N,N'-bis(dodecanoyl)-1,2-diaminocyclohexane

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: N,N'-bis(dodecanoyl)-1,2-diaminocyclohexane
• 英文别名: N-[2-(dodecanoylamino)cyclohexyl]dodecanamide
• 化学式: C₃₀H₅₈N₂O₂
• 分子量: 478.803
• InChiKey: OVJPMUAOGFRUHW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.5
• 重原子数：
  34
• 可旋转键数：
  22
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  58.2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  月桂酰氯 、 1,2-二氨基环己烷 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 以84%的产率得到N,N'-bis(dodecanoyl)-1,2-diaminocyclohexane
  参考文献：
  名称：

  Characteristics of Gelation by Amides Based on trans-1,2-Diaminocyclohexane: The Importance of Different Substituents

  摘要：

  六种二酰胺是由反式-(1R,2R)-1,2-二氨基环己烷及相应的外消旋体制备而成，随后用于凝胶化剂。制备了三种手性化合物及其外消旋体。其中一种手性化合物及其外消旋体包含两个n-十二酰氨基基团作为相同的取代基。其他两种手性化合物及其外消旋体则包含不同的取代基：10-十一烯酰氨基和2-庚基-十二酰氨基基团，以及5-羟基戊酸酰氨基和2-庚基-十二酰氨基基团。根据使用八种溶剂的最低凝胶浓度评估其凝胶化能力。通过紫外-可见光谱法研究了凝胶的热稳定性和透明性，采用十六烷基2-乙基己酸酯、液体石蜡和十甲基环五硅氧烷的三组分混合溶剂（66种组合）。还研究了凝胶到溶液的相变温度。通过流变学测量在应变扫描模式下研究了凝胶的粘弹性行为。通过透射电子显微镜和圆二色光谱法研究了构成三维网络的聚集体。通过小角X射线散射（SAXS）评估了凝胶的分子 packing。

  DOI：

  10.1246/bcsj.20160360

文献信息

• ANHYDROUS FLUID FILTERING COMPOSITION COMPRISING AN OILY PHASE, A PARTICULAR TRIAZINE FILTER AND AN OIL THICKENING OR GELLING RHEOLOGICAL AGENT
  申请人：Josso Martin

  公开号：US20110200543A1

  公开（公告）日：2011-08-18

  The present invention relates to an anhydrous fluid composition comprising, in a cosmetically acceptable medium: a) at least one oily phase and b) at least one particular triazine UV filter of formula (I) and c) at least one rheological agent for thickening or gelling the oily phase. The present invention also relates to the use of said composition for the manufacture of products for the cosmetic treatment of the skin, nails, hair, eyelashes, eyebrows and/or scalp, notably care products, sun protection products, make-up products.

  本发明涉及一种无水流体组合物，包括以下成分：a）至少一种油性相，b）至少一种特定的三嗪类紫外线过滤剂，其化学式为（I），以及c）至少一种流变剂，用于增稠或凝胶化油性相，所述组合物在美容上可接受的介质中。本发明还涉及使用该组合物制造用于皮肤、指甲、头发、睫毛、眉毛和/或头皮的化妆品治疗产品，特别是护肤产品、防晒产品、化妆品。
• COSMETIC COMPOSITION COMPRISING A SUPRAMOLECULAR COMPOUND CAPABLE OF ESTABLISHING HYDROGEN BONDS, AND A PARTICULAR ADDITIONAL INGREDIENT
  申请人：Barba Claudia

  公开号：US20130004438A1

  公开（公告）日：2013-01-03

  The present invention relates to a cosmetic composition comprising, in a cosmetically acceptable medium, (i) a supramolecular compound that may be obtained by reaction between: —at least one oil bearing at least one nucleophilic reactive function chosen from OH and NH 2 , and —at least one junction group capable of establishing hydrogen bonds with one or more partner junction groups, each pairing of a junction group involving at least three hydrogen bonds, the said junction group bearing at least one isocyanate or imidazole reactive function capable of reacting with the reactive function borne by the oil, the said junction group also comprising at least one unit of formula (I) or (II): (ii) and at least one additional ingredient preferably chosen from: —silicone elastomers, —polyesters that may be obtained by reacting: a tetraol containing from 4 to 10 carbon atoms; a saturated, linear or branched monocarboxylic acid containing from 9 to 23 carbon atoms; a cyclic dicarboxylic acid containing from 6 to 12 carbon atoms; and an aromatic monocarboxylic acid containing from 7 to 11 carbon atoms, —film-forming agents chosen from silicone resins and film-forming polymers, preferably chosen from the group comprising: a film-forming block ethylenic copolymer, a vinyl polymer comprising at least one carbosiloxane dendrimer-based unit, a dispersion of acrylic or vinyl radical homopolymer or copolymer particles dispersed in the said liquid fatty phase, —structuring agents chosen from semicrystalline polymers and thickeners comprising at least one group and preferably at least two groups capable of establishing hydrogen interactions, chosen from: polymeric thickeners, and organogelling agents. The invention also relates to a cosmetic treatment process comprising the application of the said composition.

