of enol carbamates and amides via the oxidative coupling of N,N-dialkyl formamides with 1,3-dicarbonyl compounds and aromatic aldehydes with amine hydrochloride salts, respectively. Various enol carbamates and amides were synthesized in moderate to good yields using this method. Moreover, the catalyst could be recovered and subsequently reused in further reactions. (C) 2015 Elsevier Ltd. All rights reserved.
• CuO nanoparticles supported on α-Fe2O3-modified CNTs: a magnetically separable catalyst for oxidative C–O coupling of formamides with 1,3-dicarbonyl compounds
  作者：Dariush Saberi、Akbar Heydari

  DOI：10.1016/j.tetlet.2013.05.113

  日期：2013.8

  Oxidative coupling of formamides with 1,3-dicarbonyl compounds to prepare enol carbamates was effected in the presence of CuO nanoparticles supported on alpha-Fe2O3-modified carbon nanotubes (CNTs@alpha-Fe2O3@CuO) as an environmentally friendly heterogeneous catalyst. The simple preparation, and the ability to be recycled and magnetically separated are salient features of this catalytic system. (C) 2013 Elsevier Ltd. All rights reserved.
• An Efficient Ultrasonic-Assisted Synthesis of Enol Carbamates via Oxidative Coupling of Formamides with 1,3-Dicarbonyl Compounds
  作者：Jafar Akbari、Alireza Akbari Meyestani

  DOI：10.2174/1570178617666191126095420

  日期：2020.7.7

  Sonochemical oxidative-coupling of formamides with 1,3-dicarbonyl compounds in the corresponding carbamates by CuO nanoparticles as a catalyst and tert-butyl hydroperoxide (TBHP) as an oxidant has been reported. Various derivatives of enol carbamates were synthesized with good to high yields under the optimized reaction conditions. Compared with conventional methods, the main advantage of this method

  已经报道了通过CuO纳米颗粒作为催化剂和叔丁基氢过氧化物（TBHP）作为氧化剂的甲酰胺与相应的氨基甲酸酯中的1，3-二羰基化合物的声化学氧化偶联。在优化的反应条件下，合成了烯醇氨基甲酸酯的各种衍生物，产率高到高。与常规方法相比，此方法的主要优点是条件温和。