trithiophosphoric acid O-isobutyl ester

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: trithiophosphoric acid O-isobutyl ester
• 英文别名: Trithiophosphorsaeure-O-isobutylester；2-Methylpropoxy-bis(sulfanyl)-sulfanylidene-lambda5-phosphane；2-methylpropoxy-bis(sulfanyl)-sulfanylidene-λ5-phosphane
• 化学式: C₄H₁₁OPS₃
• 分子量: 202.303
• InChiKey: WJKQJQHHHJCZHB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  9
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  43.3
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  trithiophosphoric acid O-isobutyl ester 、 aluminum isopropoxide 以 苯 为溶剂， 以96%的产率得到Al[S2P(SH)OiBu]3
  参考文献：
  名称：

  Synthesis, Spectroscopic Studies, and Antifungal Activity of Tris(O-Alkyl or O-Aryltrithiophosphato) Aluminum(III)

  摘要：

  Aluminum(III) derivatives of O-alkyl or O-aryl trithiophosphate of the type Al[S2P(SH)OR](3) (R = Me, Et, Pr-i, Bu-i, Ph, CH2Ph) have been synthesized. The products were obtained as white powdery solids. The monomers are soluble in common organic solvents and were characterized by elemental analyses, molecular weight determinations, and IR and (H-1, Al-27, and P-31) NMR spectroscopic studies, which are consistent with six coordinated aluminum and bidentate behavior of the trithiophosphate moiety. The products also exhibit antifungal effectiveness against powdery mildew disease.

  DOI：

  10.1080/10426507.2012.746345
• 作为产物：
  描述：

  异丁醇 在 tetraphosphorus decasulfide 、 三乙胺 作用下， 以 乙醚 为溶剂， 生成 trithiophosphoric acid O-isobutyl ester
  参考文献：
  名称：

  Kotovich,B.P. et al., Journal of general chemistry of the USSR, 1968, vol. 38, p. 1235 - 1239

  摘要：

  DOI：

文献信息

• Synthesis, Spectroscopic Studies and Antifungal Activity of <i>O</i>-Alkyl or <i>O</i>-Aryl Trithiophosphate Derivatives of Trimethylaminoborane
  作者：Kiran Sankhala、Alok Chaturvedi

  DOI：10.1080/10426507.2012.685995

  日期：2012.10.1

  In this work, we report on the synthesis, characterization, and antifungal activities of new boron derivatives of O-alkyl or O-aryl trithiophosphate of the type ROP(S) S-2[BS2P(S)OR](2)center dot 2NMe(3) (R = Me, Et, Pr-i, Bu-i, Ph, CH2Ph). They were synthesized by the reaction of trimethylaminoborane with O-alkyl or O-aryl trithiophosphate in 2: 3 molar ratio in dried and distilled benzene. The newly synthesized derivatives are light yellow viscous liquids, monomer, and soluble in common organic solvents. These compounds have been characterized by elemental analysis, molecular weight determinations, and spectroscopic (IR, H-1, B-11, and P-31 NMR) studies which are consistent with four-coordinated boron and bidentate behavior of the trithiophosphate moiety. It is observed that when these derivatives are applied in the form of dilute solution in ethanol of various concentrations, they show their effectiveness against powdery mildew disease at a fixed interval of days.Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file.
• Kotovich,B.P. et al., Journal of general chemistry of the USSR, 1968, vol. 38, p. 1235 - 1239
  作者：Kotovich,B.P. et al.

  DOI：——

  日期：——
• Synthesis, Spectroscopic Studies, and Antifungal Activity of Tris(<i>O</i>-Alkyl or <i>O</i>-Aryltrithiophosphato) Aluminum(III)
  作者：Kiran Sankhala、Alok Chaturvedi

  DOI：10.1080/10426507.2012.746345

  日期：2013.10.1

  Aluminum(III) derivatives of O-alkyl or O-aryl trithiophosphate of the type Al[S2P(SH)OR](3) (R = Me, Et, Pr-i, Bu-i, Ph, CH2Ph) have been synthesized. The products were obtained as white powdery solids. The monomers are soluble in common organic solvents and were characterized by elemental analyses, molecular weight determinations, and IR and (H-1, Al-27, and P-31) NMR spectroscopic studies, which are consistent with six coordinated aluminum and bidentate behavior of the trithiophosphate moiety. The products also exhibit antifungal effectiveness against powdery mildew disease.