1-propoxy-2-hexanol

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-propoxy-2-hexanol
• 英文别名: 1-Propoxyhexan-2-ol
• 化学式: C₉H₂₀O₂
• 分子量: 160.257
• InChiKey: NVAPRELWDNCHOZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  11
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  丁基环氧乙烷 、 丙醇 在 iron(III) perchlorate 作用下， 反应 0.33h， 以93%的产率得到1-propoxy-2-hexanol
  参考文献：
  名称：

  Ferric Perchlorate: An Efficient Reagent for Regio- and Stereoselective Alcoholysis and Hydrolysis of Epoxides

  摘要：

  Regio- and stereoselective ring opening reaction of epoxides is achieved efficiently by aliphatic alcohols and water in the presence of catalytic amounts of ferric perchlorate.

  DOI：

  10.1080/00397910008087447

文献信息

• A novel mononuclear Fe(iii) mono(terpyridine) complex having labile solvent ligands and its catalytic activityElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/dt/b2/b208413a/
  作者：Dong-Woo Yoo、Sang-Kun Yoo、Cheal Kim、Jin-Kyu Lee

  DOI：10.1039/b208413a

  日期：2002.10.29

  A novel Fe mono(terpyridine) complex was successfully prepared by deliberately choosing the polymer surface-anchored terpyridine as a chelating ligand and it showed an excellent catalytic activity with an easy reusability on the ring-opening reaction of various epoxides by alcohol and water under mild and neutral conditions to give stereospecific and regioselective products.

  通过特意选择聚合物表面锚定的萜吡啶作为螯合配体，成功制备了一种新型铁单（萜吡啶）配合物，该配合物在温和的中性条件下，对各种环氧化物与醇和水的开环反应具有极佳的催化活性，且易于重复使用，可得到立体选择性和区域选择性产物。
• Ferric Perchlorate: An Efficient Reagent for Regio- and Stereoselective Alcoholysis and Hydrolysis of Epoxides
  作者：Peyman Salehi、Behnam Seddighi、Mohsen Irandoost、Farahnaz Kargar Behbahani

  DOI：10.1080/00397910008087447

  日期：2000.8

  Regio- and stereoselective ring opening reaction of epoxides is achieved efficiently by aliphatic alcohols and water in the presence of catalytic amounts of ferric perchlorate.