allenyloxy radical

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: allenyloxy radical
• 化学式: C₃H₃O
• 分子量: 55.0562
• InChiKey: BTQIYASRNJTPKS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  丙二烯 在 氧气 作用下， 以 gaseous matrix 为溶剂， 生成 formyl radical 、 乙烯 、 乙烯基自由基 、 allenyloxy radical 、 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Crossed molecular beam study of the reaction O(³P)+allene

  摘要：

  The reaction between ground state (3P) oxygen atoms and allene was studied under single collision conditions using the crossed molecular beams method. Product angular distributions and the translational energy distribution were determined for each channel. Two major reaction channels could be identified unambiguously: the formation of carbon monoxide and ethylene following oxygen atom attack on the central carbon atom, and the formation of allenyloxy (formyl–vinyl) radical and hydrogen atom following oxygen atom attack on the terminal carbon atom. In addition, at least one other reaction channel, which could be identified as the production of vinyl and formyl radicals, occurs. This channel involves the decomposition of acrolein which is formed by the addition of oxygen to the terminal carbon atom, followed by 1,2-hydrogen migration.

  DOI：

  10.1063/1.465334

文献信息

• Crossed molecular beam study of the reaction O(³<i>P</i>)+allene
  作者：A. M. Schmoltner、S. Y. Huang、R. J. Brudzynski、P. M. Chu、Y. T. Lee

  DOI：10.1063/1.465334

  日期：1993.8

  The reaction between ground state (3P) oxygen atoms and allene was studied under single collision conditions using the crossed molecular beams method. Product angular distributions and the translational energy distribution were determined for each channel. Two major reaction channels could be identified unambiguously: the formation of carbon monoxide and ethylene following oxygen atom attack on the central carbon atom, and the formation of allenyloxy (formyl–vinyl) radical and hydrogen atom following oxygen atom attack on the terminal carbon atom. In addition, at least one other reaction channel, which could be identified as the production of vinyl and formyl radicals, occurs. This channel involves the decomposition of acrolein which is formed by the addition of oxygen to the terminal carbon atom, followed by 1,2-hydrogen migration.