反式-3-羟基-2-甲基环己酮 | 102547-88-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 反式-3-羟基-2-甲基环己酮
• 英文名称: 3-hydroxy-2-methyl-1-cyclohexanone
• 英文别名: 3-Hydroxy-2-methylcyclohexan-1-one
• CAS: 102547-88-6
• 化学式: C₇H₁₂O₂
• 分子量: 128.171
• InChiKey: ZBNASJDWWRBWPS-UHFFFAOYSA-N

物化性质

• 沸点：
  128-129 °C(Press: 10 Torr)
• 密度：
  1.068±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  反式-3-羟基-2-甲基环己酮 、 丁烯酮 反应 6.0h， 以80%的产率得到9-甲基-delta-5(10)-辛-1,6-二酮
  参考文献：
  名称：

  Findlay, John A.; Desai, Dixit N.; Macaulay, John B., Canadian Journal of Chemistry, 1981, vol. 59, p. 3303 - 3304

  摘要：

  DOI：
• 作为产物：
  描述：

  2-甲基-1,3-环己二酮 在 bis(η5-cyclopentadienyl)hafnium dihydride 作用下， 以 异丙醇 为溶剂， 反应 8.0h， 以52%的产率得到反式-3-羟基-2-甲基环己酮
  参考文献：
  名称：

  Meerwein-Ponndorf-Verley-type reduction of dicarbonyl compounds to hydroxy carbonyl compounds and .alpha.,.beta.-unsaturated carbonyl compounds to allylic alcohols catalyzed by zirconocene and hafnocene complexes

  摘要：

  DOI：

  10.1021/jo00251a016

文献信息

• Salt suitable for an acid generator and a chemically amplified positive resist composition containing the same
  申请人：Harada Yukako

  公开号：US20080081293A1

  公开（公告）日：2008-04-03

  The present invention provides a salt represented by the formula (I): wherein P 1 , P 2 and P 3 each independently represent a C1-C30 alkyl group which may be substituted with at least one selected from a hydroxyl group, a C3-C12 cyclic hydrocarbon group and a C1-C12 alkoxy group, or a C3-C30 cyclic hydrocarbon group which may be substituted with at least one selected from a hydroxyl group and a C1-C12 alkoxy group, provided that all of P 1 , P 2 and P 3 are not simultaneously phenyl groups which may be substituted, Q 1 and Q 2 each independently represent a fluorine atom or a C1-C6 perfluoroalkyl group, and R represents a group represented by the formula: wherein A 1 represents —OH or —Y 1 —OH, n represents an integer of 1 to 9, and Y 1 represents a divalent C1-C6 saturated aliphatic hydrocarbon group; a group represented by the formula: wherein ring X 1 represents a C3-C30 monocyclic or polycyclic hydrocarbon group in which one —CH 2 — group is substituted with —CO—, and at least one hydrogen atom in the monocyclic or polycyclic hydrocarbon group may be substituted with a C1-C6 alkyl group, a C1-C6 alkoxy group, a C1-C4 perfluoroalkyl group, a C1-C6 hydroxyalkyl group, a hydroxyl group or a cyano group; a group represented by the formula: wherein ring X 2 represents a C3-C30 monocyclic or polycyclic hydrocarbon group in which a hydrogen atom of one —CH 2 — group is substituted with a hydroxyl group, and at least one hydrogen atom in the monocyclic or polycyclic hydrocarbon group may be substituted with a C1-C6 alkyl group, a C1-C6 alkoxy group, a C1-C4 perfluoroalkyl group, a C1-C6 hydroxyalkyl group, a hydroxyl group or a cyano group; a group represented by the formula: wherein ring X 3 represents a C3-C30 monocyclic or polycyclic hydrocarbon group in which one —CH 2 — group is substituted with —COO—, and at least one hydrogen atom in the monocyclic or polycyclic hydrocarbon group may be substituted with a C1-C6 alkyl group, a C1-C6 alkoxy group, a C1-C4 perfluoroalkyl group, a C1-C6 hydroxyalkyl group, a hydroxyl group or a cyano group, and m represents an integer of 0 to 12; or a group represented by the formula: wherein ring X 4 represents a C6-C30 polycyclic hydrocarbon group having tricycle or more, and at least one hydrogen atom in the polycyclic hydrocarbon group may be substituted with a C1-C6 alkyl group, a C1-C6 alkoxy group, a C1-C4 perfluoroalkyl group, a C1-C6 hydroxyalkyl group or a cyano group, and l represents an integer of 1 to 12. The present invention further provides a chemically amplified resist composition comprising the salt represented by the above-mentioned formula (I).

