bis(2-acryloyloxyethyl) malonate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: bis(2-acryloyloxyethyl) malonate
• 英文别名: Bis(2-prop-2-enoyloxyethyl) propanedioate
• 化学式: C₁₃H₁₆O₈
• 分子量: 300.265
• InChiKey: GWGHVTLYKCWHCW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  21
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  105
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  bis(2-acryloyloxyethyl) malonate 、 环戊二烯 在 zinc(II) chloride 作用下， 反应 24.0h， 以83%的产率得到bis[4-(bicyclo[2.2.1]hept-5-en-2-yl)-4-oxo-3-oxabutyl] malonate
  参考文献：
  名称：

  Synthesis and ring-opening metathesis polymerization of fullerene-containing α,ω-bis-norbornenes

  摘要：

  Metathesis polymerization of bis[4-(bicyclo[2.2.1]hept-5-en-2-yl)-4-oxo-3-oxabutyl]cyclopropa[1,9]-C-60-fullerene-3',3'-dicarboxylate affords insoluble polymer, while a copolymer with the parent malonate is soluble in typical organic solvents.

  DOI：

  10.1016/j.mencom.2015.05.014
• 作为产物：
  描述：

  丙二酰氯 、 丙烯酸羟乙酯 以 吡啶 为溶剂， 生成 bis(2-acryloyloxyethyl) malonate
  参考文献：
  名称：

  Synthesis and ring-opening metathesis polymerization of fullerene-containing α,ω-bis-norbornenes

  摘要：

  Metathesis polymerization of bis[4-(bicyclo[2.2.1]hept-5-en-2-yl)-4-oxo-3-oxabutyl]cyclopropa[1,9]-C-60-fullerene-3',3'-dicarboxylate affords insoluble polymer, while a copolymer with the parent malonate is soluble in typical organic solvents.

  DOI：

  10.1016/j.mencom.2015.05.014

文献信息

• Photopolymerization initiator and photosensitive composition employing the same
  申请人：CANON KABUSHIKI KAISHA

  公开号：EP0353030B1

  公开（公告）日：1995-03-15
• INK-JET INK COMPOSITION FOR ETCHING RESIST
  申请人：Sato Masaki

  公开号：US20110024392A1

  公开（公告）日：2011-02-03

  An ink composition for ink jet printing is provided which gives a cured object excellent in adhesion to metallic plates, resistance to etchants, and alkali removability and can be stably ejected with an ink jet apparatus. The ink jet composition for etching resists has a viscosity at 25° C. of 3-50 mPa s and includes monomers comprising: either a polymerizable phosphoric ester compound represented by general formula (I); a polyfunctional monomer having two or more ethylenic double-bond groups per molecule and having no phosphoric ester group, the content of the ethylenic double-bond groups being 4×10 −3 to 8×10 −3 mol/g; and a monofunctional monomer having one ethylenic double-bond group per molecule and having neither phosphoric ester group nor carboxy group. In the formula, X represents C 1-3 alkylene, Y represents C 2-3 alkylene, and R represents hydrogen or methyl.
• RESIN AND PHOTORESIST COMPOSITION COMPRISING SAME
  申请人：MASUYAMA Tatsuro

  公开号：US20120270154A1

  公开（公告）日：2012-10-25

  The present invention provides a resin comprising a structural unit derived from a compound represented by the formula (I): wherein R 1 represents a hydrogen atom or a methyl group, A 2 represents a divalent fluorine-containing C1-C12 hydrocarbon group, and A 1 represents a group represented by the formula (a-g1): A 10 -X 10  s A 11 -  (a-g1) wherein A 10 is independently in each occurrence a C1-C5 aliphatic hydrocarbon group, A 11 represents a C1-C5 aliphatic hydrocarbon group, X 10 is independently in each occurrence —O—, —CO—, —CO—O— or —O—CO—, and s represents an integer of 0 to 2, and a photoresist composition comprising the resin and an acid generator.
• US5124235A
  申请人：——

  公开号：US5124235A

  公开（公告）日：1992-06-23
• US6011119A
  申请人：——

  公开号：US6011119A

  公开（公告）日：2000-01-04