1-[9-ethyl-6-[2-methyl-4-[1-(2,2-dimethyl-1,3-dioxolan-4-yl)methyloxy]benzoyl]-9H-carbazol-3-yl]ethanone-1-(O-acetyl)oxime

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 1-[9-ethyl-6-[2-methyl-4-[1-(2,2-dimethyl-1,3-dioxolan-4-yl)methyloxy]benzoyl]-9H-carbazol-3-yl]ethanone-1-(O-acetyl)oxime
• 英文别名: N-acetoxy-1-[9-ethyl-6-{2-methyl-4-(3,3-dimethyl-2,4-dioxacyclopentanylmethyloxy)benzoyl}-9H-carbazol-3-yl]ethan-1-imine；[(E)-1-[6-[4-[(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]-2-methylbenzoyl]-9-ethylcarbazol-3-yl]ethylideneamino] acetate
• 化学式: C₃₂H₃₄N₂O₆
• 分子量: 542.632
• InChiKey: FJBTVNOKENFOFP-FMFFXOCNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  40
• 可旋转键数：
  9
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.34
• 拓扑面积：
  88.4
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  3-acetyl-6-(4-fluoro-2-methylbenzoyl)-9-ethylcarbazole 、 乙酸酐 、 丙酮缩甘油 在 四丁基硫酸氢铵 sodium hydroxide 、 盐酸羟胺 作用下， 以 异丁酰胺 为溶剂， 反应 5.0h， 以71.4%的产率得到1-[9-ethyl-6-[2-methyl-4-[1-(2,2-dimethyl-1,3-dioxolan-4-yl)methyloxy]benzoyl]-9H-carbazol-3-yl]ethanone-1-(O-acetyl)oxime
  参考文献：
  名称：

  OXIME ESTER COMPOUND AND PHOTOPOLYMERIZATION INITIATOR CONTAINING SUCH COMPOUND

  摘要：

  公开号：

  EP1780209B1

文献信息

• [EN] COLORED PHOTOSENSITIVE RESIN COMPOSITION AND LIGHT SHIELDING SPACER PREPARED THEREFROM<br/>[FR] COMPOSITION DE RÉSINE PHOTOSENSIBLE COLORÉE ET ÉLÉMENT D'ESPACEMENT PARE-LUMIÈRE PRÉPARÉ PAR CELLE-CI
  申请人：ROHM & HAAS ELECT MATERIALS KOREA LTD

  公开号：WO2017078271A1

  公开（公告）日：2017-05-11

  Disclosed herein is a colored photosensitive resin composition including a copolymer, an epoxy resin compound or a compound derived therefrom, a polymerizable compound, a photoinitiator, and a colorant, wherein the photoinitiator includes an oxime compound and a triazine compound. The composition, when formed into a cured film, may facilitate the fabrication of necessary height difference and satisfy the requirements of sensitivity and an exposure margin for light shielding spacers, and, thus, is useful as a material for manufacturing a light shielding spacer such as a black column spacer used in various electronic parts including the panels of an LCD and an OLED display.

  本文揭示了一种彩色光敏树脂组合物，包括共聚物、环氧树脂化合物或其衍生物、可聚合化合物、光引发剂和着色剂，其中光引发剂包括肟化合物和三嗪化合物。该组合物在形成固化膜时，可以促进所需高度差异的制造，并满足光屏蔽间隔器的灵敏度和曝光余量要求，因此，可用作制造光屏蔽间隔器的材料，例如在包括LCD和OLED显示面板在内的各种电子零件中使用的黑色柱状间隔器。
• COMPOUND AND COLORED RESIN COMPOSITION
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20210002487A1

  公开（公告）日：2021-01-07

  An object of the present invention is to provide a novel squarylium dye that can achieve an equivalent chromaticity value of even a colored resin composition having a low content of the squarylium dye as compared with a colored resin composition comprising a conventional squarylium dye. The present invention provides a compound represented by the formula (I) wherein R 4 to R 4 each independently represent a hydrogen atom or the like; R 5 to R 8 each independently represent a hydrogen atom or the like; R 9 and R 10 each independently represent a monovalent saturated hydrocarbon group having 1 to 20 carbon atoms or the like; R 11 and R 12 each independently represent a halogen atom or an alkyl halide group having 1 to 6 carbon atoms; and m1 and m2 each independently represent an integer of 1 to 5.

