tenuifoliose N

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: tenuifoliose N
• 英文别名: [(2S,3S,4R,5R)-2-[(2R,3R,4S,5R,6R)-4-[(2S,3R,4R,5R,6R)-5-acetyloxy-6-(acetyloxymethyl)-3-hydroxy-4-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-6-(acetyloxymethyl)-5-[(E)-3-(4-hydroxy-3-methoxyphenyl)prop-2-enoyl]oxy-3-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-4-hydroxy-2-[[(E)-3-(4-hydroxy-3-methoxyphenyl)prop-2-enoyl]oxymethyl]-5-(hydroxymethyl)oxolan-3-yl] benzoate
• 化学式: C₆₃H₇₈O₃₆
• 分子量: 1411.29
• InChiKey: BEIREEVQRMGGTG-NBKBWZCNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.8
• 重原子数：
  99
• 可旋转键数：
  33
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  522
• 氢给体数：
  13
• 氢受体数：
  36

反应信息

• 作为反应物：
  描述：

  乙酸酐 、 tenuifoliose N 在 吡啶 作用下， 生成 [(2S,3S,4R,5R)-4-acetyloxy-2-[(2R,3R,4S,5R,6R)-5-[(E)-3-(4-acetyloxy-3-methoxyphenyl)prop-2-enoyl]oxy-6-(acetyloxymethyl)-4-[(2S,3R,4S,5R,6R)-3,5-diacetyloxy-6-(acetyloxymethyl)-4-[(2S,3R,4S,5R,6R)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-3-[(2S,3R,4S,5R,6R)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-2-[[(E)-3-(4-acetyloxy-3-methoxyphenyl)prop-2-enoyl]oxymethyl]-5-(acetyloxymethyl)oxolan-3-yl] benzoate
  参考文献：
  名称：

  Tenuifolioses G - P, Oligosaccharide Multi-Esters from the Roots of Polygala tenuifolia WILLD.

  摘要：

  From the roots of Polygala tenuifolia WILLD. ten new oligosaccharides, called tenuifolioses G-P, were isolated and their structures were elucidated by spectroscopic data and chemical evidance. These oligosaccharides were esterified with acetic, benzoic, p-coumaric and/or ferulic acid.

  DOI：

  10.1248/cpb.40.2741