  本发明涉及一种化妆品组合物，包括以下成分，均可用于化妆品中：（i）可通过以下反应得到的超分子化合物：至少含有一种带有OH或NH2的亲核反应功能的油，和至少含有一种能够与一种或多种配对结构单元建立氢键的连接基团，每个连接基团的配对都涉及至少三个氢键，所述连接基团带有至少一种异氰酸酯或咪唑反应功能，可与油中的反应功能发生反应，所述连接基团还包括至少一个式（I）或（II）的单元；（ii）至少一种其他成分，优选为以下成分之一：硅弹性体、聚酯物，可通过以下反应得到：含有4至10个碳原子的四元醇，含有9至23个碳原子的饱和线性或支链一元羧酸，含有6至12个碳原子的环状二元羧酸和含有7至11个碳原子的芳香族一元羧酸；膜形成剂，选择自硅树脂和膜形成聚合物，优选自以下组中选择：膜形成块乙烯共聚物、含有至少一个基于碳硅氧烷树枝状分子的乙烯基聚合物、丙烯酸或乙烯基自由基均聚物或共聚物粒子的分散液分散在所述液态脂肪相中；结构调节剂，选择自半晶态聚合物和增稠剂，包括至少一个羟基或酰胺基团，优选包括至少两个能够建立氢键相互作用的羟基或酰胺基团，选择自聚合增稠剂和有机凝胶剂。本发明还涉及一种化妆品处理过程，包括应用所述组合物。
• Liquid crystal device and process for fabricating liquid crystal device
  申请人：JSR Corporation

  公开号：EP0896048A1

  公开（公告）日：1999-02-10

  A liquid crystal device comprising a light adjusting layer which contains a liquid crystal gel which is composed from liquid crystal molecules and a gelling agent and which exhibits substantially no fluidity. Also provided are a gelling agent, particularly, 1,2-bis-(11-(4-cyanobiphenyl-4'-oxo)undecylcarbonylamino)cyclohexane, which is capable of easily producing the liquid crystal gel; a liquid crystal device made from the liquid crystal gel with substantially no fluidity; and a process for fabricating a liquid crystal device capable of providing this liquid crystal device rapidly in a simple manner.

  一种液晶装置，包括一个光调节层，该层含有液晶凝胶，该凝胶由液晶分子和胶凝剂组成，基本上没有流动性。此外，还提供了一种胶凝剂，特别是 1,2-双-(11-(4-氰基联苯-4'-氧代)十一烷基羰基氨基)环己烷，这种胶凝剂能够很容易地生成液晶凝胶；一种由液晶凝胶制成的基本上没有流动性的液晶器件；以及一种能够以简单的方式快速提供这种液晶器件的液晶器件制造工艺。
• Antiperspirant compositions
  申请人：Unilever Plc

  公开号：EP1177784A2

  公开（公告）日：2002-02-06

  Antiperspirant formulations containing an antiperspirant active and a continuous phase comprising a water-immiscible liquid carrier, such as, amongst other materials, cyclomethicones, that is structured using an amido-containing compound of the general formula in which R and R1 each independently denote a branched or unbranched moiety containing 5 to 27 carbon atoms, m and n are each independently, zero or 1, Y is a cyclohexane ring bearing the amido-containing substituent groups and in 1,2 or 1,3 positions.

  止汗剂配方，含有止汗剂活性物质和连续相，连续相包括不溶于水的液体载体，如环甲酮等材料，其结构为通式的含酰胺化合物 其中 R 和 R1 分别独立地表示含有 5 至 27 个碳原子的支链或不支链分子，m 和 n 分别独立地为 0 或 1，Y 为环己烷环，带有含酰胺基的取代基团 且 在 1,2 或 1,3 位。
• Cosmetic composition comprising a polyglycerolated silicone elastomer
  申请人：L'OREAL

  公开号：EP1579845A2

  公开（公告）日：2005-09-28

  The invention relates to a cosmetic composition containing, in at least one cosmetically acceptable medium, at least one polyglycerolated silicone elastomer and at least one ingredient chosen from at least one emulsifying elastomer different from the polyglycerolated silicone elastomer, at least one film forming polymer, at least one water-soluble humectant, at least one coated pigment, at least one structuring agent, at least one photoprotective system capable of screening out UV radiation, at least one non-emulsifying spherical silicone elastomer, at least one fiber, at least one non-crosslinked surfactant, with the proviso that the non-crosslinked surfactant is not chosen from polyglycerolated non-crosslinked silicone surfactants, at least one hydrocarbyl-functional siloxane, at least one low molecular weight phenyl-substituted siloxane and at least one cosmetically-suitable active ingredient.

  本发明涉及一种化妆品组合物，在至少一种化妆品可接受的介质中，含有至少一种聚甘油硅氧烷弹性体和至少一种成分，这些成分选自至少一种不同于聚甘油硅氧烷弹性体的乳化弹性体、至少一种成膜聚合物、至少一种水溶性保湿剂、至少一种涂层颜料、至少一种结构剂、至少一种能屏蔽紫外线辐射的光保护系统、至少一种非乳化球形硅树脂弹性体、 至少一种纤维、至少一种非交联表面活性剂，但该非交联表面活性剂不得选自聚甘油 非交联硅树脂表面活性剂、至少一种烃基官能团硅氧烷、至少一种低分子量苯基取代硅氧烷 和至少一种可用于化妆品的活性成分。