tert-butyl (10-phenyl-9-anthryl)nitroxide

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: tert-butyl (10-phenyl-9-anthryl)nitroxide
• 英文别名: BPAN
• 化学式: C₂₄H₂₄NO
• 分子量: 342.461
• InChiKey: QLBNLZZXDDEGOO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  26
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  4.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  tert-butyl (10-phenyl-9-anthryl)nitroxide 在 Vitamin C 作用下， 以 甲醇 为溶剂， 反应 0.5h， 以96%的产率得到N-tert-butyl N-(10-phenyl-9-anthryl) hydroxylamine
  参考文献：
  名称：

  Scavenging and Characterization of Short-Lived Radicals Using a Novel Stable Nitroxide Radical with a Characteristic UV–vis Absorption Spectrum

  摘要：

  A stable tert-butyl(10-phenyl-9-anthryl)nitroxide (BPAN) radical was newly synthesized and used for the capture/characterization of reactive radicals. Adducts obtained from the reactions of BPAN with in situ generated reactive radicals showed excellent stability, assuring complete isolation and purification. The structures of the adducts were established by LC-MS and NMR analyses.

  DOI：

  10.1021/ol501328k
• 作为产物：
  描述：

  9-溴-10-苯基蒽 在 叔丁基锂 、 氧气 作用下， 以 四氢呋喃 、 甲苯 、 正戊烷 为溶剂， 生成 tert-butyl (10-phenyl-9-anthryl)nitroxide
  参考文献：
  名称：

  Scavenging and Characterization of Short-Lived Radicals Using a Novel Stable Nitroxide Radical with a Characteristic UV–vis Absorption Spectrum

  摘要：

  A stable tert-butyl(10-phenyl-9-anthryl)nitroxide (BPAN) radical was newly synthesized and used for the capture/characterization of reactive radicals. Adducts obtained from the reactions of BPAN with in situ generated reactive radicals showed excellent stability, assuring complete isolation and purification. The structures of the adducts were established by LC-MS and NMR analyses.

  DOI：

  10.1021/ol501328k

文献信息

• Scavenging and Characterization of Short-Lived Radicals Using a Novel Stable Nitroxide Radical with a Characteristic UV–vis Absorption Spectrum
  作者：Ryuta Toba、Hiroaki Gotoh、Kazuhisa Sakakibara

  DOI：10.1021/ol501328k

  日期：2014.8.1

  A stable tert-butyl(10-phenyl-9-anthryl)nitroxide (BPAN) radical was newly synthesized and used for the capture/characterization of reactive radicals. Adducts obtained from the reactions of BPAN with in situ generated reactive radicals showed excellent stability, assuring complete isolation and purification. The structures of the adducts were established by LC-MS and NMR analyses.