perfluoro-(1,1,9,9-tetrahydro-2,5-bistrifluoromethyl-3,6-dioxanonenol) | 174082-85-0

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代醇
• 英文名称: perfluoro-(1,1,9,9-tetrahydro-2,5-bistrifluoromethyl-3,6-dioxanonenol)
• 英文别名: Perfluoro(1,1,9,9-tetrahydro-2,5-bis(trifluoromethyl)-3,6-dioxa-8-nonen-1-ol)；2,3,3,3-tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2-trifluoroprop-2-enoxy)propoxy]propan-1-ol
• CAS: 174082-85-0
• 化学式: C₉H₅F₁₃O₃
• 分子量: 408.116
• InChiKey: UOELVWCFAMHMML-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  25
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  38.7
• 氢给体数：
  1
• 氢受体数：
  16

反应信息

• 作为反应物：
  描述：

  perfluoro-(1,1,9,9-tetrahydro-2,5-bistrifluoromethyl-3,6-dioxanonenol) 、 2-Fluoroprop-2-enoyl fluoride 在 吡啶 作用下， 以 乙醚 为溶剂， 反应 4.5h， 生成
  参考文献：
  名称：

  JP2005/350484

  摘要：

  公开号：

文献信息

• FLUOROOLEFIN, FLUOROPOLYMER, AND THERMOPLASTIC RESIN COMPOSITION CONTAINING THE POLYMER
  申请人：DAIKIN INDUSTRIES, LIMITED

  公开号：EP0728776A1

  公开（公告）日：1996-08-28

  To provide a fluorine-containing olefin represented, for example, by CH2=CFCF2-Rf6-(CH2)k-X2 [wherein, X2 is -CH2OH, Rf6 is a fluorine-substituted fluorine-containing alkyl group having 1 to 40 carbon atoms or -ORf7- (Rf7 is a fluorine-substituted fluorine-containing alkyl group having 1 to 40 carbon atoms or a fluorine-substituted fluorine-containing ether group having 3 to 50 carbon atoms), k is 0 or an integer of 1 to 6]; a fluorine-containing polymer with functional group which is prepared by polymerizing the above-mentioned olefin, has good affinity with various heat-resisting thermoplastic resins and is capable of forming homogeneous dispersion with the thermoplastic resin; and a thermoplastic resin composition comprising the above-mentioned fluorine-containing polymer with functional group and an aromatic polyester or the like as the heat-resisting thermoplastic resin.

  提供一种含氟烯烃，例如由CH2=CFCF2-Rf6-(CH2)k-X2[其中，X2是-CH2OH、 Rf6 是具有 1 至 40 个碳原子的氟取代的含氟烷基或-ORf7-（Rf7 是具有 1 至 40 个碳原子的氟取代的含氟烷基或具有 3 至 50 个碳原子的氟取代的含氟醚基），k 是 0 或 1 至 6 的整数]；通过聚合上述烯烃制备的含氟官能团聚合物，该聚合物与各种耐热热塑性树脂具有良好的亲和性，并能与热塑性树脂形成均匀的分散体；以及由上述含氟官能团聚合物和作为耐热热塑性树脂的芳香族聚酯或类似物组成的热塑性树脂组合物。
• FLUORINATED MATERIAL FOR COATING COMPOSITION AND METHOD OF COATING USING THE SAME
  申请人：DAIKIN INDUSTRIES, LIMITED

  公开号：EP0866107A1

  公开（公告）日：1998-09-23

  To provide a fluorine-containing coating material which gives excellent adhesive strength directly to a substrate such as metal, glass, etc. with maintaining excellent characteristics of the fluorine-containing polymer such as thermal resistance, chemical resistance, non-sticking property and low friction property, and a method for coating the material. The fluorine-containing coating material is prepared by using a fluorine-containing ethylenic polymer having functional group which is obtained by copolymerizing (a-1) 0.05 to 30 % by mole of at least one of fluorine-containing ethylenic monomers having any one of functional groups selected from hydroxyl, carboxyl, carboxylate salt group, carboxylate ester group or epoxy and (b-1) 70 to 99.95 % by mole of at least one of fluorine-containing ethylenic monomers having no functional group mentioned above.