  本发明提供了一种盐，其表示为公式（I）：其中P1、P2和P3各自独立地表示一个C1-C30烷基基团，该基团可以被至少一个羟基、一个C3-C12环烃基团和一个C1-C12烷氧基中的至少一个取代，或者一个C3-C30环烃基团，该基团可以被至少一个羟基和一个C1-C12烷氧基中的至少一个取代，前提是P1、P2和P3均不同时为可以被取代的苯基；Q1和Q2各自独立地表示氟原子或者C1-C6全氟烷基基团，R表示由以下公式表示的一个基团：其中A1表示—OH或—Y1—OH，n表示1到9之间的整数，Y1表示二价的C1-C6饱和脂肪族碳氢基团；一个由以下公式表示的基团：其中环X1表示一个C3-C30的单环或多环碳氢基团，其中一个—CH2—基团被—CO—取代，并且单环或多环碳氢基团中的至少一个氢原子可以被C1-C6烷基基团、C1-C6烷氧基、C1-C4全氟烷基基团、C1-C6羟基烷基基团、羟基或氰基取代；一个由以下公式表示的基团：其中环X2表示一个C3-C30的单环或多环碳氢基团，其中一个—CH2—基团的氢原子被羟基取代，并且单环或多环碳氢基团中的至少一个氢原子可以被C1-C6烷基基团、C1-C6烷氧基、C1-C4全氟烷基基团、C1-C6羟基烷基基团、羟基或氰基取代；一个由以下公式表示的基团：其中环X3表示一个C3-C30的单环或多环碳氢基团，其中一个—CH2—基团被—COO—取代，并且单环或多环碳氢基团中的至少一个氢原子可以被C1-C6烷基基团、C1-C6烷氧基、C1-C4全氟烷基基团、C1-C6羟基烷基基团、羟基或氰基取代，m表示0到12之间的整数；或者一个由以下公式表示的基团：其中环X4表示一个具有三环或更多的C6-C30多环碳氢基团，多环碳氢基团中的至少一个氢原子可以被C1-C6烷基基团、C1-C6烷氧基、C1-C4全氟烷基基团、C1-C6羟基烷基基团或氰基取代，l表示1到12之间的整数。本发明还提供了一种化学增感抗蚀组合物，其包含上述公式（I）表示的盐。
• METHOD OF MANUFACTURING 4,4"-DIHYDROXY-M-TERPHENYL
  申请人：Honshu Chemical Industry Co., Ltd.

  公开号：US20150158800A1

  公开（公告）日：2015-06-11

  To achieve the object of providing a new method of manufacturing 4,4″-dihydroxy-m-terphenyl, the present invention provides a method of manufacturing 4,4″-dihydroxy-m-terphenyl expressed by General Formula (4) below, characterized in that such method uses a 2-cyclohexene-1-one expressed by General Formula (1) below or 3-hydroxycyclohexane-1-one expressed by General Formula (2) below, and phenol expressed by General Formula (3) below as materials and implements Step (A), Step (B), and Step (C) below, in this order, or Step (D) and Step (C) below, in this order: (In the formulas, each R 2 independently represents an alkyl group, alkoxy group, aromatic hydrocarbon group, or halogen atom, while m independently indicates 0 or an integer of 1 to 4, where R 2 substitution does not occur in the third position when m is 1 or greater, and when m is 2 or greater, R 2 's may be identical or different, and R 2 substitution does not occur in two positions of the same carbon atom. In addition, R 2 and m in General Formula (1) may be identical to or different from R 2 and m in General Formula (2), respectively.) (In the formula, each R 1 independently represents an alkyl group, alkoxy group, aromatic hydrocarbon group, halogen atom, or hydroxyl group, while n indicates 0 or an integer of 1 to 4, where R 1 's may be identical or different when n is 2 or greater.) Step (A): Step to obtain a 1,1,3-trisphenol by causing the 2-cyclohexene-1-one or 3-hydroxycyclohexane-1-one and phenol to react with each other in the presence of a catalyst. Step (B): Step to obtain a bis(4-hydroxyphenyl)cyclohexene by causing the 1,1,3-trisphenol to undergo breakdown reaction. Step (C): Step to obtain a 4,4″-dihydroxy-m-terphenyl by dehydrogenating the bis(4-hydroxyphenyl)cyclohexene. Step (D): Step to obtain a bis(4-hydroxyphenyl)cyclohexene by causing the 2-cyclohexene-1-one or 3-hydroxycyclohexane-1-one and phenol to react with each other in the presence of a catalyst. (In the formula, each R 1 and n is independently the same as the corresponding items in General Formula (3), respectively, while R 2 and m are the same as the corresponding items in General Formula (1) or General Formula (2), respectively.)

