2-(4-Chlorobenzyl)-2-(cyclopropylmethyl)malononitrile

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(4-Chlorobenzyl)-2-(cyclopropylmethyl)malononitrile
• 英文别名: 2-[(4-chlorophenyl)methyl]-2-(cyclopropylmethyl)propanedinitrile
• 化学式: C₁₄H₁₃ClN₂
• 分子量: 244.72
• InChiKey: PEDJRWACUZXTRS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  47.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-[(4-氯苯基)甲基]丙二腈 、 sodium;hydride 、 氢气 、 溴甲基环丙烷 、 盐酸 在 ice 、 乙醚 、 盐酸 、 氯化钠 、 magnesium sulfate 、 compound ( 1 ) 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 16.0h， 以to give 0.20 g of 2-(4-chlorobenzyl)-2-(cyclopropylmethyl)malononitrile (the present compound (1))的产率得到2-(4-Chlorobenzyl)-2-(cyclopropylmethyl)malononitrile
  参考文献：
  名称：

  Malononitrile compounds and their use as pesticides

  摘要：

  本发明涉及式（Y）的马隆腈化合物：其中R1和R2相同或不同，独立地为C1-C5（卤）烷基，C2-C5（卤）烷氧基，C2-C5（卤）烯基，C2-C5（卤）炔基，氢或氰基；R3为C3-C6（卤）环烷基；m为1至3的整数；R5为卤素，氰基，硝基，C1-C4（卤）烷基或类似物；n为0至4的整数，但当n为2或更多时，则R5互相相同或不同；R6为卤素，氰基，硝基，C1-C4（卤）烷基或类似物；以及含有这些化合物作为活性成分的杀虫剂组合物。本发明使得有效控制害虫，如昆虫害虫，螨类害虫和线虫害虫成为可能。

  公开号：

  US20040143007A1

文献信息

• MALONONITRILE COMPOUNDS AND THEIR USE AS PESTICIDES
  申请人：SUMITOMO CHEMICAL COMPANY LIMITED

  公开号：EP1392647A1

  公开（公告）日：2004-03-03
• [EN] MALONONITRILE COMPOUNDS AND THEIR USE AS PESTICIDES<br/>[FR] COMPOSES DE MALONONITRILE ET LEUR UTILISATION EN TANT QUE PESTICIDES
  申请人：SUMITOMO CHEMICAL CO

  公开号：WO2002090321A1

  公开（公告）日：2002-11-14

  The present invention relates to malononitrile compounds of formula (Y):wherein R1 and R2 are the same or different and independently C1-C5 (halo)alkyl, C1-C5 (halo)alkyloxy, C2-C5 (halo)alkenyl, C2-C5 (halo)alkynyl, hydrogen, or cyano; R¿3? is C?3-C6¿ (halo)cycloalkyl; m is an integer of 1 to 3; R¿5? is halogen, cyano, nitro, C?1-C4¿ (halo)alkyl, or the like; n is an integer of 0 to 4, with the proviso that when n is 2 or more, then R¿5'?s are the same or different from each other; R6 is halogen, cyano, nitro, C?1-C4¿ (halo)alkyl, or the like; as well as pesticide compositions containing these compounds as active ingredients. The present invention makes it possible to effectively control pests such as insect pests, acarine pests, and nematode pests.
• Malononitrile compounds and their use as pesticides
  申请人：——

  公开号：US20040143007A1

  公开（公告）日：2004-07-22

  The present invention relates to malononitrile compounds of formula (Y): 1 wherein R 1 and R 2 are the same or different and independently C 1 -C 5 (halo)alkyl, C 2 -C 5 (halo)alkyloxy, C 2 -C 5 (halo)alkenyl, C 2 -C 5 (halo)alkynyl, hydrogen, or cyano; R 3 is C 3 -C 6 (halo)cycloalkyl; m is an integer of 1 to 3; R 5 is halogen, cyano, nitro, C 1 -C 4 (halo)alkyl, or the like; n is an integer of 0 to 4, with the proviso that when n is 2 or more, then R 5 's are the same or different from each other; R 6 is halogen, cyano, nitro, C 1 -C 4 (halo)alkyl, or the like; as well as pesticide compositions containing these compounds as active ingredients. The present invention makes it possible to effectively control pests such as insect pests, acarine pests, and nematode pests.

  本发明涉及式（Y）的马隆腈化合物：其中R1和R2相同或不同，独立地为C1-C5（卤）烷基，C2-C5（卤）烷氧基，C2-C5（卤）烯基，C2-C5（卤）炔基，氢或氰基；R3为C3-C6（卤）环烷基；m为1至3的整数；R5为卤素，氰基，硝基，C1-C4（卤）烷基或类似物；n为0至4的整数，但当n为2或更多时，则R5互相相同或不同；R6为卤素，氰基，硝基，C1-C4（卤）烷基或类似物；以及含有这些化合物作为活性成分的杀虫剂组合物。本发明使得有效控制害虫，如昆虫害虫，螨类害虫和线虫害虫成为可能。