5,6-di(4-t-butylphenoxy)-4,7bis(2-thienyl)2,1,3-benzothiadiazole

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5,6-di(4-t-butylphenoxy)-4,7bis(2-thienyl)2,1,3-benzothiadiazole
• 英文别名: 5,6-Bis(4-tert-butylphenoxy)-4,7-dithiophen-2-yl-2,1,3-benzothiadiazole；5,6-bis(4-tert-butylphenoxy)-4,7-dithiophen-2-yl-2,1,3-benzothiadiazole
• 化学式: C₃₄H₃₂N₂O₂S₃
• 分子量: 596.838
• InChiKey: HBWVSVWFPYHECR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.9
• 重原子数：
  41
• 可旋转键数：
  8
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  129
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  4-叔丁基苯酚 、 5,6-二氟-4,7-二(噻吩基)苯并[C][1,2,5]噻二唑 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 12.0h， 以88%的产率得到5,6-di(4-t-butylphenoxy)-4,7bis(2-thienyl)2,1,3-benzothiadiazole
  参考文献：
  名称：

  [EN] DISUBSTITUTED DIARYLOXYBENZOHETERODIAZOLE COMPOUNDS
  [FR] COMPOSÉS DISUBSTITUÉS DE DIARYLOXYBENZOHÉTÉRODIAZOLE

  摘要：

  通用公式（1）的二取代二芳氧基苯并噻二唑化合物：其中：∙ - Z代表硫原子、氧原子、硒原子；或者一个NR 5基团，其中R5从线性或支链的C1-C20，优选C1-C8，烷基基团中选择，或者从可选择取代的芳基基团中选择；∙ - R1、R2和R3如权利要求中所定义。所述的通用公式（I）的二取代二芳氧基苯并噻二唑化合物可以优点地用作光致发光太阳能聚光器（LSCs）中的光谱转换器，这反过来能够改善选定的光伏器件（或太阳能器件）的性能，例如光伏电池（或太阳能电池）、光伏模块（或太阳能模块）在刚性基板或柔性基板上。

  公开号：

  WO2016046319A1

文献信息

• Disubstituted diaryloxybenzoheterodiazole compounds
  申请人：ENI S.P.A.

  公开号：US11133474B2

  公开（公告）日：2021-09-28

  Disubstituted diaryloxybenzoheterodiazole compound of general formula (1): in which:—Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR5 group in which R5 is selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, or from optionally substituted aryl groups;—R1, R2 and R3 are as defined in the claims. The said disubstituted diaryloxybenzoheterodiazole compound of general formula (I) can advantageously be used as a spectrum converter in luminescent solar concentrators (LSCs) which are in turn capable of improving the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules) on either a rigid substrate or a flexible substrate.

  通式(1)的二取代二芳基苯并二唑化合物： 其中：-Z 代表硫原子、氧原子、硒原子；或 NR5 基团，其中 R5 选自直链或支链 C1-C20，优选 C1-C8，烷基或任选取代的芳基；-R1、R2 和 R3 如权利要求书中所定义。通式(I)的上述二取代二芳基苯并二氮杂环唑化合物可有利地用作发光太阳能聚光器（LSCs）中的光谱转换器，而LSCs反过来又能提高光电设备（或太阳能设备）的性能，例如，可选自刚性基板或柔性基板上的光电池（或太阳能电池）、光电模块（或太阳能模块）。
• Disubstituted Diaryloxybenzoheterodiazole Compounds
  申请人：ENI S.p.A.

  公开号：US20170250350A1

  公开（公告）日：2017-08-31

  Disubstituted diaryloxybenzoheterodiazole compound of general formula (1): in which:—Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR 5 group in which R 5 is selected from linear or branched C 1 -C 20 , preferably C 1 -C 8 , alkyl groups, or from optionally substituted aryl groups;—R 1 , R 2 and R 3 are as defined in the claims. The said disubstituted diaryloxybenzoheterodiazole compound of general formula (I) can advantageously be used as a spectrum converter in luminescent solar concentrators (LSCs) which are in turn capable of improving the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules) on either a rigid substrate or a flexible substrate.
• PROCESS FOR THE PREPARATION OF DISUBSTITUTED DIARYLOXYBENZOHETERODIAZOLE COMPOUNDS
  申请人：ENI S.P.A.

  公开号：US20200339560A1

  公开（公告）日：2020-10-29

  Process for the preparation of a disubstituted diaryloxybenzoheterodiazole compound having general formula (I):
• [EN] DISUBSTITUTED DIARYLOXYBENZOHETERODIAZOLE COMPOUNDS<br/>[FR] COMPOSÉS DISUBSTITUÉS DE DIARYLOXYBENZOHÉTÉRODIAZOLE
  申请人：ENI SPA

  公开号：WO2016046319A1

  公开（公告）日：2016-03-31

  Disubstituted diaryloxybenzoheterodiazole compound of general formula (1): in which: ∙ - Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR 5group in which R5 is selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, or from optionally substituted aryl groups; ∙ - R1, R2 and R3 are as defined in the claims. The said disubstituted diaryloxybenzoheterodiazole compound of general formula (I) can advantageously be used as a spectrum converter in luminescent solar concentrators (LSCs) which are in turn capable of improving the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules) on either a rigid substrate or a flexible substrate.

  通用公式（1）的二取代二芳氧基苯并噻二唑化合物：其中：∙ - Z代表硫原子、氧原子、硒原子；或者一个NR 5基团，其中R5从线性或支链的C1-C20，优选C1-C8，烷基基团中选择，或者从可选择取代的芳基基团中选择；∙ - R1、R2和R3如权利要求中所定义。所述的通用公式（I）的二取代二芳氧基苯并噻二唑化合物可以优点地用作光致发光太阳能聚光器（LSCs）中的光谱转换器，这反过来能够改善选定的光伏器件（或太阳能器件）的性能，例如光伏电池（或太阳能电池）、光伏模块（或太阳能模块）在刚性基板或柔性基板上。