  提供一种含氟涂层材料，该材料可直接与金属、玻璃等基材产生优异的粘合强度，同时保持含氟聚合物的优异特性，如耐热性、耐化学性、不粘性和低摩擦性，并提供一种涂覆该材料的方法。含氟涂层材料的制备方法是使用一种具有官能团的含氟乙烯聚合物，该聚合物是由(a-1)0.05%至 30%（以摩尔计）的至少一种具有从羟基、羧基、羧酸盐基、羧酸酯基或环氧基中任选一种官能团的含氟乙烯单体和(b-1)70%至 99.95%（以摩尔计）的至少一种不具有上述官能团的含氟乙烯单体共聚而成。
• FLUOROADHESIVE AND ADHESIVE FILM AND LAMINATE PREPARED THEREFROM
  申请人：DAIKIN INDUSTRIES, LIMITED

  公开号：EP0866108A1

  公开（公告）日：1998-09-23

  To provide a fluorine-containing adhesive which maintains thermal resistance, chemical resistance, weather resistance and electric insulating property and has strong adhesive property directly to substrates particularly metal and glass, and an adhesive film and laminated article which are obtained by using the fluorine-containing adhesive. There is used a fluorine-containing ethylenic polymer having hydroxyl which is prepared by copolymerizing 0.05 to 30 % by mole of at least one of fluorine-containing ethylenic monomers having hydroxyl and 70 to 99.95 % by mole of at least one of fluorine-containing ethylenic monomers copolymerizable with the above-mentioned monomer.

  提供一种保持耐热性、耐化学性、耐候性和电绝缘性并对基材（尤其是金属和玻璃）直接具有强粘合性的含氟粘合剂，以及使用该含氟粘合剂获得的粘合薄膜和层压制品。本发明使用了一种含氟乙烯基羟基聚合物，该聚合物是由 0.05% 至 30% （摩尔）的至少一种含氟乙烯基羟基单体和 70% 至 99.95% （摩尔）的至少一种可与上述单体共聚的含氟乙烯基单体共聚而成。
• COATING COMPOSITION, COATING FILM, AND PROCESS FOR THE PRODUCTION OF THE FILM
  申请人：DAIKIN INDUSTRIES, LIMITED

  公开号：EP0909800A1

  公开（公告）日：1999-04-21

  To provide the water-repellent coating film having excellent transparency, abrasion resistance, weather resistance and water repellency, the method for producing the coating film, the multi-functional composite material provided with the coating film and the coating composition used therefor which has excellent dispersion stability. The coating composition comprises (A) the fluorine-containing ethylenic polymer prepared by copolymerizing a fluorine-containing ethylenic monomer having at least one functional group selected from hydroxyl, carboxyl, a carboxylic salt group, a carboxylic ester group and epoxy, (B-1) the metal oxide sol, and (C) the solvent.

  提供具有优异透明度、耐磨性、耐候性和憎水性的憎水涂膜、该涂膜的生产方法、与该涂膜一起提供的多功能复合材料以及用于该涂膜的具有优异分散稳定性的涂料组合物。涂层组合物包括：(A) 含氟乙烯聚合物，其制备方法是共聚具有至少一个官能团的含氟乙烯单体，官能团选自羟基、羧基、羧酸盐基、羧酸酯基和环氧基；(B-1) 金属氧化物溶胶；(C) 溶剂。
• CHEMICAL-RESISTANT COMPOSITE MATERIAL
  申请人：Daikin Industries, Ltd.

  公开号：EP0976544A1

  公开（公告）日：2000-02-02

  A composite material having chemical resistance which is produced by applying, to a substrate, a material comprising a fluorine-containing polymer having an excellent adhesive property to the substrate without necessitating complicated steps. The composite material having chemical resistance is produced by applying, to the substrate, the material comprising a fluorine-containing ethylenic polymer having functional group which is prepared by copolymerizing (a) 0.05 to 30 % by mole of at least one of fluorine-containing ethylenic monomers having at least one functional group selected from the group consisting of hydroxyl, carboxyl, a carboxylic salt group, a carboxylic ester group and epoxy, and (b) 70 to 99.95 % by mole of at least one of fluorine-containing ethylenic monomers having no functional group mentioned above.

  一种具有耐化学性的复合材料，它是通过在基材上涂敷一种由含氟聚合物组成的材料而制成的，这种含氟聚合物与基材具有极佳的粘合性，无需复杂的步骤。这种具有耐化学腐蚀性的复合材料是通过在基底上涂敷由含氟乙烯聚合物组成的材料而制得的，这种含氟乙烯聚合物具有官能团，是通过共聚 (a) 0.05% 至 30% （以摩尔计）的至少一种含氟乙烯基单体，该单体具有至少一个选自羟基、羧基、羧酸盐基、羧酸酯基和环氧基的官能团；以及 (b) 70% 至 99.95% （以摩尔计）的至少一种不含上述官能团的含氟乙烯基单体。