Zn(eIm)2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: Zn(eIm)2
• 英文别名: [zinc(2-ethylimidazole(-H))2]；Zn(2-ethylimidazole(-1H))2；[Zn(2-ethylimidazole)₂]_n；[Zn(eIM)₂]_n；zinc 2-ethylimidazolate；MAF-6
• 化学式: 2C₅H₇N₂*Zn
• 分子量: 255.638
• InChiKey: FRZNHYDXPUFGFS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  8.0
• 可旋转键数：
  1.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  26.99
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  氧气 、 Zn(eIm)2 生成 zinc(II) oxide
  参考文献：
  名称：

  通过宿主框架工程增强酶/MOF生物复合材料的生物活性

  摘要：

  本研究报告了相纯金属氮唑盐框架（MAF-6）的可持续合成方案的成功开发及其在酶固定化中的应用。合成了酯酶@MAF-6生物复合材料，并与酯酶@ZIF-8和酯酶@ZIF-90在酯交换反应中的催化性能进行了比较。Esterase@MAF-6具有较大的孔径，与esterase@ZIF-8和esterase@ZIF-90相比，在催化正丙醇和苯甲醇作为反应物的酯交换反应中表现出优异的酶性能。MAF-6平台的疏水性被证明可以将固定化酯酶激活为其开盖构象，在使用正丙醇和苯甲醇催化酯交换反应时，与游离酯酶相比，其酶活性分别是游离酯酶的1.5倍和4倍， 分别。目前的工作深入了解了 MAF-6 作为一种有前途的酶固定基质的潜力，并强调了探索具有扩大孔径的 MOF 基质以拓宽其在生物催化中的实际应用的必要性。

  DOI：

  10.1021/jacs.3c05488
• 作为产物：
  描述：

  2-乙基咪唑 、 zinc(II) oxide 在 NH₄NO₃ or NH₄CH₃SO₃ or (NH₄)2SO₄ 作用下， 以 further solvent(s) 为溶剂， 生成 Zn(eIm)2
  参考文献：
  名称：

  用机械化学快速合成沸石咪唑酯骨架的室温

  摘要：

  新鲜研磨：改进的机械化学方法，例如液体辅助研磨以及离子和液体辅助研磨，可在室温下直接从氧化锌快速和拓扑选择性地合成具有多种拓扑结构的多孔和无孔沸石咪唑酸酯骨架（参见方案） ）。

  DOI：

  10.1002/anie.201005547

文献信息

• Preparation method for zeolitic imidazolate frameworks
  申请人：China University of Petroleum-Beijing

  公开号：US10815253B2

  公开（公告）日：2020-10-27

  The present invention provides a preparation method for zeolitic imidazolate frameworks. The preparation method comprises: adding a metal carbonate or oxide, an organic ligand to a hydrophilic liquid to obtain a mixture; introducing an acidic gas to reach a reaction pressure of 0.1 MPa to 2.0 MPa, and reacting for a predetermined time; heating to 30° C.-60° C. and vacuuming to obtain the zeolitic imidazolate framework. The present invention also provides a zeolitic imidazolate framework obtained by the above preparation method. The preparation method according to the present invention is environmentally friendly and has a high yield.

  本发明提供了一种沸石咪唑酸盐框架的制备方法。所述制备方法包括：将金属碳酸盐或氧化物、有机配体加入到亲水性液体中以获得混合物；引入酸性气体以达到0.1 MPa至2.0 MPa的反应压力，并进行预定时间的反应；加热至30°C至60°C并进行真空处理以获得沸石咪唑酸盐框架。本发明还提供了通过上述制备方法获得的沸石咪唑酸盐框架。本发明的制备方法环保且产率高。
• Highly Efficient Non-Precious Metal Electrocatalysts Prepared from One-Pot Synthesized Zeolitic Imidazolate Frameworks
  作者：Dan Zhao、Jiang-Lan Shui、Lauren R. Grabstanowicz、Chen Chen、Sean M. Commet、Tao Xu、Jun Lu、Di-Jia Liu

  DOI：10.1002/adma.201304238

  日期：2014.2

  synthesis of non‐PGM ORR electrocatalysts through thermolysis of one‐pot synthesized ZIF is demonstrated. The electrocatalysts exhibit excellent activity, with a maximum volumetric current density of 88.1 A cm−3 measured at 0.8 V in PEFC tests. This approach not only makes ZIFs‐based electrocatalysts easy to scale up, but also paves the way for the tailored synthesis of electrocatalysts.

  通过单罐合成ZIF的热解，可以轻松合成非PGM ORR电催化剂。电催化剂表现出优异的活性，在PEFC测试中，在0.8 V下测得的最大体积电流密度为88.1 A cm -3。这种方法不仅使基于ZIFs的电催化剂易于扩大规模，而且为定制的电催化剂合成铺平了道路。
• WO2007/87434
  申请人：——

  公开号：——

  公开（公告）日：——
• Structural Descriptors of Zeolitic–Imidazolate Frameworks Are Keys to the Activity of Fe–N–C Catalysts
  作者：Vanessa Armel、Sheena Hindocha、Fabrice Salles、Stephen Bennett、Deborah Jones、Frédéric Jaouen

  DOI：10.1021/jacs.6b11248

  日期：2017.1.11

  Active and inexpensive catalysts for oxygen reduction are crucially needed for the widespread development of polymer electrolyte fuel cells and metal air batteries. While iron nitrogen carbon materials pyrolytically prepared from ZIF-8, a specific zeolitic imidazolate framework (ZIF) with sodalite topology, have shown enhanced activities toward oxygen reduction in acidic electrolyte, the rational design of sacrificial metal organic frameworks toward this application has hitherto remained elusive. Here, we report for the first time that the oxygen reduction activity of Fe-N-C catalysts positively correlates with the cavity size and mass specific pore volume in pristine ZIFs. The high activity of Fe-N-C materials prepared from ZIF-8 could be rationalized, and another ZIF structure leading to even higher activity was identified. In contrast, the ORR. activity is mostly unaffected by the ligand chemistry in pristine ZIFs. These structure property relationships will help identifying novel sacrificial ZIF or porous metal organic frameworks leading to even more active Fe-N-C catalysts. The findings are of great interest for a broader application of the class of inexpensive metal-nitrogen carbon catalysts that have shown promising activity also for the hydrogen evolution (Co-N-C) and carbon dioxide reduction (Fe-N-C and Mn-N-C).