(4R*,5S*)-2,2,4-triethyl-5-methyl-1,3-dioxolane

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (4R*,5S*)-2,2,4-triethyl-5-methyl-1,3-dioxolane
• 化学式: C₁₀H₂₀O₂
• 分子量: 172.268
• InChiKey: YGCDEVNIIFDSNC-DTWKUNHWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.72
• 重原子数：
  12.0
• 可旋转键数：
  3.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.46
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  反-2-戊烯 在 三氟化硼乙醚 、 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 生成 (4R*,5S*)-2,2,4-triethyl-5-methyl-1,3-dioxolane
  参考文献：
  名称：

  (4S,5S)-2,2,4-Triethyl-5-methyl-1,3-dioxolane: A New Volatile Released by a Triatomine Bug

  摘要：

  Adults of the triatomine bug Triatoma brasiliensis release 2,2,4-triethy1-5-methy1-1,3-dioxolane (1) as a mixture of the (4S,5S)- and (4R,5R)-enantiomers in a ratio of 4:1. Among the volatile acetals identified from insects so far, this is the first example resulting from an intermolecular condensation of a carbonyl moiety and a diol substructure.

  DOI：

  10.1021/ol102165q

文献信息

• (4<i>S</i>,5<i>S</i>)-2,2,4-Triethyl-5-methyl-1,3-dioxolane: A New Volatile Released by a Triatomine Bug
  作者：C. R. Unelius、B. Bohman、M. G. Lorenzo、A. Tröger、S. Franke、W. Francke

  DOI：10.1021/ol102165q

  日期：2010.12.17

  Adults of the triatomine bug Triatoma brasiliensis release 2,2,4-triethy1-5-methy1-1,3-dioxolane (1) as a mixture of the (4S,5S)- and (4R,5R)-enantiomers in a ratio of 4:1. Among the volatile acetals identified from insects so far, this is the first example resulting from an intermolecular condensation of a carbonyl moiety and a diol substructure.