  本发明的一个目的是提供一种新型的方苯基染料，即使与含有传统方苯基染料的着色树脂组合相比，也可以实现具有低含量方苯基染料的着色树脂组合的等效色度值。本发明提供了一个由式（I）表示的化合物，其中R4到R4各自独立地表示氢原子或类似物；R5到R8各自独立地表示氢原子或类似物；R9和R10各自独立地表示具有1到20个碳原子的一价饱和碳氢基团或类似物；R11和R12各自独立地表示卤素原子或具有1到6个碳原子的烷基卤素基团；m1和m2各自独立地表示1到5的整数。
• COPOLYMER AND COLORED RESIN COMPOSITION
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20210047449A1

  公开（公告）日：2021-02-18

  A copolymer useful as an ingredient of a colored resin composition, comprising a structural unit derived from an aromatic carboxylic acid having an ethylenically unsaturated bond, a structural unit (Ab) represented by formula (Z), and a structural unit (Ac) derived from an unsaturated compound having a cyclic ether structure having 2 to 4 carbon atoms, wherein L represents a single bond or a divalent linking group, A represents a phenyl group optionally having a substituent other than a carboxy group or a naphthyl group optionally having a substituent other than a carboxy group, R a represents a hydrogen atom, or an alkyl group having 1 to 4 carbon atoms, and a hydrogen atom contained in the alkyl group is optionally replaced by a hydroxy group.

  一种共聚物，可用作有色树脂组分的成分，包括从含有乙烯基不饱和键的芳香族羧酸衍生的结构单元，由式（Z）表示的结构单元（Ab），以及从具有具有2到4个碳原子的环氧结构的不饱和化合物衍生的结构单元（Ac），其中L表示单键或二价连接基团，A表示苯基，可选地具有除羧基或萘基以外的取代基，Rarepresents表示氢原子或具有1到4个碳原子的烷基，烷基中的氢原子可选地被羟基取代。
• PHOTOSENSITIVE RESIN COMPOSITION, CURED FILM, ELEMENT PROVIDED WITH CURED FILM, AND METHOD FOR MANUFACTURING SEMICONDUCTOR DEVICE
  申请人：Toray Industries, Inc.

  公开号：EP3203320A1

  公开（公告）日：2017-08-09

  To provide a photosensitive resin composition which is capable of forming a pattern with high resolution and obtaining a cured film having excellent heat resistance and cracking resistance, and is also alkali developable; and a method capable of shortening the step required to remove a cured film of the composition after formation of an impurity region on a semiconductor substrate; and a method for manufacturing a semiconductor device using the same. Disclosed is a photosensitive resin composition including a polysiloxane (A), wherein the polysiloxane (A) is a polysiloxane represented by the general formula (1), and wherein (X) and (Y) are represented by the general formulas (4) to (6). 7.5≤X≤75 2.5≤Y≤40 1.5×Y≤X≤3×Y

  提供一种光敏树脂组合物，该组合物能够形成具有高分辨率的图案并获得具有优异的耐热性和抗裂性的固化膜，而且还可进行碱显影；提供一种方法，该方法能够缩短在半导体衬底上形成杂质区后去除该组合物固化膜所需的步骤；以及提供一种使用该组合物制造半导体器件的方法。公开了一种包括聚硅氧烷(A)的光敏树脂组合物，其中聚硅氧烷(A)是由通式(1)表示的聚硅氧烷，且(X)和(Y)由通式(4)至(6)表示。7.5≤x≤75 2.5≤y≤40 1.5×y≤x≤3×y
• CURABLE RESIN COMPOSITION, FILM, LAMINATE AND DISPLAY DEVICE
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP3875493A1

  公开（公告）日：2021-09-08

  An object of the present invention is to provide a curable composition comprising a fluorescent particle containing a perovskite compound and a photopolymerizable compound, with a good dispersibility of the above semiconductor particle to the above photopolymerizable compound; a film formed by curing the curable composition; and a laminated body and a display apparatus comprising the film. Provided are a curable composition comprising a fluorescent particle (A) containing a perovskite compound, a photopolymerizable compound (B), and a dispersing agent (C), wherein the dispersing agent (C) includes at least one kind of compound selected from the group consisting of phosphoric acid compounds, carboxylic acid compounds, sulfonic acid compounds, primary to tertiary amine compounds, quaternary ammonium compounds, and thiol compounds; a film formed by curing the curable composition; and a laminated body and a display apparatus comprising the film.

  本发明的目的是提供一种可固化组合物，该组合物包含一种含有包晶化合物和可光聚合化合物的荧光颗粒，上述半导体颗粒对上述可光聚合化合物具有良好的分散性；通过固化该可固化组合物形成的薄膜；以及包含该薄膜的层压体和显示装置。本发明提供了一种可固化组合物，该组合物包括含有过氧化物化合物的荧光颗粒（A）、可光聚合化合物（B）和分散剂（C），其中分散剂（C）包括至少一种选自磷酸化合物、羧酸化合物、磺酸化合物、伯至叔胺化合物、季铵化合物和硫醇化合物组成的组的化合物；通过固化该可固化组合物形成的薄膜；以及包含该薄膜的层压机身和显示设备。