  为了提供一种制造4,4″-二羟基-m-联苯的新方法，本发明提供了一种制造4,4″-二羟基-m-联苯的方法，其由下式（4）表示，其特征在于该方法使用下式（1）表示的2-环己烯-1-酮或下式（2）表示的3-羟基环己烷-1-酮以及下式（3）表示的苯酚作为原料，并按照以下顺序实施步骤（A）、（B）和（C），或按照以下顺序实施步骤（D）和（C）：（在公式中，每个R2独立表示烷基、烷氧基、芳香烃基或卤素原子，而m独立表示0或1至4的整数，在m为1或更大时不在第三位置发生R2取代，在m为2或更大时，R2可以相同或不同，并且在同一碳原子的两个位置不发生R2取代。此外，通式（1）中的R2和m可以与通式（2）中的R2和m分别相同或不同。）（在公式中，每个R1独立表示烷基、烷氧基、芳香烃基、卤素原子或羟基，而n表示0或1至4的整数，在n为2或更大时，R1可以相同或不同。）步骤（A）：在催化剂的存在下，使2-环己烯-1-酮或3-羟基环己烷-1-酮和苯酚相互反应以获得1,1,3-三酚。步骤（B）：使1,1,3-三酚发生分解反应以获得双（4-羟基苯基）环己烯。步骤（C）：通过脱氢反应获得4,4″-二羟基-m-联苯。步骤（D）：在催化剂的存在下，使2-环己烯-1-酮或3-羟基环己烷-1-酮和苯酚相互反应以获得双（4-羟基苯基）环己烯。（在公式中，每个R1和n分别独立于相应的通式（3）中的相应项，而R2和m与相应的通式（1）或通式（2）中的相应项相同。）
• A salt suitable for an acid generator and a chemically amplified resist composition containing the same
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1873143A1

  公开（公告）日：2008-01-02

  The present invention provides a salt of the formula (L) wherein Q represents -CO- group or -C(OH)- group; ring X represents monocyclic or polycyclic hydrocarbon group having 3 to 30 carbon atoms in which a hydrogen atom is substituted by a hydroxyl group at Q position when Q is -C(OH)- group or in which two hydrogen atoms are substituted by =O group at Q position when Q is -CO- group, and at least one hydrogen atom in the monocyclic or polycyclic hydrocarbon group may optionally be substituted by an alkyl group having 1 to 6 carbon atoms, alkoxy group having 1 to 6 carbon atoms, perfluoroalkyl group having 1 to 4 carbon atoms, hydroxyalkyl group having 1 to 6 carbon atoms, hydroxyl group or cyano group; R10 and R20 each independently represent fluorine atom or perfluoroalkyl group having 1 to 6 carbon atoms; and A+ represents organic counter ion. The present invention also provides a chemically amplified resist composition comprising the salt of the formula (L).

  本发明提供了一种式 (L) 的盐 其中 Q 代表-CO-基团或-C(OH)-基团；环 X 代表具有 3 至 30 个碳原子的单环或多环烃基；当 Q 为-C(OH)-基团时，其中一个氢原子在 Q 位被羟基取代；当 Q 为-CO-基团时，其中两个氢原子在 Q 位被 =O 基团取代、单环或多环烃类基团中的至少一个氢原子可选择被 1 至 6 个碳原子的烷基、1 至 6 个碳原子的烷氧基、1 至 4 个碳原子的全氟烷基、1 至 6 个碳原子的羟烷基、羟基或氰基取代；R10 和 R20 各自独立地代表氟原子或具有 1 至 6 个碳原子的全氟烷基；以及 A+ 代表有机反离子。 本发明还提供了一种包含式（L）盐的化学放大抗蚀剂组合物。
• METHOD FOR PRODUCING 4,4''-DIHYDROXY-M-TERPHENYLS
  申请人：Honshu Chemical Industry Co., Ltd.

  公开号：EP2851359B1

  公开（公告）日：2017-03-29
• WÄSSRIGES HERBIZIDES MITTEL AUF BASIS EINES SUSPENSIONSKONZENTRATS ENTHALTEND HERBIZIDE UND SAFENER
  申请人：Bayer Intellectual Property GmbH

  公开号：EP1951052B1

  公开（公告）日：2017-05-03